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Physics and Chemistry of Electrons and Ions in Condensed Matter pp 437–458Cite as

Electronic Properties of Intercalate Complexes of Layer Type Transition Metal Dichalcogenides

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Part of the book series: NATO ASI Series ((ASIC,volume 130))

Abstract

This paper discusses some of the physical and chemical phenomena encountered during intercalation of the layered transition metal dichalcogenides. For convenience three classes of intercalate complexes are distinguished; 1) those formed with nitrogen containing organic molecules, and ammonia and hydrazine, 2) complexes with alkali and alkali earth metals, and 3) complexes with the “3d” transition metals. Intercalation can cause profound changes in the electronic properties of the host lattice, and these can be understood in terms of charge transfer and increased interlayer separation. The phenomena discussed include optical properties, transport properties, superconductivity, phase changes, staging, magnetic properties, metal insulator transitions, Anderson localisation, and fast ion conduction. Some possible practical applications are also mentioned.

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Author information

Authors and Affiliations

  1. Cavendish Laboratory, University of Cambridge, UK

    A. D. Yoffe

Authors
  1. A. D. Yoffe
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Editor information

Editors and Affiliations

  1. San José University, San José, California, USA

    J. V. Acrivos

  2. Trinity College, Cambridge, UK

    J. V. Acrivos

  3. Cavendish Laboratory, Cambridge, UK

    N. F. Mott  & A. D. Yoffe  & 

  4. Gonville and Caius College, Cambridge, UK

    N. F. Mott

  5. Darwin College, Cambridge, UK

    A. D. Yoffe

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© 1984 D. Reidel Publishing Company

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Yoffe, A.D. (1984). Electronic Properties of Intercalate Complexes of Layer Type Transition Metal Dichalcogenides. In: Acrivos, J.V., Mott, N.F., Yoffe, A.D. (eds) Physics and Chemistry of Electrons and Ions in Condensed Matter. NATO ASI Series, vol 130. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6440-2_37

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  • DOI: https://doi.org/10.1007/978-94-009-6440-2_37

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-6442-6

  • Online ISBN: 978-94-009-6440-2

  • eBook Packages: Springer Book Archive

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