Abstract
Current analytical methods for the determination of PAH in environmental samples require the separation of individual compounds, either by thin layer or high performance liquid chromatography with fluorescence detection, or better, by gas chromatography on capillary columns, coupled to a flame ionisation detector or a mass spectrometer. Modern thermostable capillary columns will allow the elution of PAH in the molecular weight range above coronene. Prior isolation of PAH as a compound class by liquid-liquid partition and column chromatography is necessary before most of these techniques can be applied.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Commins B.T.: 1962, National Cancer Institute Monograph 9, pp 225.
Rondia D.: 1965, Intern. J. Water Air Poll. 9, pp 113.
Pupp C., Lao R.C., Murray J.J. and Pottie R.F.: 1974, Atmos. Environ. 8, pp 915.
Tomingas R. and Voltmer G.: 1978, Staub Reinhalt. Luft 38, pp 216.
Peters J. and Seifert B.: 1980, Atmos. Environ. 14, pp 117.
Brockhaus A.: 1974, Atmos. Environ. 8, pp 521.
König J., Funcke W., Balfanz E., Grosch B. and Pott F.: 1980, Atmos. Environ. 14, pp 609–613.
Van Vaeck L., Broddin G. and Van Cauwenberghe K.: 1980, Biomed. Mass Spectrom. 7, pp 473–483.
Thrane K.E. and Mikalsen A.: 1981, Atmos. Environ. 15, pp 909–918.
Grimmer G.: 1981, Workshop on Polycyclic Aromatic Hydrocarbons, OECD Paris, Report to the Air Management Policy Group, Appendix.
Hughes M.M., Natusch D.F.S., Taylor D.R. and Zeller M.V.: 1980, ‘Chemical Transformations of Particulate Polycyclic Organic Matter’ in Polynuclear Aromatic Hydrocarbons, eds. Björseth A. and Dennis A.J., Batteile Press, Columbus Ohio.
Grimmer G.: 1981, Workshop on Polycyclic Aromatic Hydrocarbons, OECD Paris, ‘Analysis, Data Reporting and Profile Concept’ background paper.
Griest W.H., Yeatts Jr L.B. and Caton J.E.: 1980, Anal. Chem. 52, pp 199–201.
Stenberg U.R. and Aisberg T.E.: 1981, Anal. Chem. 53, pp 2067–2072.
Sawicki E.: 1964, Chemist Analyst 53, pp 24, 56, 88.
Pierce R.C. and Katz M.: 1975, Anal. Chem. 47, pp 1743.
Wilk M., Rochlitz J. and Bende H.: 1966, J. Chromatog. 24, pp 414–416.
Oelert H.H.: 1969, Fresenius Z. Anal. Chem. 224, pp 91.
Carugno N. and Rossi S.: 1967, J. Gas Chromatog. 5, pp 103.
Grimmer G. and Böhnke H.: 1972, Z. Anal. Chem. 261, pp 310.
Lee M.L., Bartle K.D. and Novotny M.V.: 1975, Anal. Chem. 47, pp 540.
Dandeneau R.D. and Zerenner E.H.: 1979, J. High Resoln Chromatog. Chromatog. Commun. 2, pp 351.
Cantuti V., Cartoni G.P., Liberti A. and Torri A.G.: 1965, J. Chromatog. 17, pp 60.
Borwitzky H. and Schomburg G.: 1979, J. Chromatog. 170, pp 99.
Grob K.: 1974, Chromatographia 7, pp 94.
Romanowski T., Funcke W., König J. and Balfanz E.: 1961, J. High Resoln Chromatog./Chromatog. Commun. 4, pp 209–214.
Lee M.L. and Wright B.W.: 1980, J. Chromatog. Sci. 18, pp 345–358.
Wakeham S.G.: 1979, Environ. Sci. Technol. 13, pp 1119.
Willey C., Lee M.L., Iwao M. and Castle R.N.: 1982, Anal. Chem.
Van Vaeck L. and Van Cauwenberghe K.: 1978, Atmos. Environ. 12, pp 2229–2237.
Ogan K. and Katz E.: 1980, J. Chromatog. 188, pp 115–127.
Dong M., Locke D. and Hoffmann D.: 1977, Environ. Sci. Technol. 11, pp 612–618.
Peaden P.A., Lee M.L., Hirata Y. and Novotny M.: 1980, Anal. Chem. 52, pp 2268–2271.
Pierce R.C. and Katz M.: 1976, Environ. Sci. Technol. 10, pp 45.
Arpino P.J. and Guiochon G.: 1979, Anal. Chem. 51, pp 682A.
Schäfer K.H. and Levsen K.: 1981, J. Chromatog. 206, pp 245–252.
Chmielowiec J. and George A.E.: 1980, Anal. Chem. 52, pp 1154–1157.
Yang Y., D’Silva A.P. and Fassel V.A.: 1981, Anal. Chem. 53, pp 894–899.
Maple J.R., Wehry E.L. and Mamantov G.: 1980, Anal. Chem. 52, pp 920–924.
Brown J.C., Duncanson J.A. and Small G.J.: 1980, Anal. Chem. 52, pp 1711–1715.
Zakett D., Shaddock M. and Cooks R.G.: 1979, Anal. Chem. 51, pp 1849–1852.
Zakett D., Ciuper J.D. and Cooks R.G.: 1981, Anal. Chem. 53, pp 723–726.
Wilson B.W., presented at the Second Symposium on Environmental Analytical Chemistry, Provo Utah 1980.
Schuetzle D., Riley T.L., Prater T.J., Harvey T.M. and Hunt D.F.: 1982, Anal. Chem. 54, pp 265–271.
Jerina D., Lehr R., Yagi H., Hernandez O., Dansette P., Wislocki P., Wood A., Chang R., Levin W. and Conney A.: 1976 in de Serres F., Fouts J., Bend J. and Philpot R. (eds) In Vitro Metabolic Activation in Mutagenesis Testing, Elsevier, Amsterdam.
Schuetzle D., Lee F.S.C., Prater T.J. and Tejada S.B.: 1981, Intern. J. Environ. Anal. Chem. 9, pp 93–144.
Choudhury D.R.: 1982, Environ. Sci. Technol. 16, pp 102–106.
Sawicki E.: 1967, Archives Environ. Health 14, pp 46.
Mc Clusky G.A., Huang S.K., Moore C.J. and Selkirk J.K.: 1980, Annual Conference of the American Society for Mass Spectrometry New York Abstr. RAMOA5.
Ishii D. and Takeuchi T.: 1980, J. Chromatog. Sci. 18, pp 462.
Ames B.N., Mc Cann J. and Yamasaki E.: 1975, Mutation Res. 31, pp 347.
Pitts Jr J.N., Doyle G.J., Lloyd A.C. and Winer A.M.: 1975, ‘Dhemical Transformations in Photochemical Smog and their Applications to Air Pollution Control Strategies’, 2nd Annual Report to NSF-RANN, Grant No AEN 73-02904-A02.
Pitts Jr J.N., Grosjean D., Mischke T.M., Simmon V.F. and Poole D.: 1977, Toxicol. Lett. 1, pp 65–70.
Tokiwa H., Tokeyoshi H., Morita K., Takahashi K., Soruta N. and Ohnishi Y.: 1976, Nutation Res. 38, pp 351–359.
Talcott R. and Wei E.: 1977, J. National Cancer Institute 58, pp 449–451.
Teranishi K., Hamada K. and Watanabe H.: 1978, Mutation Res. 56, pp 273–280.
Möller M. and Alfheim I.: 1980, Atmos. Environ. 14, pp 83.
Wang Y.Y., Talcott R.E., Sawyer R.F., Rappaport S.M. and Wei B.T.: 1978, ‘Mutagens in Automobile Exhaust’ presented at the Symposium on Application of Short Term Bioassays in the Fractionation and Analysis of Complex Environmental Mixtures, U.S. EPA, Williamsburg Virginia.
Barth D.S. and Blacker S.M.: 1978, ‘EPA’s Program to Assess the Public Health Significance of Diesel Emissions’ presented at the 71st Air Pollution Control Association Annual Meeting, Houston Texas.
Chrisp C.E., Fisher G.L. and Lammert J.E.: 1978, Science 199, PP 73.
Kaden D.A. and Thilly W.G.: 1978, ‘Genetic Toxicology of Kerosene Soot’ in Proceedings of the Workshop on Unregulated Diesel Emissions and their Potential Health Effects, U.S. Dept. of Transportation, Washington DC, pp 612–633.
Pelroy R., Stewart D., Tominaga Y., Iwao M., Castle R. and Lee M.: 1981, Mutation Res., in press.
Ho C., Clark B., Guerin M., Barkenbus B., Rau T. and Epier J.: 1981, Mutation Res., in press.
Dean B.J.: 1978, Mutation Res. 47, pp 75–97.
Brown J. and Brown R.: 1976, Mutation Res. 40, pp 203–224.
Talcott R. and Harger W.: 1980, Mutation Res. 79, pp 177.
Cautreels W. and Van Cauwenberghe K.: 1976, Atmos. Environ. 10, pp 447.
Rappaport S.M., Wang Y.Y., Wei E.T., Watkins B.E. and Rapoport H.: 1980, Environ. Sci. Technol. 14, pp 1505.
Pitts Jr J.N., Van Cauwenberghe K., Grosjean D., Schmid J.P., Fitz D.R., Belser W.L., Knudson G.B. and Hynds P.M.: 1978, Science 202, pp 515.
Pitts Jr J.N., Lokensgard D.M., Ripley P.S., Van Cauwenberghe K., Van Vaeck L., Shaffer S.D., Thill A.J. and Belser W.L.: 1980, Science 210, pp 1347.
Berry R.S. and Lehman P.A.: 1971, Ann. Rev. Phys. Chem. 22, pp 47–84.
Jerina D., Yagi H., Hernandez O., Dansette P., Wood A., Levin W., Chang R., Wislocki P. and Conney A.: 1976, ‘Synthesis and Biological Activity of Potential Benzo(a)pyrene Metabolites’ in Freudenthal R. and Jones P. (eds), Polynuclear Aromatic Hydrocarbons: Chemistry, Metabolism and Carcinogenesis, Raven Press, New York.
Burton R.M., Howard J.N., Penley R.L., Ramsay P.A. and Clark T.A.: 1973, J. Air Pollut. Control Assoc. 23, pp 277.
National Academy of Science: 1972, ‘Particulate Polycyclic Organic Matter’, Committee on Biological Effects of Atmospheric Pollutants, Washington DC.
Inscoe M.N.: 1964, Anal. Chefn. 36, pp 2505.
Inomata M. and Nagata C.: 1972, GANN 63, pp 119.
Schaap P.A. (ed): 1976,’ singlet Molecular Oxygen’, Dowden, Hutchinson and Ross Inc., Strondsburg PA.
Geacintov N.E.: 1973, ‘Reactivity of PAH with O2 and NO in the presence of light’, U.S. EPA, Washington DC, Publ. No650/l-74-010.
Grossman B.: 1976, ‘Photooxidation of PAH by Singlet Oxygen’, Ph.D. thesis, Universitaire Instelling Antwerpen.
Falk H.L., Narkul I. and Kotin P.: 1956, A.M.A. Arch. Ind. Health 13, pp 13.
Tebbens B.D., Thomas J.F. and Mukai M.: 1966, J. Amer. Ind. Hyg. Assoc. 27, pp 415.
Thomas J.F., Mukai M. and Tebbens B.D.: 1968, Environ. Sci. Technol. 2, pp 33.
Criegee R.: 1957, Rec. Chem. Progress 18, pp 111.
Moriconi E., Rackoczy B. and O’Connor W.: 1961, J. Am. Chem. Soc. 83, pp 4618.
Kemps M. and Van Cauwenberghe K.: unpublished results.
Chen P.N., Junk G.A. and Svec H.J.: 1979, Environ. Sci. Technol. 13, pp 451.
