Skip to main content
SpringerLink
Log in

Selectivity and Ion Speciation in Cation-Exchange Resins

  • Chapter
Book cover Mass Transfer and Kinetics of Ion Exchange

Part of the book series: NATO ASI Series ((NSSE,volume 71))

  • 475 Accesses

Abstract

The development of a model for the prediction of ion-exchange selectivity has been described in detail. Cation-exchange selectivity in aqueous media is shown to be determined by the difference in interaction of various cations with water. The difference in selectivity is resolvable through the analysis of osmotic coefficient data obtained for the pure ionic forms of the linear polyelectrolyte analogue of the cross-linked cation exchange resin. The utility of this approach has been tested and is shown to be applicable to a weakly dissociated cation-exchange resin as well as to the fully dissociated one. The insight gained from this study is believed to be useful to the analysis of mass transport phenomena in cation-exchange materials.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Gregor, H. P. J. Amer. Chem. Soc., 70, (1948) 1293.

    Article  CAS  Google Scholar 

  2. Gregor, H. P., ibid., 73, (1951) 642.

    Google Scholar 

  3. Ekedahl, E., Hogfeldt, E. and Sillen, L. G., Acta Chim. Scand., 4, (1950) 556.

    Article  CAS  Google Scholar 

  4. Hogfeldt, E., Ekedahl, E. and Sillen, L. G., ibid., 4, (1950) 828.

    Google Scholar 

  5. Bonner, O. D., Argersinger, W. J., Jr. and Davidson, A. W., J. Amer. Chem. Soc., 74, (1952) 1044.

    Article  CAS  Google Scholar 

  6. Glueckauf, E., Proc. Roy. Soc., Ser. A, 214, (1952) 207.

    Article  CAS  Google Scholar 

  7. Duncan, J. F., Aust. J. Chem., 8, (1955) 293.

    Article  CAS  Google Scholar 

  8. Soldano, B. and Chestnut, D., J. Amer. Chem. Soc., 77, (1955) 1334.

    Article  CAS  Google Scholar 

  9. Myers, G. E. and Boyd, G. E., J. Phys. Chem., 60, (1956) 521.

    Article  CAS  Google Scholar 

  10. Boyd, G. E., Lindenbaum, S. and Myers, G. E., ibid., 65, (1961) 577.

    Google Scholar 

  11. Feitelson, J., ibid., 66, (1962) 1295.

    Google Scholar 

  12. Marinsky, J. A., ibid., 71, (1967) 1572.

    Google Scholar 

  13. Helfferich, F., “Ion Exchange”, McGraw-Hill, New York (1962).

    Google Scholar 

  14. Donnan, F. G. and Guggenheim, E. A., Z. Physik. Chem. (Leipzig) 162A, (1932) 356

    Google Scholar 

  15. Donnan, F. G., ibid., 168A, (1934) 369.

    Google Scholar 

  16. Bukata, S. and Marinsky, J. A., J. Phys. Chem., 68, (1964) 994.

    Article  CAS  Google Scholar 

  17. Robinson, R. A. and Stokes, R. H., “Electrolyte Solutions”, 2nd ed., Butterworth Scientific Publications, London (1959).

    Google Scholar 

  18. Robinson, R. A., J. Phys. Chem., 65, (1961) 662.

    Article  CAS  Google Scholar 

  19. Soldano, B. and Larson, Q. V., J. Amer. Chem. Soc., 77, (1955) 1331.

    Article  CAS  Google Scholar 

  20. Soldano, B., Larson, Q. V. and Myers, G. S., ibid., 77, (1955) 1339.

    Google Scholar 

  21. Reddy, M. M., Marinsky, J. A. and Sarkar, A., J. Phys. Chem., 74, (1970) 3891.

    Article  Google Scholar 

  22. Reddy, M. M. and Marinsky, J. A., ibid., 74, (1970) 3884.

    Google Scholar 

  23. Reddy, M. M. and Marinsky, J. A., J. Macromol. Sci-Phys., B5(1), (1971) 135.

    Article  Google Scholar 

  24. Reddy, M. M., Amdur, S. and Marinsky, J. A., J. Amer. Chem. Soc., 94, (1972) 4087.

    Article  CAS  Google Scholar 

  25. Marinsky, J. A., Reddy, M. M. and Amdur, S., J. Phys. Chem., 77, (1973) 2128.

    Article  CAS  Google Scholar 

  26. Yang, R. and Marinsky, J. A., J. Phys. Chem., 83, (1979) 2737.

    Article  CAS  Google Scholar 

  27. Manning, G. S., J. Chem. Phys., 51, (1969) 924, 3249.

    Article  CAS  Google Scholar 

  28. Boyd, G. E. and Bunzl, K., J. Amer. Chem. Soc., 96 (1974) 2054.

    Article  CAS  Google Scholar 

  29. Baldwin, R., Ph.D. Thesis., State University of New York at Buffalo, Buffalo, NY, 1978.

    Google Scholar 

  30. Linderstrøm-Lang, Compt. Rend. Trav. Lab, Carlsberg, l5, (1924) No. 7.

    Google Scholar 

  31. Scatchard, G., Ann. N.Y. Acad. Sci., 51, (1949) 660.

    Article  CAS  Google Scholar 

  32. Tanford, C., J. Amer. Chem. Soc., 72, (1950) 441.

    Article  CAS  Google Scholar 

  33. Arnold, R. and Overbeek, J. Th. G., Rec. Trav. Chim. Phys.- Bas, 69, (1950) 592.

    Google Scholar 

  34. Nagasawa, M. and Holtzer, A., J. Am. Chem. Soc., 86, (1964) 538.

    Article  CAS  Google Scholar 

  35. Travers, L. and Marinsky, J. A., J. Polymer. Sci., Symposium No. 47, (1974) 285.

    Google Scholar 

  36. Marinsky, J. A. and Hogfeldt, E., Chemica Scripta, 9, (1976) 233.

    CAS  Google Scholar 

  37. Marinsky, J. A., J. Chromatography, 201, (1980) 5.

    Article  CAS  Google Scholar 

  38. Marinsky, J. A., Reddy, M. M. and Baldwin, R. S., “Water in Polymers”, ACS Symposium Series No. 127, Amer. Chem. Soc., edited by S. P. Rowland, (1980) 387.

    Chapter  Google Scholar 

  39. Boyd, G. E., Myers, G. E. and Lindenbaum, S., J. Phys. Chem., 78, (1974) 110.

    Google Scholar 

  40. The data for Fig. 12 are from Marinsky, J. A., Bunzl, K. and Wolf, A., Talanta, 27, (1980) 461–8.

    Article  CAS  Google Scholar 

  41. Slota, P. and Marinsky, J. A., “Ions in Polymers”, ACS Symposium Series No. 187, Amer. Chem. Soc., edited by A. Eisenberg, (1980) 313.

    Chapter  Google Scholar 

  42. Mukherjee, P., J. Phys. Chem., 65, (1961) 740.

    Article  Google Scholar 

  43. Gekko, K. and Nozuchi, H., Biopolymers, 14, (1975) 2555.

    Article  CAS  Google Scholar 

  44. Merle, Y. and Marinsky, J. A., presented for publication in Talanta (1982).

    Google Scholar 

  45. Marinsky, J. A. and Anspach, W. M., J. Phys. Chem., 79, (1975) 433.

    Article  Google Scholar 

  46. Marinsky, J. A. and Anspach, W. M., J. Phys. Chem., 79, (1975) 439.

    Article  CAS  Google Scholar 

  47. Marinsky, J. A., Coord. Chem. Rev., 19, (1976) 125.

    Article  CAS  Google Scholar 

  48. Marinsky, J. A., J. Phys. Chem., 86, (1982) 0000.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, State University of New York at Buffalo, Buffalo, New York, 14214, USA

    Jacob A. Marinsky

Authors
  1. Jacob A. Marinsky
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. University of Bari, Italy

    Lorenzo Liberti (Senior Researcher at the Water Research Institute of the National Research Council of Italy Associate Professor of Industrial Chemistry at the Faculty of Engineering) (Senior Researcher at the Water Research Institute of the National Research Council of Italy Associate Professor of Industrial Chemistry at the Faculty of Engineering)

  2. Pennsylvania State University, University Park, PA, 16802, USA

    Friedrich G. Helfferich (Professor of Chemical Engineering) (Professor of Chemical Engineering)

Rights and permissions

Reprints and permissions

Copyright information

© 1983 Martinus Nijhoff Publishers, The Hague

About this chapter

Cite this chapter

Marinsky, J.A. (1983). Selectivity and Ion Speciation in Cation-Exchange Resins. In: Liberti, L., Helfferich, F.G. (eds) Mass Transfer and Kinetics of Ion Exchange. NATO ASI Series, vol 71. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6899-8_4

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-6899-8_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-6901-8

  • Online ISBN: 978-94-009-6899-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation