Abstract
As a low-abundance, quadrupolar nucleus, 17O has often been overlooked as a viable NMR nucleus for structure determination. The 17O nucleus has, however, proved to be a surprisingly convenient nucleus for study by NMR techniques due to the availability of water and dioxygen enriched in 17O and the relatively small magnitude of the 17O quadrupole moment. This chapter focuses on two practical aspects of 17O NMR spectroscopy. First, methods for optimizing sensitivity and resolution are outlined. Correlations between chemical shift and structural environment are then presented in the context of examples selected from the organometallic, organic, inorganic, and biochemical literature.
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Klemperer, W.G. (1983). Application of 17O NMR Spectroscopy to Structural Problems. In: Lambert, J.B., Riddell, F.G. (eds) The Multinuclear Approach to NMR Spectroscopy. NATO ASI Series, vol 103. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7130-1_11
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DOI: https://doi.org/10.1007/978-94-009-7130-1_11
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