Abstract
Ionic species and ion–molecule reactions provide, in one way or another, a major contribution to the Earth’s chemistry. Although the most familiar reactions occur in solution (where they are often significantly moulded by solvent interaction) there are a number of important areas where ions exist and react in the gas phase. The upper atmosphere is an obvious and important example (0(2). An even more hospitable environment for free ions lies outside the Earth, in outer space. It is only just being revealed how important such reactions are in the creation and propagation of interstellar clouds (3). Gas phase ion–molecule reactions also occur in flames (4) electrical discharges (50). and are sometimes a corrosive nuisance in the coolant gases of nuclear reactors, Finally, they have become an important tool in analytical mass spectrometry (6).
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References
Ferguson E.E., Fehsenfeld F.C., and Albritton D.L.: 1979, in Gas Phase Ion Chemistry, Vol. 1, (ed. M.T. Bowers ), Academic Press, Chap. 2, pp 45–82.
Smith D., and Adams N.G.: 1980, Topics in Current Chemistry 89, pp J—43.
Viggiano A.A., Haworka F., Albritton D.L., Fehsenfeld F.C., Adams N.G., and Smith D.: 1980, The Astrophys.J. 236, pp 492.
Bohme D.K.: 1979, in Kinetics of Ion–Molecule Reactions, (ed. P. Ausloos), Plenum, New York, pp 323–343.
Wickham A.J., Best J.V., and Wood C.J.: 1977, Radiat. Phys.Chem. 10, pp 107.
Jennings K,R.: 1979, in Gas Phase Ion Chemistry, Vol. 2 (ed. M.T. Bowers ), Academic Press, Chap. 12, pp 123–151.
Taft, R.W.: 1979, in Kinetics of Ion Molecule Reactions, (ed. P. Ausloos), Plenum, New York, pp 323–343.
For example: Traeger J.C., and McLoughlin R.G.: 1981, JACS 103, pp 3647–3652.
Kebarle, P.: 1975, in Interaction Between Ions and Molecules, (ed. P. Ausloos), Plenum, New York, pp 459–487.
Aue D.H., and Bowers M.T.: 1979, in Gas Phase Ion Chemistry, Vol. 2, (ed. M.T. BowersX, Academic Press, pp 1–51.
Bartmess J.L., and Mclver R.T.: 1979, in Gas Phase Ion Chemistry Vol. 2, (ed. M.T. Bowers ), Academic Press, pp 87–121.
For example: Moet–Ner M., Sieck L.W., and Ausloos P.: 1981, JACS 103, pp 5342–5348.
For example: Uppal J.S., and Staley R.H.: 1982, JACS 104, pp 1229–1238.
Rosenstock H.M., Draxl K., Steiner B.W., and Herron J.T.: 1977, J. Phys. and Chem. Ref. Data 6, Suppl. 1.
Kiser R.W.: “Introduction to Mass Spectrometry and Its Ap–plications” 1965, Prentice Hall Inc.
Lehman T.A., Bursey M.M.; Ion Cyclotron Resonance Spectrometry, 1976, Wiley–Interscience; Mclver R.T., and Dunbar R.C.: 1971, Int.J.Mass.Spectrom. Ion. Phys. 7, pp 471; Mclyer R.T., Rev.Sci. Instrum. 41, pp 555.
Bowers M.T., Aue D.H., Webb H.M., and Mclver R.T.: 1971, JACS 93, pp 4314.
Herzberg G.: 1944, Atomic Spectra and Atomic Structure, Dover; 1950, Molecular Spectra and Molecular Structure, Vol. 1, Spectra of Diatomic Molecules, Van Nostrand.
Turner D.W., Baker A.D., Baker C., and Brundle C.R.: 1970, High Resolution Molecular Photoelectron Spectroscopy, New York, J. Wiley.
Janousek B.K., and Brauman J.I.: 1979, in Gas Phase Ion Chemistry, Vol. 2., (ed. M.T. BowersX, pp 53–86.
Siegel N.W., Celotta R.J., Hall J.L., Levin J., and Bennett R.A.: 1972, Phys. Rev. A6, pp 607–630.
Celotta R.J., Bennett R.A., Hall J.L., Siegel M.W. and Levine J.: 1972, Phys. Rev. A6, pp 631.
Smyth K.C., and Brauman J.I.: 1972, J.Chem.Phys. 56, pp J J32– 1142.
Zimmerman A.H., Reed K.J., and Brauman J.I.: 1977, JACS 99, pp 7203.
Beynon J.H., Cooks R.G., Jennings K.R., and Ferrer-Correia A.J. 1975, Int.J.Mass Spectrom. Ion Phys. 18, pp 87–99.
Morrison J.D.: 1972, Org. Phys. Chemistry Series One, Vol. 5, (ed. A. Maccoll), pp 25–54; Maccoll A.: 1982, Org. Mass Spectrom. 17, pp 1–9.
See for example: McCulloh K.E.: 1976, Int.J. Mass Spectrom. Ion Phys. 64, pp 333–342.
Parr G.R., and Taylor J.W.: 1973, Rev. Sci. Instrum. 44. pp 1578.
See: Chesnavich W.J., and Bowers M.T.: 1979, in Gas Phase Ion Chemistry, Vol. 1, (ed. M.T. Bowers), pp 119–151, and refs. therein.
