Skip to main content
SpringerLink
Log in

Dielectric Polarization and Relaxation

  • Chapter
Molecular Liquids

Part of the book series: NATO ASI Series ((ASIC,volume 135))

Abstract

A review of field quantities and formal results is followed by discussion of equilibrium theories and simulations for polar liquids. Relaxation processes are considered primarily in terms of correlation function treatments, starting with models of behavior in simple systems and going on to cooperative behavior in more complex systems as a function of temperature, with some reference to polymers and molecular crystals. Other aspects discussed include correlation functions from transient birefringence, ion-solvent interaction effects in electrolytes and relaxation in mixtures of polar liquids.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Jackson, J.D. 1975, ‘Classical Electrodynamics,’2nd Ed. ( Wiley, New York ), pp. 226–235.

    MATH  Google Scholar 

  2. Buckingham, A.D., Disch, R. 1963, Proc. Roy. Soc. (London) A273. pp. 275–280.

    Google Scholar 

  3. Van Vleck, J.H. 1932, ‘Theory of Electric and Magnetic Susceptibilities’ (Oxford)

    Google Scholar 

  4. Kubo, R. 1957, 1. J. Phys. Soc. Japan 12, pp. 570–586.

    Google Scholar 

  5. Glarum, S.H. 1960, J. Chem. Phys. 33, pp. 1371–1375.

    Article  MathSciNet  ADS  Google Scholar 

  6. Cole, R.H. 1965. J. Chem. Phys. 42, pp. 637–643.

    Article  MathSciNet  ADS  Google Scholar 

  7. Lorentz. H.A. 1909, ‘The Theory of Electrons’ ( Teubuer, Leipzig).

    Google Scholar 

  8. Van Vleck, J.H. 1937, J. Chem. Phys. 5, pp. 556–568.

    Article  ADS  Google Scholar 

  9. Cole, R.H. 1957, J. Chem. Phys. 27, pp. 33–35.

    Article  MathSciNet  ADS  Google Scholar 

  10. Toupin, R.A., Lax, M. 1957, J. Chem. Phys. 27. pp. 458–464.

    Google Scholar 

  11. Cole, R.H. 1963, J. Chem. Phys. 39, pp. 2602–2609.

    Article  ADS  Google Scholar 

  12. Onsager, L. 1936, J. Am. Chem. Soc. 58, pp. 1486–1493.

    Article  Google Scholar 

  13. Böttcher, C.J.F. 1973, ‘Theory of Electric Polarization’. 2nd Ed., Vol. I, ‘Dielectric in Static Fields’, completely revised by van Belle, O.C., Bordewijk, P., Rip, A. ( Elsevier, Amsterdam).

    Google Scholar 

  14. See Ref. (13) for details.

    Google Scholar 

  15. C. Brot, personal communication.

    Google Scholar 

  16. Kirkwood. J. G. 1939, J. Chem. Phys. 7, pp. 911–919.

    Google Scholar 

  17. Frohlich, H. 1956, Physics 22, pp. 898–904.

    Google Scholar 

  18. Fulton, R.L. 1975, Mol. Phys. 29, pp. 405–413.

    Article  MathSciNet  ADS  Google Scholar 

  19. Felderhof, B.U. 1977, J. Chem. Phys. 67, pp. 493–500; Titulaer, U.M., Felderhof, B.U. 1977, J. Chem. Phys. 67, pp. 3126–3132

    Article  ADS  Google Scholar 

  20. Fulton, R.L. 1983, J. Chem. Phys. 78, pp. 6865–6876, 6877–6884.

    Google Scholar 

  21. Buckingham, A.D., Pople, J.A. 1956, Discuss, Far, Soc. 22, p. 17.

    Article  Google Scholar 

  22. Sutter, H. 1972, ‘Dielectric and Related Molecular Processes’ Vol. I, M. Davies. Senior Reporter (Chem. Soc. London ) pp. 64–99.

