Abstract
Although a classification of aquatic organic matter is difficult, an examination of recent literature reviews (Williams (1975), Reuter and Perdue (1977), Buffle (1984)) indicates that the major groups of organic ligands are polysaccharides, proteins and peptides, “pedogenic” (soil derived) refractory organic matter (PROM) and “aquogenic” (formed in situ in the water body) refractory organic matter (AROM). Altogether, the last two groups form the so-called water fulvic and humic acids which represent a large proportion (~ 70–80%) of the organic matter in natural waters. The characteristics of PROM resemble those of soil fulvic acids (SFA: extracted from soil; Schnitzer (1978)), but differ markedly from those of AROM and of humic and fulvic fractions of sediments (Buffle (1984)). The complexation data reported in the literature concern mostly SFA and the fulvic fractions of PROM and AROM.
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References
-Baccini, P., U. Suter (1979) (B1). Melimex, an experimental heavy metal pollution study. Chemical speciation and biological availability of copper in lake water. Schw. Z. Hydrol. 41: 291–314.
-Bhat, G.A., J.H. Weber (1982) (B2). Cadmium binding by soil derived fulvic acid measured by anodic stripping voltammetry. Anal. Chim. Acta 141: 95–103.
-Bhat, G.A., R.A. Saar, R.B. Smart, J.H. Weber (1981) (B3). Titration of soil derived fulvic acid by copper (II) and measurement of free copper (II) by anodic stripping voltammetry and copper (II) selective electrode. Anal. Chem. 53: 2275–2280.
-Bresnahan, W.T., C.L. Grant, J.H. Weber (1978) (B4). Stability constants for the complexation of copper (II) ions with water and soil fulvic acids measured by an ion selective electrode. Anal. Chem. 50: 1675–1679.
-Buffle, J. (1981) (B5). Calculation of the surface concentration of the oxidized metal during the stripping step in the anodic stripping techniques and its influence on speciation measurements in natural waters. J. Electroanal. Chem. 125: 273–294.
-Buffle, J. (1984) (B6). The natural organic substances and their metal complexes in aquatic systems. In H. Sigel (Ed.): Circulation of metals in the environment. Vol. 18 of the series: Metal ions in biological systems. M. Dekker, N.Y., Basel.
-Buffle, J., A. Cominoli (1980) (B7). Voltammetric study of humic and fulvic substances. Part IV: Behaviour of fulvic substances at the mercury water interface. J. Electroanal. Chem. 121: 273–299.
-Buffle, J., P. Deladoey, F.L. Greter, W. Haerdi (1980) (B8). Study of the complex formation of copper (II) by humic and fulvic substances. Anal. Chim. Acta 116: 255–274.
-Buffle, J., F.L. Greter (1979) (B9). Voltammetric study of humic and fulvic substances. Part II. J. Electroanal. Chem. 101: 231–251.
-Buffle, J., F.L. Greter, W. Haerdi (1977) (B10). Measurement of complexation properties of humic and fulvic acids in natural waters with lead and copper ion-selective electrodes. Anal. Chem. 49: 216–222.
-Chau, Y.K., P.T.S. Wong (1976) (C1). Complexation of metals in natural waters. In R.W. Andrew, P.V. Hodson, D.E. Konasewitch (Ed.). Toxicity to biota of metal forms in natural waters. Proceedings Workshop, held in Minnesota (7–8/10/1975). International Joint Commission’s Research Advisory Board.
-Dauthuille, P. (1982) (D1). Etude électrochimique des complexes Cu (II)- acides fulviques en solution aqueuse. Thèse. Ecole nationale supérieure de chimie de Paris.
-Davey, E.W., M.J. Morgan, S.J. Erickson (1973) (D2). A biological measurement of the copper complexation capacity of sea water. Limnol. Oceanogr. 18: 993–997.
-Davidson, W. (1978) (D3). Defining the electroanalytically measured species in a natural water sample. J. Electroanal. Chem. 87: 395–404.
-Duinker, J.C., C.J.M. Kramer (1977) (D4). An experimental study on the speciation of dissolved zinc, cadmium, lead and copper in river Rhine and North Sea water, by differential pulsed anodic stripping voltammetry. Mar. Chem. 5: 207–228.
-Gächter, R., J.S. Davis, A. Mares (1978) (G1). Regulation of copper availability to phytoplancton by macromolecules in lake water. Environ. Sci. Technol. 12: 1416–1421.
-Gamble, D.S., M. Schnitzer (1973) (G2). The chemistry of fulvic acid and its reactions with metal ions. In P.C. Singer (Ed.). Trace metals and metalorganic interactions in natural waters. Ann Arbor Science Pub. Inc., Ann Arbor, Mich.
-Gamble, D.S., A.W. Underdown, C.H. Langford (1980) (G3). Copper(II) titration of fulvic acid ligand sites with theoretical, potentiometric and spectrophotometric analysis. Anal. Chem. 52: 1901–1908.
-Gillespie, P.A., R.F. Vaccaro (1978) (G4). A bacterial bioassay for measuring the copper chelation capacity of sea water. Limnol. Oceanogr. 23: 543–548.
-Greter, F.L., J. Buffle, W. Haerdi (1979) (G5). Voltammetric study of humic and fulvic substances. Part. I. J. Electroanal. Chem. 101: 211–229.
-Hart, B.T., S.H.R. Davies (1981) (H1). Copper complexing capacity of waters in the Magela creek system, Northern Australia. Environ. Technol. Letters 2: 205–214.
-Heyrovsky, J., J. Kuta (1966) (H2). Principles of polarography, Academic Press, N.Y., London.
-Hirata, S. (1981) (H3). Stability constants for the complexes of transition metal ions with fulvic and humic acids in sediments measured by gel filtration. Talenta 28: 809–815.
-Hirose, K., Y. Dokiya, Y. Sugimura (1982) (H4). Determination of conditional stability constants of organic copper and zinc complexes dissolved in sea water using ligand exchange method with EDTA. Mar. Chem. 11: 343–354.
-Hoffman, M.R., E.C. Yost, S.J. Eisenreich, W.J. Maier (1981) (H5). Characterization of soluble and colloidal phase metal complexes in river water by ultrafiltration. A mass-balance approach. Environ. Sci. Technol. 15: 655–661.
-Mantoura, R.F.C. (1981) (M1). Organo-metallic interactions in natural waters. In E.K. Duursma, R. Dawson (Ed.). Marine organic chemistry, Elsevier Oceanography Series 31. Elsevier Sci. Publ. Cy., Amsterdam. N.Y.
-Mantoura, R.F.C., J.P. Riley (1975) (M2). The use of gel filtration in the study of metal binding hy humic acids and related compounds. Anal. Chim. Acta 78: 193–200.
-Reuter, J.H., E.M. Perdue (1977) (R1). Importance of heavy metal-organic matter interaction in natural water. Geochim. Cosmochim. Acta 41: 326–334.
-Ryan, D.K., J.H. Weber (1982) (R2). Copper (II) complexing capacities of natural waters by fluorescence quenching. Environ. Sci. Technol. 16: 866–872.
-Saha, S.K., S.L. Dutta, S.K. Chakravarti (1979) (S1). Polarographic study of metal-humic acid interaction. Determination of stability constants of cadmium and zinc-humic acids at different pH. J. Indian Chem. Soc. 56: 1129–1134.
-Schnitzer, M. (1978) (S2). Humic substances: chemistry and reactions. In M. Schnitzer, S.U. Khan, Soil organic matter. Developments in soil science 8. Elsevier Sci. Publ. Co., Amsterdam, N.Y.
-Schnitzer, M., E.H. Hansen (1970) (S3). Organo-metallic interactions in soils: an evaluation of methods for the determination of stability constants of metal-fulvic acids complexes. Soil Sci. 109: 333–340.
-Shuman, M.S., G.P. Woodward (1977) (S4). Stability constants of copper-organic chelates in aquatic samples. Environm. Sci. Technol. 11: 809–813.
-Shuman, M.S., J.L. Cromer (1979) (S5). Copper association with aquatic fulvic and humic acids. Estimation of conditional formation constants with a titrimetric anodic stripping voltammetry procedure. Environ. Sci. Technol. 13: 543–545.
-Srna, R.F., K.S. Garrett, S.M. Miller, A.B. Thum (1980) (S6). Copper complexation capacity of marine water samples from southern California. Environ. Sci. Technol. 14: 1482–1486.
-Stokes, P., T.C. Hutchinson (1976) (S7). Copper toxicity to phytoplaneton, as affected by organic ligands, other cations and inherent tolerance of algae to copper. In R.W. Andrew, P.V. Hodson, D.E. Konasewitch, Toxicity to Biota of Metal Forms in Natural Waters. Proc. Workshop held in Minnesota (7–8/10/1976). International Joint Commission’s Research Advisory Board.
-Sunda, W.C., P.J. Hanson (1979) (S8). Chemical speciation of copper in river water. Effect of total copper, pH, carbonate, and dissolved organic matter. In E.A. Jenne (Ed.). Chemical modeling in aqueous systems. American Chemical Society, Washington.
-Truitt, R.E., J.H. Weber (1981) (T1). Determination of complexing capacity of fulvic acid for copper (II) and cadmium (II) by dialysis titration. Anal. Chem. 53: 337–342.
-Truitt, R.E., J.H. Weber (1981) (T2). Copper(II) and cadmium(II) binding abilities of some New Hampshire freshwaters determined by dialysis titration. Environ. Sci. Technol. 15: 1204–1208.
-Van den Berg, C.M.G. (1982). (VI). Determination of copper complexation with natural organic ligands in sea water, by equilibration with MnO2. Part II. Mar. Chem. 11: 323–342.
-Van den Berg, C.M.G., J.R. Kramer (1979) (V2). Determination of complexing capacities of ligands in natural waters and conditional stability constants of the copper complexes by means of manganese dioxide. Anal. Chim. Acta 106: 113–120.
-Van Leeuwen, H.P. (1978) (V3). Pulse polarography of heavy metal ions in the presence of natural complexing agents. Lecture at 29th ISE Meeting, Budapest.
- Williams, P.J. le B. (1975) (W1). Biological and chemical aspects of dissolved organic material in sea water. In J.P. Riley, G. Skirrow (Ed.). Chemical Oceanography, vol. 2, Academic Press, London.
-Wilson, D.E., P. Kinney (1977) (W2). Effects of polymeric charge variations on the proton metal ion equilibria of humic materials. Limnol. Oceanogr. 22: 281–289.
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Buffle, J., Tessier, A., Haerdi, W. (1984). Interpretation of Trace Metal Complexation by Aquatic Organic Matter. In: Kramer, C.J.M., Duinker, J.C. (eds) Complexation of trace metals in natural waters. Developments in Biogeochemistry, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-6167-8_27
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DOI: https://doi.org/10.1007/978-94-009-6167-8_27
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