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Transition Metal NMR Spectroscopy

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The Multinuclear Approach to NMR Spectroscopy

Part of the book series: NATO ASI Series ((ASIC,volume 103))

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Abstract

Oxidation state is the variable exerting the largest influence on nuclear shielding of transition metal atoms. Sensitivity measured in dδ/d(oxidation state) units is linear for a given atom and undergoes modest increases from left to right and from top to bottom within the transition metal rectangle. The sensitivity for 59Co is anomalously high. The incidence of inverse halogen dependence is traced and attributed to the sign of the spin-orbit coupling constant. The σP = 0 standard state for absolute shielding of 59Co is located using the extrapolation technique.

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References

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Author information

Authors and Affiliations

  1. Faculty of Graduate Studies, The University of Western Ontario, London, Canada

    R. Garth Kidd

Authors
  1. R. Garth Kidd
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Northwestern University, Evanston, Illinois, USA

    Joseph B. Lambert

  2. Department of Chemistry, University of Stirling, Stirling, Scotland

    Frank G. Riddell

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© 1983 D. Reidel Publishing Company

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Kidd, R.G. (1983). Transition Metal NMR Spectroscopy. In: Lambert, J.B., Riddell, F.G. (eds) The Multinuclear Approach to NMR Spectroscopy. NATO ASI Series, vol 103. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7130-1_21

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  • DOI: https://doi.org/10.1007/978-94-009-7130-1_21

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-7132-5

  • Online ISBN: 978-94-009-7130-1

  • eBook Packages: Springer Book Archive

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