    Google Scholar 

  23. Copeland, T.G., Cole, R.H. 1976, J. Chem. Phys. 64, pp. 1741–1746.

    Article  ADS  Google Scholar 

  24. Van Vleck, J.H. 1937, J. Chem. Phys. 5, pp. 356–568.

    Google Scholar 

  25. Rosenberg, R., Lax, M. 1953. J. Chem. Phys. 21, pp. 424–428.

    Article  ADS  Google Scholar 

  26. Cole, R.H. 1963, J. Chem. Phys. 39, pp. 2603–2609.

    ADS  Google Scholar 

  27. Toupin, R.A., Lax, M. 1957, J. Chem. Phys. 27, pp.. 458–464.

    Google Scholar 

  28. Nienhuis, G., Deutch, J.M. 1972, J. Chem. Phys. 56, pp. 235–247, pp. 1819–1834.

    Google Scholar 

  29. Wertheim, M.S. 1971, J. Chem. Phys. 55. pp. 4291–4298.

    Article  ADS  Google Scholar 

  30. Wertheim, M.S. 1979, Ann. Rev. Phys. Chem. 30, pp 471–501.

    Article  ADS  Google Scholar 

  31. Berkowitz, M., Adelman, S.A. 1980, J. Chem. Phys. 72, pp 4796 – 4798.

    ADS  Google Scholar 

  32. Patey, G.N., Valleau, J.P. 1976, J. Chem. Phys. 64, pp. 170–184.

    Article  ADS  Google Scholar 

  33. Carnie, S.L., Patey, G.N. 1982, Mol. Phys. 47, pp. 1129–1154.

    Article  ADS  Google Scholar 

  34. Alder, B. J., Pollock, E. L. 1981, Ann. Rev. Phys. Chem. 32, pp. 311–330.

    Article  ADS  Google Scholar 

  35. Bossis, G., Quentrec, B., Brot, C. 1980, Mol. Phys. 39, pp. 1233–1249.

    Article  ADS  Google Scholar 

  36. Pollock, E.L., Alder, B.J. 1980, Physica 102A, pp. 1–21.

    Article  Google Scholar 

  37. Patey, G.N., Levesque, D., Weis, J. J. 1979, Mol. Phys. 38, pp. 1635 - 1654.

    Article  ADS  Google Scholar 

  38. Patey, G.N., Levesque, D., Weis, J.J. 1982, Mol. Phys. 45, pp. 733–746.

    Article  ADS  Google Scholar 

  39. Brot, C., Darmon, I. 1970, J. Chem. Phys. 53, pp. 2271–2280.

    Article  ADS  Google Scholar 

  40. Cole, R.H. 1983, IEEE Trans. Instrum. Meas. IM–32, pp. 42– 47.

    Google Scholar 

  41. Van Vleck, J.H., Weisskopf, V.F. 1945, Rev. Mod. Phys. 17, pp. 227–236.

    Article  ADS  Google Scholar 

  42. Titulaer, U.M., Deutch, J.M. 1974, J. Chem. Phys. 60, pp. 1502–1513.

    Article  ADS  Google Scholar 

  43. Fulton. R.L. 1975, J. Chem. Phys. 62, pp. 4355–4359.

    Article  ADS  Google Scholar 

  44. Fatuzzo, E., Mason, P.R. 1967, Proc. Phys. Soc. 90, ppl. 729–741.

    Google Scholar 

  45. Cole, R.H. 1938, J. Chem. Phys. 6, pp. 385–391.

    Article  ADS  Google Scholar 

  46. Vaughan. W. 1979, Ann. Rev. Phys. Chem. 30, pp. 103–124.

    Article  ADS  Google Scholar 

  47. Berne, B.J. 1975, J. Chem. Phys. 62, pp. 1154–1160.

    Article  ADS  Google Scholar 

  48. Böttcher, C.J.F., Bordewijk, P. 1978, ‘Theory of Electric Polarization’, 2nd Ed., Vol. I I ( Elsevier, Amsterdam ).

    Google Scholar 

  49. Buckley, F., Maryott, A.A. 1954, J. Res. Nat’l. Bur. Std. 53, pp. 229–234.

    MATH  Google Scholar 

  50. Gerschel, A. Brot, C., Dimicoli, I., Rion, A. 1977, Mol. Phys. 33, pp. 527–541.

    Article  ADS  Google Scholar 

  51. Hoffman, J.D. 1955, J. Chem. Phys. 23, pp. 1331–1339.

    Article  ADS  Google Scholar 

  52. Davidson. D.W., Cole, R.H. 1951, J. Chem. Phys. 19, pp. 1484–1490.

    Article  ADS  Google Scholar 

  53. Williams, G., Watts, D.C. 1970, Trans. Far. Soc. 66, pp. 80–85.

    Article  Google Scholar 

  54. Denney, D.J. 1957, J. Chem. Phys. 27, pp. 259–264.

    Google Scholar 

  55. Cole, K. S., Cole, R.H. 1941, J. Chem. Phys. 9, pp. 341–351.

    Article  ADS  Google Scholar 

  56. Havriliak, S., Negami, S. 1966, J. Polymer Sci. C14, p. 99.

    Google Scholar 

  57. Colonomos, P., Gordon, R.G. 1979, J. Chem. Phys. 91, pp. 1159–1166.

    Article  ADS  Google Scholar 

  58. Glarum, S.H. 1960, J. Chem. Phys. 33, pp. 639–643.

    Article  MathSciNet  ADS  Google Scholar 

  59. Chandresekhar, S. 1943, Rev. Mod. Phys. 15, pp. 1–89.

    Article  MathSciNet  ADS  Google Scholar 

  60. Berberian, J.G., Cole, R.H. 1968 J. Chem. Phys. Soc. 90, pp. 3100–3104.

    Google Scholar 

  61. Shore, J.E., Zwanzig, R.W. 1975, J. Chem. Phys. 63, pp. 5445–5458.

    Article  ADS  Google Scholar 

  62. Helfand. E. 1983, to appear in J. Polymer Sci., Polymer Physics Ed.

    Google Scholar 

  63. Skinner, J.L. 1983, to appear in J. Chem. Phys.

    Google Scholar 

  64. Evans, G.J., personal communication.

    Google Scholar 

  65. Zwanzig, R.W. 1963, J. Chem. Phys. 38, pp. 2766–2772.

    Article  ADS  Google Scholar 

  66. Scher, H., Montroll, E.W. 1975, Phys. Rev. B12, pp. 2455–2463.

    ADS  Google Scholar 

  67. Scher, H., Lax, M. 1973, Phys. Rev. B7, pp. 4491–4501.

    Google Scholar 

  68. Cole, R.H. 1980, (British) Inst. of Phys. Conf. Series No. 58, pp. 1–21.

    Google Scholar 

  69. Brot, C. Bossis, G., Hesse-Bezot, C. 1980, Mol. Phys. 40, pp. 1053–1072.

    Article  ADS  Google Scholar 

  70. Levesque, D., Weis, J.J., Oxtoby, D.W. 1983, J. Chem. Phys. 79, pp. 917–925.

    Article  ADS  Google Scholar 

  71. Klein, M.L., McDonald. I.R. 1981, Mol. Phys. 42, pp. 243–247.

    Article  ADS  Google Scholar 

  72. Swenson, R.W., Cole, R.H. 1954, J. Chem. Phys. 22, pp. 284–288.

    Article  ADS  Google Scholar 

  73. Benoit. H. 1951, Ann. Phys. (Paris) 6, p. 561.

    Google Scholar 

  74. Cole, R.H. 1982, J. Phys. Chem. 86, pp. 4700–4704.

    Article  Google Scholar 

  75. Rosato, V., Williams, G. 1981, J. Chem. Soc. Far. Trans 2, 77, pp. 1767–1778.

    Google Scholar 

  76. For a review, see Hasted. J.B. 1973, ‘Aqueous Dielectrics’ ( Chapman and Hall, London).

    Google Scholar 

  77. Hubbard, J. B., Onsager, L. 1977, J. Chem. Phys. 67. pp. 4850–4857.

    Article  ADS  Google Scholar 

  78. Hubbard, J. B., Onsager, L. 1978, J. Chem. Phys. 68, pp. 1649–1664.

    Article  ADS  Google Scholar 

  79. Hubbard, J.B., Onsager, L., van Beek, W.M., Mandel, M. 1977, Proc. Nat. Acad. Sci. 7, pp. 401–404.

    Article  ADS  Google Scholar 

  80. Hall, D.G., Cole, R.H. 1981, J. Chem. Phys. 85, pp. 1065–1069.

    Article  Google Scholar 

  81. Hubbard, J.B., Colonomos, P., Wolynes, P.G. 1979. J. Chem. Phys. 71, pp. 2652–2661.

    Article  ADS  Google Scholar 

  82. Winsor, P. Cole, R.H. 1982, J. Chem. Phys. 86, pp. 2486–2490, pp. 2491–2496.

    Google Scholar 

  83. Wolynes, P.G. 1980, Ann. Rev. Phys. Chem. 31, pp. 345–376.

    Article  ADS  Google Scholar 

  84. Patey, G.N., Carnie, S.L. 1983, J. Chem. Phys. 78. pp. 5183–5190.

    Google Scholar 

  85. Friedman. H.L. 1983,, J. Chem. Phys. 76, pp. 1092–1105.

    Google Scholar 

  86. Schallamach, A. 1946, Trans. Far. Soc. 42A, pp. 180–186.

    Article  Google Scholar 

  87. Denney. D.J., Cole, R.H. 1955, J. Chem. Phys. 23, pp. 1767–1772.

    Article  ADS  Google Scholar 

  88. Denney, D.J. 1959, J. Chem. Phys. 30, pp. 1019–1024.

    Article  ADS  Google Scholar 

  89. Bos, F.F. 1958, doctoral thesis, Leiden. See also Ref.(48).

    Google Scholar 

  90. Kivelson, D., personal communication.

    Google Scholar 

  91. Bertolini, D., Cassettari, M., Salvetti, G. 1982, J. Chem. Phys 76 pp. 3285–3290.

    Article  ADS  Google Scholar 

  92. Perl, J., Wasan, D.T., Winsor, P., Cole, R.H. To be submitted to J. Mol. Liquids.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, Brown University, Providence, Rhode Island, USA

    Robert H. Cole

Authors
  1. Robert H. Cole
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Chemistry and Applied Chemistry, University of Salford, Salford, UK

    A. J. Barnes  & W. J. Orville-Thomas  & 

  2. Department of Chemistry, University of Durham, Durham, UK

    J. Yarwood

Rights and permissions

Reprints and permissions

Copyright information

© 1984 D. Reidel Publishing Company

About this chapter

Cite this chapter

Cole, R.H. (1984). Dielectric Polarization and Relaxation. In: Barnes, A.J., Orville-Thomas, W.J., Yarwood, J. (eds) Molecular Liquids. NATO ASI Series, vol 135. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6463-1_3

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-6463-1_3

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-6465-5

  • Online ISBN: 978-94-009-6463-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation