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High-spin Iron Complexes

  • Chapter
Mössbauer Spectroscopy

Abstract

The facility with which 57Fe 14·41-keV Mössbauer spectra can be measured has resulted in considerable use of the technique for probing iron solid-state systems; so much so that it would be impossible to summarise the data adequately in a single chapter. The general field of iron chemistry has therefore been subdivided into a number of subsections and, although this division is to some extent arbitrary it simplifies the task of presenting the results considerably. The subsections are as follows,

  1. (i)

    iron(II) and iron(III) complexes with high-spin electronic configurations (Chapter 6);

  2. (ii)

    iron(II) and iron(III) complexes with low-spin electronic configurations (Chapter 7);

  3. (iii)

    ligand-field crossover situations and uncommon paramagnetic oxidation states (Chapter 8);

  4. (iv)

    covalent, diamagnetic iron complexes (Chapter 9);

  5. (v)

    iron oxides, chalcogenides, and minerals (Chapter 10);

  6. (vi)

    intermetallic systems and alloys (Chapter 11);

  7. (vii)

    decay after-effects and impurity studies, together with some miscellaneous topics (Chapter 12);

  8. (viii)

    biological systems (Chapter 13).

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    N. N. Greenwood (Professor of Inorganic and Structural Chemistry) & T. C. Gibb (Lecturer in Inorganic and Structural Chemistry)

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Greenwood, N.N., Gibb, T.C. (1971). High-spin Iron Complexes. In: Mössbauer Spectroscopy. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5697-1_6

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