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Cadmium-113 Nuclear Magnetic Resonance Spectroscopy in Bioinorganic Chemistry. A Representative Spin 1/2 Metal Nuclide

  • Chapter
The Multinuclear Approach to NMR Spectroscopy

Part of the book series: NATO ASI Series ((ASIC,volume 103))

Abstract

The main theme of this chapter involves the utilization of 113Cd NMR spectroscopy to probe interesting structural and dynamic problems in inorganic and bioinorganic chemistry. Within the first portion of the chapter we have summarized most of the known 113Cd chemical shifts and coupling constants. Further, we have also presented introductory comments with regard to relaxation mechanisms and the importance of chemical dynamics. Subsequently, we discuss in detail the consequences that chemical dynamics have upon the interpretation of relaxation parameters and chemical shifts. The discussion then shifts to solid state NMR methods. Our recent work on cadmium-substituted porphyrins and 113Cd NMR of single crystals serve as examples. Finally, we bring all of these points into focus when we examine the utilization of cadmium as a surrogate probe for Ca+2 and Zn+2 in bioinorganic systems. Here, we have limited our discussion to our work on Concanavalin A and skeletal Troponin C.

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Authors and Affiliations

  1. Department of Chemistry, University of South Carolina, Columbia, South Carolina, 29208, USA

    Paul D. Ellis

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  1. Department of Chemistry, Northwestern University, Evanston, Illinois, USA

    Joseph B. Lambert

  2. Department of Chemistry, University of Stirling, Stirling, Scotland

    Frank G. Riddell

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Ellis, P.D. (1983). Cadmium-113 Nuclear Magnetic Resonance Spectroscopy in Bioinorganic Chemistry. A Representative Spin 1/2 Metal Nuclide. In: Lambert, J.B., Riddell, F.G. (eds) The Multinuclear Approach to NMR Spectroscopy. NATO ASI Series, vol 103. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7130-1_22

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