Radding S.B., Mill T., Could C.W., Liu D.H., Johnson H.L., Bomberger D.C. and Tojo C.J.: 1976, ‘The Environmental Fate of Selected PAH’, Stanford Research Institute EPA No 68-01-2681.
Lane D.A. and Katz M.: 1977, ‘The Photomodification of Benzo(a) pyrene and Benzo(b)-and (k)f luoranthenes under Simulated Atmospheric Conditions’ in Fate of Pollutants in the Air and Water Environment, Part 2, Suffet I.(ed), Wiley-Interscience, New York.
Atkinson R.A., Darnall K.D., Lloyd A.C., Winer A.M. and Pitts Jr J.N.: 1979, ‘Kinetics and Mechanisms of the Reactions of the Hydroxyl Radical with Organic Compounds in the Gas Phase’ in Advances in Photochemistry 11, Pitts Jr J.N., Hammond G.S. and Gollnick K. (eds), Wiley, New York.
Chekulaev V.P. and Shevchuk I.M.: 1981, Eesti NSV Teod. Akad. Toim. Keem. 30, pp 138–140.
Dewar M.J., Mole T., Urch D.S. and Warford E.W.: 1956, J. Chem. Soc. pp 3572.
Vollman H., Becker H., Corell M., Streeck H. and Longbein G.: 1937, Ann. Chem. 531, pp 1459.
Nielsen T.: 1961, ‘A Study of the Reactivity of PAH’, Nordic PAH project, Report No 10, Central Institute for Industrial Research, Oslo.
Van Cauwenberghe K. and Van Vaeck L.: 1980, ‘Physical and Chemical Transformations of Organic Pollutants during Aerosol Sampling’ in Quayle A.(ed), Advances in Mass Spectrometry 8, pp 1499, Heyden and Son Ltd, London.
Grover P.L. and Sims P.: 1970, Biochem. Pharmacol. 19, pp 2251
Jaeger J.: 1978, J. Chromatog. 152, pp 575.
Wang C.Y., Lee M., King C.M. and Warner P.O.: 1980, Chemosphere 9, pp 63.
Jaeger J. and Hanus V.: 1980, J. Hyg. Epidemiol. Microbiol. Immunol 24, pp 1.
Jaeger J. and Rakovic M.: 1974, J. Hyg. Epidemiol. Microbiol. Immunol 18, pp 137.
Miguel A.M., Korfmacher W.A., Wehry E.L., Mamantov G. and Natusch D.F.: 1979, Environ. Sci. Technol. 13, pp 1229.
Korfmacher W.A., Wehry E.L., Mamantov G. and Natusch D.F.: 1980, Environ. Sci. Technol. 14, pp 1094.
Fox M.A. and Olive S.: 1979, Science 205, pp 582.
Butler J.D. and Crossley P.: 1981, Atmos. Environ. 15, pp 91.
Löfroth G., Toftgard R., Carlstedt-Duke J., Gustafsson J.A., Brorström E., Grennfelt P. and Lindskog A.: 1981, ‘Effects of Ozone and Nitrogen Dioxide present during Sampling of Genuine Particulate Matter as detected by Two Biological Test Systems and Analysis of PAH’ presented at EPA’s Diesel Emissions Symposium, Raleigh North Carolina.
De Wiest F. and Brull P.: 1960, ‘Interfacial Physicochemical Characteristics of Airborne Soot Particles’ in Proceedings of the 14th International Colloquium on Atmospheric Pollution Paris, Benarie M.(ed), Studies in Environmental Science 8, pp 227, Elsevier Scientific Publ. Co, Amsterdam.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1983 D. Reidel Publishing Company
About this chapter
Cite this chapter
Van Cauwenberghe, K., Van Vaeck, L. (1983). Modern PAH-Analysis and Fate of PAH in Air. In: Rondia, D., Cooke, M., Haroz, R.K. (eds) Mobile Source Emissions Including Policyclic Organic Species. NATO ASI Series, vol 112. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7197-4_25
Download citation
DOI: https://doi.org/10.1007/978-94-009-7197-4_25
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-009-7199-8
Online ISBN: 978-94-009-7197-4
eBook Packages: Springer Book Archive