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Thermochemistry and Its Applications to Chemical and Biochemical Systems pp 601–626Cite as

Experimental Methods to Study the Thermochemistry of Gas Phase Ions and Ion-Molecule Reactions

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Part of the book series: NATO ASI Series ((ASIC,volume 119))

Abstract

Ionic species and ion–molecule reactions provide, in one way or another, a major contribution to the Earth’s chemistry. Although the most familiar reactions occur in solution (where they are often significantly moulded by solvent interaction) there are a number of important areas where ions exist and react in the gas phase. The upper atmosphere is an obvious and important example (0(2). An even more hospitable environment for free ions lies outside the Earth, in outer space. It is only just being revealed how important such reactions are in the creation and propagation of interstellar clouds (3). Gas phase ion–molecule reactions also occur in flames (4) electrical discharges (50). and are sometimes a corrosive nuisance in the coolant gases of nuclear reactors, Finally, they have become an important tool in analytical mass spectrometry (6).

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Authors and Affiliations

  1. Department of Chemistry and Molecular Sciences, University of Warwick, Coventry, CV4 7AL, UK

    Rod S. Mason

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  1. Rod S. Mason
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Editors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, University of Oporto, Portugal

    Manuel A. V. Ribeiro da Silva

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Mason, R.S. (1984). Experimental Methods to Study the Thermochemistry of Gas Phase Ions and Ion-Molecule Reactions. In: Ribeiro da Silva, M.A.V. (eds) Thermochemistry and Its Applications to Chemical and Biochemical Systems. NATO ASI Series, vol 119. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6312-2_30

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  • DOI: https://doi.org/10.1007/978-94-009-6312-2_30

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