Skip to main content
SpringerLink
Log in
Book cover

The Multinuclear Approach to NMR Spectroscopy pp 207–244Cite as

Nitrogen Nuclear Magnetic Resonance Spectroscopy

  • Chapter

Part of the book series: NATO ASI Series ((ASIC,volume 103))

Abstract

Experimental aspects associated with the two magnetic isotopes of nitrogen, 14N (natural abundance = 99.6%, spin quantum number = 1) and 15N (natural abundance = 0.4%, spin quantum number = 1/2) are discussed briefly. General relationships of molecular structure to nitrogen chemical shifts and spin-spin coupling constants involving 15N are presented. The utility of nitrogen NMR for examining molecular dynamics is described. Illustrations are provided that are chosen largely from organic and biochemistry.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J. D. Ray and R. A. Ogg, Jr., J. Chem. Phys. 26, pp. 1452–1454 (1957).

    Article  Google Scholar 

  2. B. E. Holder and M. P. Klein, J. Chem. Phys., 23, p. 1956 (1955).

    Article  Google Scholar 

  3. B. M. Schmidt, L. C. Brown, and D. Williams, J. Mol. Spectrosc., 2, pp. 539–550, 551-558 (1958); J. Mol. Spectrosc, 3, pp. 30-35 (1959).

    Google Scholar 

  4. D. H. Evans and R. E. Richards, Mol. Phys., 8, pp. 19–31 (1964).

    Article  Google Scholar 

  5. M. Bose, N. Das, and N. Chatterjee, J. Mol. Spectrosc., 18, pp. 32–40 (1965).

    Article  Google Scholar 

  6. M. Witanowski, T. Urbanski, and L. Stefaniak, J. Am. Chem. Soc., 86, pp. 2569–2570 (1964).

    Article  Google Scholar 

  7. G. C. Levy and R. L. Lichter, “Nitrogen-15 Nuclear Magnetic Resonance Spectroscopy,” Wiley-Interscience, New York, 1979.

    Google Scholar 

  8. M. Witanowski, L. Stefaniak, and G. A. Webb, Ann. Rep. NMR Spectrosc., 11B, (1981).

    Google Scholar 

  9. G. J. Martin, M. C. Martin, and J. P. Gouesnard, NMR-Basic Prin. Progr., 18, (1981).

    Google Scholar 

  10. J. Mason, Chem. Rev., 81, pp. 205–227 (1981).

    Article  Google Scholar 

  11. K. Kanamori and J. D. Roberts, Acc. Chem. Res., in press.

    Google Scholar 

  12. J. M. Lehn and J. P. Kintzinger, in “Nitrogen NMR,” M. Witanowski and G. A. Webb, Eds., Plenum Press, London, 1973, pp. 79–161.

    Chapter  Google Scholar 

  13. G. A. Morris, J. Am. Chem. Soc., 102, pp. 428–429 (1980).

    Article  Google Scholar 

  14. W. Städeli, P. Bigler, and W. von Philipsborn, Org. Magn. Reson., 16, pp. 170–172 (1981).

    Article  Google Scholar 

  15. G. C. Levy, T. Pehk, and P. R. Srinivasan, Org. Magn. Reson., 14, pp. 129–132 (1980).

    Article  Google Scholar 

  16. M. Witanowski, L. Stefaniak, S. Szymanski, and H. Januszewski, J. Magn. Reson., 28, pp. 217–226 (1977).

    Google Scholar 

  17. P. R. Srinivasan and R. L. Lichter, ibid., 28, pp. 227–231 (1977).

    Google Scholar 

  18. R. O. Duthaler and J. D. Roberts, J. Am. Chem. Soc., 100, pp. 3889–3895 (1980).

    Article  Google Scholar 

  19. R. O. Duthaler, K. L. Williamson, D. D. Giannini, W. H. Bearden, and J. D. Roberts, J. Am. Chem. Soc., 99, pp. 8406–8414 (1977).

    Article  Google Scholar 

  20. F. W. Vierhapper, G. T. Furst, S. N. Y. Fanso-Free, E. L. Eliel, and R. L. Lichter, J. Am. Chem. Soc., 103, pp. 5629–5633 (1981).

