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The Catalytic Effects of Water and Halogens on the Alteration of Catalyst Surfaces

  • Dennis A. Dowden
Conference paper
Part of the NATO Advanced Study Institutes Series book series (NSSE, volume 54)

Summary

The sintering of particulate solids is described and the possible mechanisms briefly outlined. Little is known about the sintering of very small particles but surface diffusion probably plays an important part. The effects of water, steam and halogens upon these processes are then examined using current models and it is seen that some simple parameters, such as solubility, melting point and lattice energy, are useful indicators of the behaviour of solids under a number of conditions ranging from states with capillary water to those with chemisorbed water.

Some situations are mentioned which present problems in industrial catalysis.

Keywords

Volume Diffusion Lattice Energy Frenkel Defect Kink Site Excess Chemical Potential 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Martinus Nijhoff Publishers, The Hague 1982

Authors and Affiliations

  • Dennis A. Dowden
    • 1
  1. 1.Department of Chemical Engineering and Chemical TechnologyImperial CollegeLondonUK

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