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High Resolution Solid-State NMR Studies of Group IV Elements

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The Multinuclear Approach to NMR Spectroscopy

Part of the book series: NATO ASI Series ((ASIC,volume 103))

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Abstract

The practical limitations of the high-power-decoupling/ cross-polarization/magic-angle-rotation suite of NMR techniques are discussed, with mention made of such matters as “dilution,” mobility, and physical state. Various types of information available from such solid-state NMR studies which distinguish them from solution work are listed. A number of examples of applications for 13C are reviewed, including questions of crystal symmetry, molecular conformation and motion, polymorphism, and tautomerism. Work on the silicon-29 nucleus, especially in studies of zeolites and related materials, is discussed and references given.

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References

  1. E. T. Lippmaa, M. A. Alla, T. J. Pehk, and G. Engelhardt, J. Am. Chem. Soc., 100, p. 1929 (1978).

    Article  Google Scholar 

  2. D. J. Burton, R. K. Harris, and L. H. Merwin, J. Magn. Reson., 39, p. 159 (1980).

    Google Scholar 

  3. K. W. Zilm, R. T. Conlin, D. M. Grant, and J. Michl, J. Am. Chem. Soc., 100, p. 8038 (1978).

    Article  Google Scholar 

  4. K. W. Zilm and D. M. Grant, J. Am. Chem. Soc., 103, p. 2913 (1981).

    Article  Google Scholar 

  5. A. N. Garroway, D. L. VanderHart, and W. L. Earl, Phil. Trans. Roy. Soc. A, 299, p. 609 (1981).

    Google Scholar 

  6. R. D. Kendrick, C. S. Yannoni, R. Aikman, and R. J. Lagow, J. Magn. Reson., 37, p. 555 (1980).

    Google Scholar 

  7. G. E. Balimann, C. J. Groombridge, R. K. Harris, K. J. Packer, B. J. Say, and S. F. Tanner, Phil. Trans. Roy. Soc. A, 299, p. 643 (1981).

    Article  Google Scholar 

  8. C. J. Groombridge, R. K. Harris, and K. J. Packer, unpublished work.

    Google Scholar 

  9. M. H. Frey and S. J. Opella, J. C. S. Chem. Commun., 474 (1980).

    Google Scholar 

  10. C. J. Groombridge, R. K. Harris, K. J. Packer, B. J. Say, and S. F. Tanner, J. C. S. Chem. Commun., 174 (1980).

    Google Scholar 

  11. C. D. Campbell, R. K. Harris, P. Jonsen, and K. J. Packer, unpublished work.

    Google Scholar 

  12. A. Naito, S. Ganapathy, and C. A. McDowell, J. Chem. Phys., 74, p. 5393 (1981).

    Article  Google Scholar 

  13. N. Zumbulyadis, P. M. Henrichs, and R. H. Young, J. Chem. Phys., 75, p. 1603 (1981).

    Article  Google Scholar 

  14. S. J. Opella, J. G. Hexem, M. H. Frey, and T. A. Cross, Phil. Trans. Roy. Soc. A, 299, p. 665 (1981).

    Article  Google Scholar 

  15. J. Schaefer, E. O. Stejskal, M. D. Sefcik, and R. A. McKay, Phil. Trans. Roy. Soc. A, 299, p. 593 (1981).

    Article  Google Scholar 

  16. C. J. Groombridge, R. K. Harris, and K. J. Packer, unpublished work.

    Google Scholar 

  17. M. B. Hursthouse, unpublished work.

    Google Scholar 

  18. R. A. Aujla, A. M. Chippendale, R. K. Harris, A. Mathias, and K. J. Packer, to be published.

    Google Scholar 

  19. A. Bunn, M. E. A. Cudby, R. K. Harris, K. J. Packer, and B. J. Say, J. C. S. Chem. Commun., p. 15 (1981).

    Google Scholar 

  20. P. Corradini, G. Natta, P. Ganis, and P. A. Temussi, J. Polym. Sci., C 16, p. 2477 (1967).

    Google Scholar 

  21. S. Neidle, I. M. Ismail, and P. J. Sadler, J. Inorg. Biochem. 13, p. 205 (1980).

    Article  Google Scholar 

  22. J. R. Lyerla, C. A. Fyfe, and C. S. Yannoni, J. Am. Chem. Soc., 101, p. 1351 (1979).

    Article  Google Scholar 

  23. W.-I. Shiau, E. N. Duesler, I. C. Paul, D. Y. Curtin, W. G. Blann, and C. A. Fyfe, J. Am. Chem. Soc., 102, p. 4546 (1980).

    Article  Google Scholar 

  24. W. G. Blann, C. A. Fyfe, J. R. Lyerla, and C. S. Yannoni, J. Am. Chem. Soc., 103, p. 4030 (1981).

    Article  Google Scholar 

  25. H. D. W. Hill, A. P. Zens, and J. Jacobus, J. Am. Chem. Soc., 101, p. 7090 (1979).

    Article  Google Scholar 

  26. R. K. Harris, A. M. Kenwright, K. J. Packer, R. A. Fletton, and G. I. Gregory, unpublished work.

    Google Scholar 

  27. C. A. Fyfe, J. R. Lyerla, W. Volksen, and C. S. Yannoni, Macromolecules, 12, p. 757 (1979).

    Article  Google Scholar 

  28. W. L. Earl and D. L. VanderHart, Macromolecules, 12, p. 762 (1979).

    Article  Google Scholar 

  29. R. S. Aujla, R. K. Harris, K. J. Packer, M. Parameswaran, B. J. Say, A. Bunn, and M. E. A. Cudby, Polymer Bull., 8, p. 253 (1982).

    Article  Google Scholar 

  30. G. R. Hays, The Analyst, 107, p. 241 (1982).

    Article  Google Scholar 

  31. C-H. Chiang, N-I. Liu, and J. L. Koenig, J. Colloid. Interfac. Sci., 86, p. 26 (1982).

    Article  Google Scholar 

  32. J. B. Lambert and J. S. Frye, Science, 217, p. 55 (1982).

    Article  Google Scholar 

  33. E. Lippmaa, M. Mägi, A. Samosan, G. Engelhardt, and A-R. Grimmer, J. Am. Chem. Soc., 102, p. 4889 (1980).

    Article  Google Scholar 

  34. G. Engelhardt, D. Zeigan, E. Lippmaa, and M. Mägi, Z. anorg. allgem. Chem., 468, p. 35 (1980).

    Article  Google Scholar 

  35. J. Klinowski, J. M. Thomas, C. A. Fyfe, and G. C. Gobbi, Nature, 296, p. 533 (1982).

    Article  Google Scholar 

  36. J. B. Nagy, J.-P. Gilson, and E. G. Derouane, J. C. S. Chem. Commun., p. 1129 (1981).

    Google Scholar 

  37. G. E. Maciel and D. W. Sindorf, J. Am. Chem. Soc., 102, p. 7606 (1980).

    Article  Google Scholar 

  38. E. Lippmaa and A. Samosan, Bruker Report No. 1, p. 6 (1982).

    Google Scholar 

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© 1983 D. Reidel Publishing Company

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Harris, R.K. (1983). High Resolution Solid-State NMR Studies of Group IV Elements. In: Lambert, J.B., Riddell, F.G. (eds) The Multinuclear Approach to NMR Spectroscopy. NATO ASI Series, vol 103. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7130-1_17

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  • DOI: https://doi.org/10.1007/978-94-009-7130-1_17

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-7132-5

  • Online ISBN: 978-94-009-7130-1

  • eBook Packages: Springer Book Archive

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