    Article  Google Scholar 

  21. G. C. Levy, T. Pehk, and E. Lippmaa, Org. Magn. Reson., 14, pp. 214–219 (1980).

    Article  Google Scholar 

  22. M. P. Sibi and R. L. Lichter, J. Org. Chem., 42, pp. 2999–3004 (1977)

    Article  Google Scholar 

  23. E. Prince, J. LeMelle, and R. L. Lichter, unpublished results.

    Google Scholar 

  24. K. Crimaldi, R. L. Lichter, and A. D. Baker, J. Org. Chem., 42, pp. 3524–3528 (1982).

    Article  Google Scholar 

  25. G. J. Martin, T. Bertrand, D. LeBotlan, and J. M. LeTourneux, J. Chem. Res. (S), pp. 408–409 (1979).

    Google Scholar 

  26. M. J. Kamlet, C. Dickinson, and R. W. Taft, J. Chem. Soc Perkin 2, pp. 353–355 (1981).

    Article  Google Scholar 

  27. I. I. Schuster and J. D. Roberts, J. Org. Chem., 45, pp. 284–287 (1980).

    Article  Google Scholar 

  28. O. W. Sørensen, S. Scheibye, S. O. Lawesson, and H. J. Jakobsen, Org. Magn. Reson., 16, pp. 322–324 (1981).

    Article  Google Scholar 

  29. G. J. Martin, J. P. Gouesnard, J. Dorie, C. Rabiller, and M. L. Martin, J. Am. Chem. Soc., 99, pp. 1381–1384 (1977).

    Article  Google Scholar 

  30. J. Dorie, J. P. Gouesnard, C. Rabiller, B. Mechin, N. A. Naulet, and G. J. Martin, Org. Magn. Reson., 13, pp. 126–131 (1980).

    Article  Google Scholar 

  31. M. Witanowski, L. Stefaniak, and G. A. Webb, Org. Magn. Reson., 16, pp. 309–311 (1981).

    Article  Google Scholar 

  32. W. Städeli and W. von Philipsbom, Org. Magn. Reson., 15, pp. 106–109 (1981).

    Article  Google Scholar 

  33. W. Städeli, W. von Philipsborn, A. Wick, and I. Kompis, Helv. Chim. Acta, 63, pp. 504–522 (1980).

    Article  Google Scholar 

  34. M. Witanowski, L. Stefaniak, B. N. Lamphun, and G. A. Webb, Org. Magn. Reson., 16, pp. 57–59 (1981).

    Article  Google Scholar 

  35. D. J. Craik, G. C. Levy, and R. T. C. Brownlee, submitted for publication and private communication.

    Google Scholar 

  36. S. Bulusu, T. Axenrod, and J. Autera, Org. Magn. Reson., 16, pp. 52–56 (1981).

    Article  Google Scholar 

  37. J. P. Gouesnard and G. J. Martin, Org. Magn. Reson., 12, pp. 263–270 (1979).

    Article  Google Scholar 

  38. N. Naulet and G. J. Martin, Tetrahedron Lett., pp. 1493–1496 (1979).

    Google Scholar 

  39. A. Lyčka, D. Šnobl, V. Machaček, and M. Večeřa, Org. Magn. Reson., 16, pp. 17–19 (1981).

    Article  Google Scholar 

  40. D. M. Kanjia, J. Mason, I. A. Stenhouse, R. E. Banks, and N. D. Venayak, J. Chem. Soc. Perkin 2, pp. 975–979 (1981).

    Article  Google Scholar 

  41. H. J. Jakobsen and W. S. Brey, J. Am. Chem. Soc., 101, pp. 774–775 (1979).

    Article  Google Scholar 

  42. O. W. Sørensen, S. Scheibye, S.-O. Lawesson, and H. J. Jakobsen, Org. Magn. Reson., 16, pp. 322–324 (1981).

    Article  Google Scholar 

  43. H. J. Jakobsen and S. Deshmukh, J. Magn. Reson., 42, pp. 337–340 (1981).

    Google Scholar 

  44. G. Binsch, J. B. Lambert, B. W. Roberts, and J. D. Roberts, J. Am. Chem. Soc., 86, pp. 5564–5568 (1964).

    Article  Google Scholar 

  45. D. Crepaux and J. M. Lehn, Mol. Phys., 14, pp. 547–550 (1968).

    Article  Google Scholar 

  46. A. Danoff, M. Franzen-Sieveking, R. Lichter, and S. N. Y. Fanso-Free, Org. Magn. Reson., 12, pp. 83–86 (1979).

    Article  Google Scholar 

  47. D. R. Boyd, M. E. Stubbs, N. J. Thompson, H. J. C. Yeh, D. M. Jerina, and R. E. Wasylishen, Org. Magn. Reson., 14, pp. 528–533 (1980).

    Article  Google Scholar 

  48. W. Städeli, P. Bigler, and W. von Philipsborn, Org. Magn. Reson., 16, pp. 170–172 (1981).

    Article  Google Scholar 

  49. V. F. Bystrov, Y. D. Favrilov, and V. N. Solkan, J. Magn. Reson., 19, pp. 123–126 (1975).

    Google Scholar 

  50. A. J. Fishman, D. H. Live, H. R. Wyssbrod, W. C. Agosta, and D. Cowburn, J. Am. Chem. Soc., 102, pp. 2533–2539 (1980).

    Article  Google Scholar 

  51. A. DeMarco and M. Llinas, Org. Magn. Reson., 12, pp. 454–460 (1979).

    Article  Google Scholar 

  52. R. E. Wasylishen, Ann. Rep. NMR Spectrosc., 7, pp. 245–291 (1977).

    Article  Google Scholar 

  53. J. M. Schulman and T. Venanzi, J. Am. Chem. Soc., 98, pp. 4701–4705, 6739-6741 (1976).

    Article  Google Scholar 

  54. R. Siegel, K. Crimaldi, R. Lichter, and J. Schulman, J. Phys. Chem., 85, p. 4157 (1981).

    Article  Google Scholar 

  55. V. N. Solkan and V. F. Bystrov, Bull. Acad. Sci. USSR, Div. Chem. Sci., 23, pp. 95–97 (1975).

    Article  Google Scholar 

  56. R. E. London, T. E. Walker, T. W. Whaley, and N. A. Matwiyoff, Org. Magn. Reson., 9, pp. 598–602 (1978).

    Article  Google Scholar 

  57. J. M. Schulman, J. Ruggio, and T. J. Venanzi, J. Am. Chem. Soc., 99, pp. 2045–2048 (1977).

    Article  Google Scholar 

  58. A. Lyčka and D. Šnobl, Coll. Czech. Chem. Comm., 46, pp. 892–897 (1981).

    Article  Google Scholar 

  59. T. Khin, S. Duangthai, and G. A. Webb, Org. Magn. Reson., 13, pp. 240–243 (1980).

    Article  Google Scholar 

  60. H. J. Jakobsen and W. S. Brey, J. Chem. Soc. Chem. Commun., pp. 478–479 (1979).

    Google Scholar 

  61. M. P. Sibi and R. L. Lichter, Org. Magn. Reson., 14, pp. 494–498 (1980).

    Article  Google Scholar 

  62. R. J. Gillespie and R. Hulme, J. Chem. Soc. Dalton Trans., pp. 1261–1267 (1973).

    Google Scholar 

  63. J. H. Hargis, W. B. Jennings, S. D. Worley, and M. S. Tolley, J. Am. Chem. Soc., 102, pp. 13–17 (1980).

    Article  Google Scholar 

  64. G. W. Buchanan, F. G. Morin, and R. R. Fraser, Can. J. Chem., 58, pp. 2442–2446 (1980).

    Article  Google Scholar 

  65. J. R. Lyerla, Jr., and G. C. Levy, Top. Carbon-13 NMR Spectrosc. 1, pp. 79–148 (1974).

    Google Scholar 

  66. T. L. James and A. Lapidot, J. Am. Chem. Soc., 103, pp. 6748–6750 (1981).

    Article  Google Scholar 

  67. P. B. Dervan, M. E. Squillacote, P. M. Lahti, A. P. Sylvester, and J. D. Roberts, J. Am. Chem. Soc., 103, pp. 1120–1122 (1981).

    Article  Google Scholar 

  68. H. Nakanishi, A. Yabe, and K. Honda, J. Chem. Soc. Chem. Commun., pp. 86–87 (1982).

    Google Scholar 

  69. R. E. Botto, J. H. Schwartz, and J. D. Roberts, Proc. Natl. Acad. Sci. USA, 77, pp. 23–25 (1980).

    Article  Google Scholar 

  70. W. E. Hull and H. R. Kricheldorf, Liebigs Ann. Chem., pp. 158–164 (1980).

    Google Scholar 

  71. Y. Nomuro and Y. Takeuchi, J. Chem. Soc. Chem. Commun., pp. 295–296 (1979).

    Google Scholar 

  72. F. W. Vierhapper, G. T. Furst, and R. L. Lichter, Org. Magn. Reson., 17, pp. 127–130 (1981).

    Article  Google Scholar 

  73. G. E. Hawkes, E. W. Randall, W. E. Hull, and O. Convert, Biopolymers, 19, pp. 1815–1826 (1980).

    Article  Google Scholar 

  74. C. Garbay-Jaureguiberry, J. Baudet, D. Florentin, and B. P. Roques, FEBS Letters, 115, pp. 315–318 (1980).

    Article  Google Scholar 

  75. H. R. Kricheldorf and W. E. Hull, Org. Magn. Reson., 12, pp. 607–611 (1979).

    Article  Google Scholar 

  76. C. D. Poulter and C. L. Livingston, Tetrahedron Lett., pp. 755–758 (1979).

    Google Scholar 

  77. C. Dyllick-Brenzinger, G. R. Sullivan, P. P. Pang, and J. O. Roberts, Proc. Natl. Acad. Sci. USA, 77, pp. 5580–5582 (1980).

    Article  Google Scholar 

  78. W. Bachovchin and J. D. Roberts, J. Am. Chem. Soc., 100, pp. 8041–8048 (1978).

    Article  Google Scholar 

  79. W. Bachovchin, K. Kanamori, B. L. Vallee, and J. D. Roberts, Biochemistry, 21, pp. 2885–2892 (1982).

    Article  Google Scholar 

  80. T. L. Legerton, K. Kanamori, R. L. Weiss, and J. D. Roberts, Proc. Natl. Acad. USA, 78, pp. 1495–1498 (1981).

    Article  Google Scholar 

  81. N. C. Gonnella and J. D. Roberts, J. Am. Chem. Soc., 104, pp. 3162–3164 (1982).

    Article  Google Scholar 

  82. M. A. Alei, Jr., L. O. Morgan, W. E. Wageraan, and T. W. Whaley, J. Am. Chem. Soc., 102, 2881–2887 (1980).

    Article  Google Scholar 

  83. N. J. Oppenheimer and R. M. Davidson, Org. Magn. Reson., 13, pp. 14–16 (1980).

    Article  Google Scholar 

  84. G. Burton, P. E. Fagerness, P. M. Jordan, and A. I. Scott, Tetrahedron, 36, pp. 2721–2725 (1980).

    Article  Google Scholar 

  85. A. I. Scott, G. Burton, P. M. Jordan, H. Matsumoto, P. E. Fagerness, and L. M. Pryde, J. Chem. Soc. Chem. Commun., pp. 384–387 (1980).

    Google Scholar 

  86. H. R. Kricheldorf, Pure Appl. Chem., 54, pp. 467–481 (1982).

    Article  Google Scholar 

  87. H. R. Kricheldorf and W. E. Hull, Makromol. Chem., 182, pp. 1177–1196 (1981).

    Article  Google Scholar 

  88. Macromolecules, 13, pp. 87-95 (1980).

    Google Scholar 

  89. B. S. Holmes, G. C. Chingas, W. B. Moniz, and R. E. Ferguson, Macromolecules, 14, pp. 1785–1787 (1981).

    Article  Google Scholar 

  90. R. D. Bertrand, W. B. Moniz, A. N. Garroway, and G. C. Chingas, J. Am. Chem. Soc., 100, pp. 5227–5229 (1978).

    Article  Google Scholar 

  91. J. Magn. Reson., 32, pp. 465-467 (1978).

    Google Scholar 

  92. W. E. Hull, E. Bullesbach, H.-J. Wieneke, H. Zahn, and H. R. Kricheldorf, Org. Magn. Reson., 17, pp. 92–96 (1981).

    Article  Google Scholar 

  93. J. Schaefer and E. O. Stejskal, Top. Carbon-13 NMR Spectrosc., 3, pp. 283–342 (1979).

    Google Scholar 

  94. J. Schaefer, E. O. Stejskal, and R. A. McKay, Biochem. Biophys. Res. Commun., 88, pp. 274–280 (1979).

    Article  Google Scholar 

  95. T. A. Skokut, J. E. Varner, J. Schaefer, E. O. Stejskal, and R. A. McKay, Plant Physiol., 69, pp. 314–316 (1982).

    Article  Google Scholar 

  96. G. C. Jacob, J. Schaefer, E. O. Stejskal, and R. A. McKay, Biochem. Biophys. Res. Commun., 97, pp. 1176–1182 (1980).

    Article  Google Scholar 

  97. M. Munowltz, W. W. Bachovchin, J. Herzfeld, C. M. Dobson, and R. G. Griffin, J. Am. Chem. Soc., 104, pp. 1192–1196 (1982).

    Article  Google Scholar 

  98. J. Schaefer, E. O. Stejskal, G. S. Jacob, and R. A. McKay, Appl. Spectrosc., 36, pp. 179–182 (1982).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Hunter College of CUNY, New York, NY, 10021, USA

    Robert L. Lichter

Authors
  1. Robert L. Lichter
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Chemistry, Northwestern University, Evanston, Illinois, USA

    Joseph B. Lambert

  2. Department of Chemistry, University of Stirling, Stirling, Scotland

    Frank G. Riddell

Rights and permissions

Reprints and permissions

Copyright information

© 1983 D. Reidel Publishing Company

About this chapter

Cite this chapter

Lichter, R.L. (1983). Nitrogen Nuclear Magnetic Resonance Spectroscopy. In: Lambert, J.B., Riddell, F.G. (eds) The Multinuclear Approach to NMR Spectroscopy. NATO ASI Series, vol 103. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7130-1_10

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-7130-1_10

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-7132-5

  • Online ISBN: 978-94-009-7130-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation