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Effects of Short Wavelength Composition Modulations on Interdiffusion in Silver-Palladium Thin Foils

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Modulated Structure Materials

Part of the book series: Nato ASI Series ((NSSE,volume 83))

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Abstract

The effects of short wavelength composition modulations upon interdiffusion were evidenced in the Ag-Pd system by an x-ray diffraction technique. The general behavior of the interdiffusity versus the wavelength of the concentration wave was found in agreement with the nonlinear diffusion theory of Tsakalakos. Super-imposed on this general behavior, two anomalies were found which can be attributed respectively to, 1) a loss of coherency between the Ag-rich and Pd-rich regions, and 2) a screening singularity or an increase in the shear modulus (or both) such as was found in the Au-Ni system. The wavelength dependence of the interdiffusion coefficient yielded the first four gradient-energy for this system.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Materials Research Center, Northwestern University, Evanston, Illinois, 60201, USA

    G. E. Hénein & J. E. Hilliard

Authors
  1. G. E. Hénein
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  2. J. E. Hilliard
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Editor information

Editors and Affiliations

  1. Department of Mechanics and Materials Science, Rutgers University, Piscataway, NJ, 08854, USA

    T. Tsakalakos

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© 1984 Martinus Nijhoff Publishers, Dordrecht

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Hénein, G.E., Hilliard, J.E. (1984). Effects of Short Wavelength Composition Modulations on Interdiffusion in Silver-Palladium Thin Foils. In: Tsakalakos, T. (eds) Modulated Structure Materials. Nato ASI Series, vol 83. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6195-1_26

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  • DOI: https://doi.org/10.1007/978-94-009-6195-1_26

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-6197-5

  • Online ISBN: 978-94-009-6195-1

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