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Telomerization of Dienes by Homogeneous Transition Metal Catalysts

  • Chapter
Aspects of Homogeneous Catalysis

Part of the book series: Aspects of Homogeneous Catalysis ((AHCA,volume 5))

Abstract

In homogeneous catalysis telomerization is defined as the oligomerization of dienes under the concomitant addition of a nucleophilic reagent. For example, two molecules of butadiene react with one nucleophile HY to form the dimeric telomers 1 and 2. This reaction (Equation 1) is catalyzed by various organometallic compounds

of the transition metals, especially by palladium complexes. The nucleophiles — for example, water, alcohols, amines or acids — are introduced mainly at the terminal position of the dimeric molecule giving excellent yields of the product 1.

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  1. Institut für Technische Chemie und Petrolchemie der, Rheinisch-Westfälischen Technischen Hochschule Aachen, Worringer Weg 1, D-5100, Aachen, Germany

    Arno Behr

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  1. Istituto di Chimica Generale ed Inorganica, Universita di Milano, Italy

    Renato Ugo

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Behr, A. (1984). Telomerization of Dienes by Homogeneous Transition Metal Catalysts. In: Ugo, R. (eds) Aspects of Homogeneous Catalysis. Aspects of Homogeneous Catalysis, vol 5. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6363-4_1

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