Skip to main content
SpringerLink
Log in
Book cover

Thermochemistry and Its Applications to Chemical and Biochemical Systems pp 789–802Cite as

Barriers to Internal Rotation in Inorganic Species

  • Chapter

  • 386 Accesses

Part of the book series: NATO ASI Series ((ASIC,volume 119))

Abstract

Barriers to internal rotation have been determined using infrared and Raman spectroscopy for some inorganic species. The methods used for the determination of these barriers will be described for a high barrier (BCℓ2SH), a medium barrier (PF5, AsF5 and VF5) and a low or zero energy barrier (B(CH3)3).

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Kirklin, D.R., Ritter, J.J., and Abramowitz, S.: 1977, J. Mol. Spectroscopy, 67, 322.

    Article  Google Scholar 

  2. Levin, I.W., and Abramowitz, S.: 1965, J. Chem., 43, 4213.

    CAS  Google Scholar 

  3. Bernstein, L.S., Kim, J.J., Pitzer, K.S., Abramowitz, S., and Levin, I.W.: 1975, J. Chem. Phys., 62, 3671.

    Article  CAS  Google Scholar 

  4. Bernstein, L.S., Abramowitz, S., and Levin, I.W.: 1976, 64, 3228.

    CAS  Google Scholar 

  5. Holmes, R.R. Sr.„ Deiters, R.M., and Hora, C.J.: 1974, J. Chem. Soc. Commun., 175.

    Article  Google Scholar 

  6. Furukawa, G.T. and Park, R.P.: 1954, National Bureau of Standard Report3644.

    Google Scholar 

  7. Woodward, L.A., Hall, T.R., Dixon, R.N.: 1959, Spectrochim. Acta 15, 249.

    Article  Google Scholar 

  8. Longuet-Higgins, H.C.: 1963, Molecular Phys., 6, 445.

    Article  CAS  Google Scholar 

  9. Bunker, P.R.: 1979, Molecular Symmetry and Molecular Structure, Academic Press, New York.

    Google Scholar 

  10. Bartell, L.S and Carroll, B.L.: 1965, J. Chem. Phys., 42, 3076

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National Bureau of Standards, Washington, D.C, 20234, USA

    Stanley Abramowitz

Authors
  1. Stanley Abramowitz
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, University of Oporto, Portugal

    Manuel A. V. Ribeiro da Silva

Rights and permissions

Reprints and permissions

Copyright information

© 1984 D. Reidel Publishing Company

About this chapter

Cite this chapter

Abramowitz, S. (1984). Barriers to Internal Rotation in Inorganic Species. In: Ribeiro da Silva, M.A.V. (eds) Thermochemistry and Its Applications to Chemical and Biochemical Systems. NATO ASI Series, vol 119. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6312-2_38

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-6312-2_38

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-6314-6

  • Online ISBN: 978-94-009-6312-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation