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Spectroscopic and Chemical Investigations of PVC Structure

  • W. F. Maddams

Abstract

The substantial progress achieved during the past two decades in elucidating the molecular structure of PVC owes much to four spectroscopic techniques. At the outset, infrared spectroscopy proved valuable for the characterisation of the configurational and conformational chain isomers present and, more recently, 1H- and 13C-NMR spectroscopy have provided the means for quantitative measurements of tacticity. As there are increasing indications that a knowledge of the configurational and conformational states of PVC chains are important for an understanding of the propagation stage of the degradation process,1–4 the availability of such information is very useful.

Keywords

Chlorine Atom Chemical Investigation Methyl Branch Commercial Polymer Lithium Aluminium Hydride 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    Millán, J., Madruga, E. L., Bert, M. and Guyot, A. J. Polym. Sci., Polym. Chem. Ed., 11 (1973), 3299.Google Scholar
  2. 2.
    Millán, J. and Carranza, M. Rev. Plast. Mod., 30 (1975), 67.Google Scholar
  3. 3.
    Millán, J., Madruga, E. L. and Martinez, G. Angew. Makromol. Chem., 45 (1975), 172.Google Scholar
  4. 4.
    Millán, J. and Guzman, J. Eur. Polym. J., 12 (1976), 299.Google Scholar
  5. 5.
    Fuller, C. S. Chem. Rev., 26 (1940), 143.Google Scholar
  6. 6.
    Krimm, S. and Liang, C. Y. J. Polym. Sci., 22 (1956), 95.Google Scholar
  7. 7.
    Mizushima, S., Shimanouchi, T., Nakamura, K., Hayashi, M. and Tsuchiya, S. J. Chem. Phys., 26 (1957), 970.Google Scholar
  8. 8.
    Grisenthwaite, R. J. and Hunter, R. F. Chem. Ind. (1958), 719.Google Scholar
  9. 9.
    Grisenthwaite, R. J. and Hunter, R. F. Chem. Ind. (1958), 1513.Google Scholar
  10. 10.
    Krimm, S., Berens, A. R., Folt, V. L. and Shipman, J. J. Chem. Ind. (1958), 1512.Google Scholar
  11. 11.
    Shimanouchi, T., Tsuchiya, S. and Mizushima, S. J. Chem. Phys., 30 (1959), 1365.Google Scholar
  12. 12.
    Shimanouchi, T. and Tasumi, M. Bull. Chem. Soc. Japan, 34 (1961), 359.Google Scholar
  13. 13.
    Shimanouchi, T. and Tasumi, M. Spectrochim. Acta, 17 (1961), 755.Google Scholar
  14. 14.
    Shipman, J. J., Folt, V. L. and Krimm, S. Spectrochim. Acta, 18 (1962), 1603.Google Scholar
  15. 15.
    Krimm, S., Folt, V. L., Shipman, J. J. and Berens, A. R. J. Polym. Sci., A1, 1 (1963), 2621.Google Scholar
  16. 16.
    Shimanouchi, T., Tsuchiya, S. and Mizushima, S. Kobunshi, 8 (1959), 202.Google Scholar
  17. 17.
    Krimm, S., Folt, V. L., Shipman, J. J. and Berens, A. R. J. Polym. Sci., B2 (1964), 1009.Google Scholar
  18. 18.
    Pohl, H. U. and Hummel, D. O. Makromol. Chem., 113 (1968), 190.Google Scholar
  19. 19.
    Pohl, H. U. and Hummel, D. O. Makromol. Chem., 113 (1968), 203.Google Scholar
  20. 20.
    Baruya, A., Booth, A. D., Maddams, W. F., Grasselli, J.G. and Hazle, M. A.S. J. Polym. Sci., Polym. Lett. Ed., 14 (1976), 329.Google Scholar
  21. 21.
    Robinson, M. E. R., Bower, D. I. and Maddams, W. F. Polymer, 19 (1978), 773.Google Scholar
  22. 22.
    Maddams, W. F. and Tooke, P. B. J. Macromol. Sci., Chem., A17 (1982), 951.Google Scholar
  23. 23.
    Maddams, W. F. and Southon, M. J. Spectrochim. Acta, A38 (1982), 459.Google Scholar
  24. 24.
    Shimanouchi, T., Tasumi, M. and Abe, Y. Makromol. Chem., 86 (1965), 43.Google Scholar
  25. 25.
    Doskocilova, D., Stokr, J., Schneider, B., Pivcova, H., Kolinsky, M., Petranek, J. and Lim, D. J. Polym. Sci., C16 (1967), 215.Google Scholar
  26. 26.
    Schneider, B., Stokr, J., Doskocilova, D., Kolinsky, M., Sykora, S. and Lim, D. J. Polym. Sci., C16 (1968), 3891.Google Scholar
  27. 27.
    Opaskar, C. G. and Krimm, S. J. Polym. Sci., A-2, 7 (1969), 57.Google Scholar
  28. 28.
    Rubčič, A. and Zerbi, G. Macromolecules, 7 (1974), 754.Google Scholar
  29. 29.
    Rubčič, A. and Zerbi, G. Macromolecules, 7 (1974), 759.Google Scholar
  30. 30.
    Germar, H., Hellwege, K.-H. and Johnsen, U. Makromol Chem., 60 (1963), 106.Google Scholar
  31. 31.
    Nakajima, A., Hamada, H. and Hayashi, S. Makromol. Chem., 95(1966), 40.Google Scholar
  32. 32.
    Krimm, S. and Enomoto, S. J. Polym. Sci., A1, 2 (1964), 669.Google Scholar
  33. 33.
    Krimm, S., Shipman, J. J., Folt, V. L. and Berens, A. R. J. Polym. Sci., B3 (1965), 275.Google Scholar
  34. 34.
    Koenig, J. L. and Druesedow, D. J. Polym. Sci., A2, 7 (1969), 1075.Google Scholar
  35. 35.
    Robinson, M. E. R., Bower, D. I. and Maddams, W. F. Polymer, 17 (1976), 355.Google Scholar
  36. 36.
    Moore, W. H. and Krimm, S. Makromol Chem. Suppl. 1 (June 1975), 491.Google Scholar
  37. 37.
    Morrow, B. A. and Cody, I. A. J. Phys. Chem., 77 (1973), 1465.Google Scholar
  38. 38.
    Vandeginste, B. G. M. and De Galan, L. Anal Chem., 47 (1975), 2124.Google Scholar
  39. 39.
    Maddams, W. F. Appl. Spectrosc., 34 (1980), 245.Google Scholar
  40. 40.
    Baker, C., Cockerill, I. P., Kelsey, J. E. and Maddams, W. F. Spectrochim. Acta, 34A (1978), 673.Google Scholar
  41. 41.
    Baker, C., Johnson, P. S. and Maddams, W. F. Spectrochim. Acta, 34A (1978), 683.Google Scholar
  42. 42.
    Baker, C., Maddams, W. F., Grasselli, J. G. and Hazle, M. A. S. Spectrochim. Acta, 34A (1978), 761.Google Scholar
  43. 43.
    Goodfield, J. E., George, W. O. and Maddams, W. F. Unpublished results.Google Scholar
  44. 44.
    Bovey, F. A. and Tiers, G. V. D. J. Polym. Sci., 44 (1960), 173.Google Scholar
  45. 45.
    Sewell, P. R. The nuclear magnetic resonance spectra of polymers. In: Annual Review of NMR Spectroscopy, Vol. 1, Ed. E. F. Mooney, Academic Press, New York, 1968.Google Scholar
  46. 46.
    Shimanouchi, T. Pure Appl. Chem., 12 (1966), 287.Google Scholar
  47. 47.
    Johnsen, U. J. Polym. Sci., 54 (1961), 56.Google Scholar
  48. 48.
    Tincher, W. C. J. Polym. Sci., 62 (1962), S148.Google Scholar
  49. 49.
    Yoshino, T. and Komiyama, J. J. Polym. Sci., B3 (1965), 311.Google Scholar
  50. 50.
    Bovey, F. A., Anderson, E. W., Douglass, D. C. and Manson, J. A. J. Chem. Phys., 39 (1963), 1199.Google Scholar
  51. 51.
    Doskocilova, D. J. Polym. Sci., B2 (1964), 421.Google Scholar
  52. 52.
    Heatley, F. and Bovey, F. A. Macromolecules, 2 (1969), 241.Google Scholar
  53. 53.
    Abdel-Alim, A. H. J. Appl. Polym. Sci., 19 (1975), 1227.Google Scholar
  54. 54.
    Robinson, M. E. R., Bower, D. I., Maddams, W. F. and Pyszora, H. Makromol. Chem., 179 (1978), 2895.Google Scholar
  55. 55.
    Carman, C. J., Tarpley, A. R. and Goldstein, J. H. Macromolecules, 4 (1971), 445.Google Scholar
  56. 56.
    Inoue, Y., Ando, I. and Nishioka, A. Polym. J., 3 (1972), 246.Google Scholar
  57. 57.
    Carman, C. J., Tarpley, A. R. and Goldstein, J. H. J. Am. Chem. Soc., 93 (1971), 2864.Google Scholar
  58. 58.
    Carman, C. J. Macromolecules, 6 (1973), 725.Google Scholar
  59. 59.
    Schaefer, J. Macromolecules, 4 (1971), 110.Google Scholar
  60. 60.
    Liu, N.-L, Tong, S. N. and Koenig, J. L. J. Appl. Polym. Sci., 25(1980), 2205.Google Scholar
  61. 61.
    Elgert, K.-F. and Kosfeld, R. Paper presented at the Third International Symposium on Poly(vinyl chloride), Cleveland, Ohio, USA, 10-15 August, 1980.Google Scholar
  62. 62.
    King, J., Bower, D. I., Maddams, W. F. and Pyszora, H. Makromol. Chem., 184 (1983), 879.Google Scholar
  63. 63.
    Pham, Q. T., Millán, J. and Madruga, E. L. Makromol Chem., 175 (1974), 945.Google Scholar
  64. 64.
    Cais, R. E. and Brown, W. L. Macromolecules, 13 (1980), 801.Google Scholar
  65. 65.
    Coleman, B. D. and Fox, T. G. J. Chem. Phys., 38 (1963), 1065.Google Scholar
  66. 66.
    Coleman, B. D. and Fox, T. G. J. Polym. Sci., A1, 1 (1963), 3183.Google Scholar
  67. 67.
    Bovey, F. A. Chapter VIII in: High Resolution NMR of Macromolecules, Academic Press, New York, 1972.Google Scholar
  68. 68.
    Martinez, G., Mijangos, C., Millán, J., Gerrard, D. L. and Maddams, W. F. Makromol Chem., 180 (1979), 2937.Google Scholar
  69. 69.
    Fordham, J. W. L. J. Polym. Sci., 39 (1959), 321.Google Scholar
  70. 70.
    Schneider, B., Stokr, J., Doskocilova, D., Sykora, S., Jakes, J. and Kolinsky, M. J. Polym. Sci., C22 (1969), 1073.Google Scholar
  71. 71.
    Caraculacu, A. A. Pure and Appl. Chem., 53 (1981), 385.Google Scholar
  72. 72.
    Haslam, J., Willis, H. A. and Squirrel, D. C. M. Identification and Analysis of Plastics, 2nd ed., Illiffe Books, London, 1972, 374.Google Scholar
  73. 73.
    Baker, C. and Maddams, W. F. Makromol. Chem., 177 (1976), 437.Google Scholar
  74. 74.
    Cotman, J. Ann. N.Y. Acad. Sci., 57 (1953), 417.Google Scholar
  75. 75.
    Nakajima, A., Hamada, H. and Hayashi, S. Makromol. Chem., 95 (1966), 40.Google Scholar
  76. 76.
    Binder, L. Doctoral Thesis, Techn. Hochschule Vienna, 1962.Google Scholar
  77. 77.
    Braun, D. and Scharek, W. Angew. Makromol. Chem., 7 (1969), 121.Google Scholar
  78. 78.
    Barnett, G. M., Ross, F. L. and Hay, J. N. J. Polym. Sci., 5 (1967), 1467.Google Scholar
  79. 79.
    Baijal, M. D., Wang, T. S. and Dillen, R. M. J. Macromol. Sci., Chem., A4 (1970), 965.Google Scholar
  80. 80.
    Boccato, G., Rigo, A., Talamini, G. and Zilio-Grandi, F. Makromol. Chem., 108 (1967), 218.Google Scholar
  81. 81.
    Baker, C., Maddams, W. F., Park, G. S. and Robertson, B. Makromol. Chem., 165 (1973), 321.Google Scholar
  82. 82.
    Rigo, A., Palma, G. and Talamini, G. Makromol. Chem., 153 (1972), 219.Google Scholar
  83. 83.
    Preedy, J. E. Br. Polym. J., 5 (1973), 13.Google Scholar
  84. 84.
    Baker, C., David, P. and Maddams, W. F. Makromol. Chem., 180 (1979), 975.Google Scholar
  85. 85.
    McRae, M. A. and Maddams, W. F. Makromol. Chem., 177 (1976), 449.Google Scholar
  86. 86.
    Dorman, D. E., Otocka, E. P. and Bovey, F. A. Macromolecules, 5 (1972), 574.Google Scholar
  87. 87.
    Randall, J. C. J. Polym. Sci., Polym. Phys. Ed., 11 (1973), 275.Google Scholar
  88. 88.
    Axelson, D. E., Mandelkern, L. and Levy, G. C. Macromolecules, 10 (1977), 557.Google Scholar
  89. 89.
    Abbås, K. B., Bovey, F. A. and Schilling, F. C. Makromol. Chem. Suppl., 1 (June 1975), 227.Google Scholar
  90. 90.
    Carrega, M. E. Pure and Appl. Chem., 49 (1977), 569.Google Scholar
  91. 91.
    Bovey, F. A., Abbås, K. B., Schilling, F. C. and Starnes, W. H. Macromolecules, 8 (1975), 437.Google Scholar
  92. 92.
    Park, G. S. and Saleen, M. Polymer Bull., 1 (1979), 409.Google Scholar
  93. 93.
    Park, G. S. J. Macromol. Sci., Phys., B14 (1977), 151.Google Scholar
  94. 94.
    Starnes, W. H., Schilling, F. C., Abbås, K. B., Cais, R. E. and Bovey, F. A. Macromolecules, 12 (1979), 556.Google Scholar
  95. 95.
    Starnes, W. H., Schilling, F. C., Abbås, K. B., Plitz, I. M., Hartless, R. L. and Bovey, F. A. Macromolecules, 12 (1979), 13.Google Scholar
  96. 96.
    Starnes, W. H., Schilling, F. C., Plitz, I. M., Cais, R. E., Freed, D. J. and Bovey, F. A. Paper presented at the Third International Symposium on Poly(vinyl chloride), Cleveland, Ohio, USA, 10-15 August, 1980.Google Scholar
  97. 97.
    Park, G. S., Maddams, W. F. and Pyszora, H. Unpublished results.Google Scholar
  98. 98.
    Sörvik, E. M. J. Polym. Sci., Polym. Lett. Ed., 14 (1976), 735.Google Scholar
  99. 99.
    Sörvik, E. M. and Hjertberg, T. J. Macromol. Sci., Chem., A11 (1977), 1349.Google Scholar
  100. 100.
    Uuskyla, L. and Sörvik, E. M. J. Polym. Sci., Polym. Lett. Ed., 15 (1977), 387.Google Scholar
  101. 101.
    Hjertberg, T. and Sörvik, E. M. J. Polym. Sci., Polym. Chem. Ed., 16 (1978), 645.Google Scholar
  102. 102.
    Hjertberg, T. and Sörvik, E. M. Chemical methods for characterising defect structures in PVC, Report of the IUPAC PVC Working Party, Pure and Appl. Chem., in press.Google Scholar
  103. 103.
    Schwenk, U., Cavagna, F., Lömker, F., König, I. and Streitberger, H. J. Appl. Polym. Sci., 23 (1979), 1589.Google Scholar
  104. 104.
    Michel, A. Report to the Third International Symposium on Poly(vinyl chloride), Cleveland, Ohio, USA, 10-15 August, 1980.Google Scholar
  105. 105.
    Bowmer, T. N. and O’Donnell, J. H. Polymer, 18 (1977), 1032.Google Scholar
  106. 106.
    Bowmer, T. N., O’Donnell, J. H., Park, G. S. and Saleen, M. Paper presented at the Third International Symposium on Poly(vinyl chloride), Cleveland, Ohio, USA, 10-15 August, 1980.Google Scholar
  107. 107.
    Schröder, E. and Byrdy, M. Plaste Kautschuk, 14 (1977), 757.Google Scholar
  108. 108.
    Ahlstrom, D. A., Liebman, S. A. and Abbås, K. B. J. Polym. Sci., Polym. Chem. Ed., 14 (1976), 2479.Google Scholar
  109. 109.
    Liebman, S. A., Ahlstrom, D. H. and Starnes, W. H. Paper presented at the Third International Symposium on Poly(vinyl chloride), Cleveland, Ohio, USA, 10-15 August, 1980.Google Scholar
  110. 110.
    Bovey, F. A., Schilling, F. C. and Starnes, W. H. Polym. Prepr., Am. Chem. Soc. Div. Polym. Chem., 20 (1979), 160.Google Scholar
  111. 111.
    Starnes, W. H., Schilling, F. C., Plitz, I. M., Cais, R. E. and Bovey, F. A. Polym. Bull., 4 (1981), 555.Google Scholar
  112. 112.
    Abbås, K. B. Pure and Appl. Chem., 53 (1981), 411.Google Scholar
  113. 113.
    Thurmond, C. D. and Zimm, B. H. J. Polym. Sci., 8 (1952), 477.Google Scholar
  114. 114.
    Zimm, B. H. and Kulb, R. W. J. Polym. Sci., 37 (1959), 19.Google Scholar
  115. 115.
    Hengstenberg, J. and Schuch, E. Makromol. Chem., 74 (1964), 55.Google Scholar
  116. 116.
    Gautron, R. and Wippler, C. J. Chem. Phys., 58 (1961), 754.Google Scholar
  117. 117.
    Kobayashi, T. Bull. Chem. Soc. Japan, 35 (1962), 637.Google Scholar
  118. 118.
    Lyngaae-Jorgensen, J. J. Chromatogr. Sci., 9 (1971), 331.Google Scholar
  119. 119.
    Crugnola, A. and Danusso, F. J. Polym. Sci., B6 (1968), 535.Google Scholar
  120. 120.
    Andersson, K. B. and Sörvik, E. M. J. Polym. Sci., C33 (1971), 247.Google Scholar
  121. 121.
    De Vries, A. J., Bonnebat, C. and Carrega, M. Pure Appl. Chem., 25 (1971), 209.Google Scholar
  122. 122.
    Hlousek, M. and Lanikova, J. J. Polym. Sci., C16 (1967), 935.Google Scholar
  123. 123.
    Morikawa, T. Kagaku to Kogyo (Osaka), 41 (1967), 169.Google Scholar
  124. 124.
    Boissel, J. J. Appl. Polym. Sci., 21 (1977), 855.Google Scholar
  125. 125.
    Lee, T. S., Kolthoff, I. M. and Mairs, M. A. J. Polym. Sci., 3 (1948), 66.Google Scholar
  126. 126.
    Müller, K. Functional Group Determination of Olefinic and Acetylenic Unsaturation, Academic Press, New York, 1975, 132.Google Scholar
  127. 127.
    Ahrens, W., Brandstetter, F., Hildenbrand, P. and Simak, P. Paper presented at the Third International Symposium on Poly(vinyl chloride), Cleveland, Ohio, USA, 10-15 August, 1980.Google Scholar
  128. 128.
    Park, G. S. and Saremi, A. A. Unpublished results.Google Scholar
  129. 129.
    Merz, W. and Muller, K. Microchim. Acta., 6 (1974), 60.Google Scholar
  130. 130.
    Braun, D. and Quarg, W. Angew. Makromol. Chem., 29/30 (1973), 163.Google Scholar
  131. 131.
    Lindenschmidt, G. Angew. Makromol. Chem., 47 (1975), 79.Google Scholar
  132. 132.
    Michel, A., Schmidt, G., Castaneda, E. and Guyot, A. Angew. Makromol. Chem., 47 (1975), 61.Google Scholar
  133. 133.
    Abbås, K. B. and Sörvik, E. M. J. Appl. Polym. Sci., 19 (1975), 2991.Google Scholar
  134. 134.
    Minsker, K. S., Lisitskii, V. V., Gataullin, R. F., Saveliev, A. P., Gagarina, L. P. and Gorbatsevskaia, I. I. Plast. Massy, 2 (1980), 6.Google Scholar
  135. 135.
    Minsker, K. S., Berlin, A. A., Lisitskii, V. S. and Kolesov, S.V. Visokomol. Soed., A19 (1977), 32.Google Scholar
  136. 136.
    Caraculacu, A. A. and Bezdadea, E. C. Revue Roum. Chim., 14 (1969), 1171.Google Scholar
  137. 137.
    Caraculacu, A. A. and Bezdadea, E. C. J. Polym. Sci., Polym. Chem. Ed., 15 (1977), 611.Google Scholar
  138. 138.
    Pétiaud, R. and Pham, Q. T. Makromol. Chem., 178 (1977), 741.Google Scholar
  139. 139.
    Schwenk, U., König, I., Cavagna, F. and Wrackmeyer, B. Angew. Makromol. Chem., 83 (1979), 183.Google Scholar
  140. 140.
    IUPAC Working Party on the Characterisation of Defects in the Molecular Structure of Poly(vinyl chloride), unpublished results.Google Scholar
  141. 141.
    Kohn, P., Marechal, C. and Verdu, J. Anal. Chem., 51 (1979), 1000.Google Scholar
  142. 142.
    Sondheimer, F., Ben Efrain, D. A. and Wolovsky, R. J. Am. Chem. Soc., 83 (1961), 1675.Google Scholar
  143. 143.
    Peitscher, G. and Holtrup, W. Angew. Makromol. Chem., 47 (1975), 111.Google Scholar
  144. 144.
    Bassez, C. Thesis, University of Lille, France, 1978.Google Scholar
  145. 145.
    Bier, G. and Krämer, H. Kunststoffe, 46 (1956), 468.Google Scholar
  146. 146.
    Enomoto, S. J. Polym. Sci., A1, 7 (1969), 1255.Google Scholar
  147. 147.
    Caraculacu, A. A., Buruiana, E. C. and Robila, G. J. Polym. Sci., Polym. Chem. Ed., 16 (1978), 2741.Google Scholar
  148. 148.
    Hansen, K. and Ugelstad, J. Makromol. Chem., 180 (1979), 2423.Google Scholar
  149. 149.
    Minsker, K. S., Lisitskii, V. V., Kolinsky, M., Vizmazal, Z., Bort, D.H., Lebedev, V. P., Petzena, A. I. and Il’kaeva, E. M. Plast. Massy, 9 (1977), 44.Google Scholar
  150. 150.
    Minsker, K. S., Lisitskii, V. V., Gataullin, R. F. and Zaikov, G. E. Visokomol. Soed., B20 (1978), 571.Google Scholar
  151. 151.
    Burille, P. Thesis, University Claude Bernard, Lyons, 1979.Google Scholar
  152. 152.
    Robila, G., Buruiana, E. C. and Caraculacu, A. A. Eur. Polym. J., 13 (1977), 21.Google Scholar
  153. 153.
    Caraculacu, A. A. J. Polym. Sci., A1, 4 (1966), 1839.Google Scholar
  154. 154.
    Michel, A., Burille, P. and Guyot, A. Paper presented at the IUPAC 26th International Symposium, Mainz, 1979.Google Scholar
  155. 155.
    Buruiana, E. C., Barbinta, V. T. and Caraculacu, A. A. Eur. Polym. J., 13 (1977), 311.Google Scholar
  156. 156.
    Saremi, A. A. Ph.D. Thesis, University of Wales Institute of Science and Technology, Cardiff, 1981.Google Scholar
  157. 157.
    Hjertberg, T. Thesis, Chalmers University of Technology, Gothenburg, 1982.Google Scholar
  158. 158.
    Berens, A. R. Polym. Eng. Sci., 14 (1974), 318.Google Scholar
  159. 159.
    Crawley, S. and McNeill, I. C. J. Polym. Sci., Polym. Chem. Ed., 16 (1978), 2593.Google Scholar
  160. 160.
    Shimizu, A. and Ohtsu, T. Kogyo Kagaku Zasshi, 67 (1964), 966.Google Scholar
  161. 161.
    Mitani, K., Ogata, T., Awaya, H. and Tomari, Y. J. Polym. Sci., A1, 13 (1975), 2813.Google Scholar
  162. 162.
    Svetly, J., Lukas, R. and Kolinsky, M. Makromol. Chem., 180 (1979), 1363.Google Scholar
  163. 163.
    Zeppenfeld, G. Makromol. Chem., 90 (1966), 109.Google Scholar
  164. 164.
    Getmanenko, E. N. and Perepletchikova, E. Fiz. Khim. Metody Anal., 1 (1976), 75.Google Scholar
  165. 165.
    Mair, R. D. and Graupner, A. J. Anal. Chem., 36 (1964), 194.Google Scholar
  166. 166.
    Decker, C. J. Appl. Polym. Sci., 20 (1976), 3321.Google Scholar
  167. 167.
    Scott, G., Tahan, M. and Vyvoda, J. C. Chem. Ind. (London), 20 (1976), 903.Google Scholar
  168. 168.
    Nagy, T. T., Kelen, T., Turcsanyi, B. and Tüdos, F. Plaste u. Kautschuk, 23 (1976), 894.Google Scholar
  169. 169.
    Abbås, K. B. and Sörvik, E. M. J. Appl. Polym. Sci., 17 (1973), 3577.Google Scholar
  170. 170.
    Arlman, A. J. J. Polym. Sci., 12 (1954), 547.Google Scholar
  171. 171.
    Geddes, W. C. Rubber Chem. Technol., 40 (1967), 177.Google Scholar
  172. 172.
    Druesedow, D. and Gibbs, C. F. Nat. Bur. Stand. Circular, 525 (1953), 69.Google Scholar
  173. 173.
    Havens, C. B. Nat. Bur. Stand. Circular, 525 (1953), 107.Google Scholar
  174. 174.
    Imoto, M. and Otsu, T. J. Inst. Polytech., Osaka City Univ., Ser. C, 4 (1953), 1.Google Scholar
  175. 175.
    Rieche, A., Grimm, A. and Mücke, H. Kunststoffe, 52 (1962), 265.Google Scholar
  176. 176.
    Bengough, W. I. and Sharpe, H. M. Makromol. Chem., 66 (1963), 31.Google Scholar
  177. 177.
    Stepek, J., Vymazal, Z. and Dolezel, B. Mod. Plast., 40 (1963), 146.Google Scholar
  178. 178.
    Talamini, G., Cinque, G. and Palma, G. Mat. Plast. Mod., 32 (1966), 50.Google Scholar
  179. 179.
    Guyot, A. and Benevise, J. P. J. Appl. Polym. Sci., 6 (1962), 98.Google Scholar
  180. 180.
    ASTM Method D793-49 (1965).Google Scholar
  181. 181.
    Vymazal, Z., Dolezel, B. and Stepek, J. Kunststoffe, 56 (1966), 86.Google Scholar
  182. 182.
    Minsker, K. S., Krats, E. O. and Pakhomova, I. K. Vysokomol. Soedin, A12 (1970), 483.Google Scholar
  183. 183.
    Cittadini, A. and Palillo, R. Chim. Ind. (Milan), 41 (1966), 980.Google Scholar
  184. 184.
    Marks, G. C., Benton, J. L. and Thomas, C. M. S.C.I. Monograph, 26 (1967), 204.Google Scholar
  185. 185.
    Geddes, W. C. Eur. Polym. J., 3 (1967), 267.Google Scholar
  186. 186.
    Laczkó, M. Plast. Kaut., 17 (1970), 25.Google Scholar
  187. 187.
    Stapfer, C. H. and Granick, J. D. Proc. 161st A.C.S. Meeting, Organic Coatings and Plastic Chemistry, 31 (1971), 204.Google Scholar
  188. 188.
    Arlman, E. J. J. Polym. Sci., 12 (1954), 547.Google Scholar
  189. 189.
    Baum, B. and Wartman, L. H. J. Polym. Sci., 28 (1958), 537.Google Scholar
  190. 190.
    Talamini, G. and Pezzin, G. Makromol. Chem., 39 (1960), 26.Google Scholar
  191. 191.