See, for instance: Cooks R.G., Beynon J.H., Caprioli R.M., and Lester G.R.: 1973, Metastable Ions, Elsevier Scientific Pub. Co.; Burgers P.C., and Holmes J.L.: 1982, Org. Mass Spectrom. 17, pp 123–130.
See: Stockbauer R., and Rosenstock H.M.: 1978, Int.J.Mass Spectrom. Ion Phys. 27, pp 185–195, and refs. therein.
Lifshitz C.: 1982, J.Phys.Chem 86, pp 606.
Lifshitz C., Peers A.M., Weiss M., and Weiss M.J.: 1973, Adv. Mass Spectrom. 6, pp 871.
Werner A.S., and Baer T.: 1975, J. Chem. Phys. 62, pp 2900– 2910.
Stockbauer R.: 4977, In::.J. Mass Spectrom. Ion Phys. 25, pp 89.
Rosens tock H.M., Buff R., Ferreira M.A.A., Lias S.G., Parr A.C., Stockbauer R.L., and Holmes J.L.:’ –1982, JACS 104, pp 2337–2345.
Baer T.: 1979, Gas Phase Ion Chemistry, Vol. 1 (ed. M.T.Bowers), Academic Press, pp 153–196, and refs. therein.
Talt Roze V.L., and Frankevich E.L.: 1956, Dokl. Akad, Nauk. SSR 111, pp 376.
Beauchamp J.L: 1971, Annu. Rev. Phys. Chem. 22, pp 527.
Kebarle, P.: 1977, Annu. Rev. Phys. Chem., pp 445–476.
Bohme D.K., Stone J.A., Mason R.S., Stradling R.S., and Jennings K.R.: 1981, Int. J. Mass Spectrom Ion Phys. 37, pp 283–296.
Headley J.V., Mason R.S., and.Jennings K.R.: 1982, J. Chem. Soc. Faraday Trans:. 1, V78, pp 933–945.
Brauman J.I., and Blair L.K.: 1968, JACS 90, pp 5636.
See, for example: Hartman K., and Lias S.G.: 1978, Int. J. Mass Spectrom. Ion Phys. 28, pp 213–223.
See, for instance: Smith D., Adams N.G., and Lindinger W.: 1982, J..Chem. Phys. 75, pp 3365–3370.
Marx R., “Energetics and Dynamics of Positive Ion–Molecule Reactions in Thermal Energy Collisions”, NATO Advanced Study Institute: Chemistry of Ions in the Gas Phase, Portugal,J982.
Smith D., and Adams N.G.: 1979, in Gas Phase Ion Chemistry, Vol. 1, (ed. M.T. Bowers ), Academic Press, pp 1–44.
Ferguson E.E., Fehsenfeld F.C., and Schmeltekopf A.L.: J969, Adv. At. Mol. Phys. 5, pp 1–56.
Mason R.S., Bahme D.K., and Jennings K.R.: 1982, J. Chem. Soc Faraday Trans. 1, 78, pp 1943–1952.
Pedley J.B., and Rylance J.: 1977, Sussex–NPL Computer Analysed Thermochemical Data, Organic and Organometallic Compounds, University of Sussex Press.
Cooks R.G. (ed.),: 1978, Collision Spectroscopy, Plenum Press.
Wagman D.D., Evans W.H., Parker V.B., Halow I., Bailey S.M., and SchumnR.H.: 1968, Selected Values of Chemical Thermo¬dynamic Properties, NBS Technical Note 270–3: 1971, JANAF Thermochemical Tables, Nat. Stand. Ref. Data Ser., N.B.S. (US) 37.
Franklin J.L., Dillard J.G., Rosenstock H.M., Herron J.T., Draxl K., and Field F.H.: 1969, Nat. Stand. Ref. Data Series, N.B.S. (US) 26.
Levin R.D*, Lias S.G., Ionisation Potential and Appearance Potential Measurements, 1971–1981, N.B.S. Washington, 1983, In Press.
Walder R., and Franklin J.L.: 1980, Int. J. Mass Spectrom. Ion Phys. 36, pp 85–112.
Lias S.G., Holmes J.L., Bartmess J., and others, to be pub¬lished by National Bureau of Standards (US) in 1983.
Holmes J.L., Fingas M., and Lossing F.P.: 1981, Can. J. Chem. 59, pp 80–93.
Schiff H.I., and Bohme D.K.: 1975, Int. J. Mass Spectrom. Ion Phys. 16, pp 167–189.
Pack J.L., and Phelps A.V.: 1966, J. Chem. Phys. 44, pp 1870.
Studniarz S.A: 1972, in Ion–Molecule Reactions Vol. 2 (,ed. J.L. Franklin), Butterworths, London, Chap. 14, pp 647–671.
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Mason, R.S. (1984). Experimental Methods to Study the Thermochemistry of Gas Phase Ions and Ion-Molecule Reactions. In: Ribeiro da Silva, M.A.V. (eds) Thermochemistry and Its Applications to Chemical and Biochemical Systems. NATO ASI Series, vol 119. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6312-2_30
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DOI: https://doi.org/10.1007/978-94-009-6312-2_30
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