Abstract
In a solid, the character of the electrons outside of closed atomic shells depends upon the relative strengths of four competing energies:
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1.
Heat: TΔS
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2.
Intra-atomic energies: Ueff, ΔLS
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3.
Interatomic energies: Δc, Δnc, w ≈ 2zb
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4.
Electron-lattice interaction energy: Δel
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References
M.D. Banus and T.B. Reed, in The Chemistry of Extended Defects in Non-metallic Solids, L. Eyring and M. O’Keeffe, eds, North Holland, Amsterdam (1970) 488.
M.R. Oliver, Ph. D. Thesis, M.I.T. (1970).
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© 1984 D. Reidel Publishing Company
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Goodenough, J.B. (1984). The Effective U in Oxides and in Sulfides: Conceptual Phase Diagrams and Their Applications. In: Acrivos, J.V., Mott, N.F., Yoffe, A.D. (eds) Physics and Chemistry of Electrons and Ions in Condensed Matter. NATO ASI Series, vol 130. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6440-2_1
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DOI: https://doi.org/10.1007/978-94-009-6440-2_1
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