    Braun, D. and Thallmaier, M. Kunststoffe, 56 (1960), 80.Google Scholar
  192. 192.
    Guyot, A. and Bert, M. Polymer Preprints, 12 (1971), 303.Google Scholar
  193. 193.
    Abbås, K. B. and Sörvik, E. M. J. Appl. Polym. Sci., 17 (1973), 3567.Google Scholar
  194. 194.
    Abbås, K. B. J. Macromol. Sci. Chem., A12 (1978), 479.Google Scholar
  195. 195.
    Braun, D. and Thallmaier, M. Makromol. Chem., 99 (1966), 59.Google Scholar
  196. 196.
    Scott, A. I. Interpretation of the Ultraviolet Spectra of Natural Products, International Series of Monographs on Organic Chemistry, Vol. 7, Pergamon Press, New York, 1964.Google Scholar
  197. 197.
    Braude, E. A. J. Chem. Soc. (1950), 379.Google Scholar
  198. 198.
    Popov, K. P. and Smirnov, L. V. Optika Spektroskopiya, 14 (1963), 787.Google Scholar
  199. 199.
    Braun, D. Pure Appl. Chem., 26 (1971), 173.Google Scholar
  200. 200.
    Daniels, V. D. and Rees, N. H. J. Polym. Sci., Polym. Chem. Ed., 12 (1974), 2115.Google Scholar
  201. 201.
    Woodward, R. B. J. Amer. Chem. Soc., 64 (1942), 72.Google Scholar
  202. 202.
    Hirayama, K. J. Amer. Chem. Soc., 77 (1955), 373, 382.Google Scholar
  203. 203.
    Naylor, P. and Whiting, M. C. J. Chem. Soc. (1955), 3037.Google Scholar
  204. 204.
    Ferguson, L. N. Chem. Rev., 43 (1948), 385.Google Scholar
  205. 205.
    Matsumoto, T., Mune, I. and Watatani, S. J. Polym. Sci., Al, 7 (1969), 1609.Google Scholar
  206. 206.
    Schlimper, R. Plaste Kautschuk, 13 (1966), 196.Google Scholar
  207. 207.
    Schlimper, R. Plaste Kautschuk, 14 (1967), 657.Google Scholar
  208. 208.
    Onozuka, M. and Asahini, M. J. Macromol Sci., C3 (1969), 235.Google Scholar
  209. 209.
    Gerrard, D. L. and Maddams, W. F. To be published.Google Scholar
  210. 210.
    Liebman, S. A., Foltz, C. R., Reuwer, J. F. and Obremski, R. J. Macromolecules, 4 (1971), 134.Google Scholar
  211. 211.
    Liebman, S. A., Ahlstrom, D. H., Quinn, E. J., Geigley, A. G. and Meluskey, J.T. J. Polym. Sci., A1, 9 (1971), 1921.Google Scholar
  212. 212.
    Rimai, L., Kilponen, E. G. and Gill, D. J. Amer. Chem. Soc., 92 (1970), 3824.Google Scholar
  213. 213.
    Gerrard, D. L. and Maddams, W. F. Macromolecules, 8 (1975), 54.Google Scholar
  214. 214.
    Gerrard, D. L. and Maddams, W. F. Macromolecules, 10 (1977), 1221.Google Scholar
  215. 215.
    Biggin, I. S., Gerrard, D. L. and Williams, G. E. J. Vinyl Tech., 4 (1982), 150.Google Scholar
  216. 216.
    Gerrard, D. L. and Maddams, W. F. Macromolecules, 14 (1981), 1356.Google Scholar
  217. 217.
    Tonks, D. L. and Page, J. B. Chem. Phys. Lett., 66 (1979), 449.Google Scholar
  218. 218.
    Hizhnyakov, V. and Tehver, I. Phys. Status Solidi, 21 (1967), 755.Google Scholar
  219. 219.
    Hassing, S. and Mortensen, O. S. J. Chem. Phys., 73 (1980), 1078.Google Scholar

Copyright information

© Elsevier Applied Science Publishers Ltd 1984

Authors and Affiliations

  • W. F. Maddams
    • 1
  1. 1.The British Petroleum Company plcSunbury-on-Thames, MiddlesexUK

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