Abstract
This article reviews the structural characterization, by means of rotational spectroscopy, of a number of complexes of HF, H2O, NH3, and HCN. In addition to the complexes of each of these hydrides with each other, the complexes with CO, CO2, C2H2, and C2H4 are also examined. The studies of the complexes of NH3 are complemented by recently obtained infrared-microwave double resonance results.
Supported by the National Science Foundation.
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References
F. Franks, “Water, A Comprehensive Treatise,” Vol. 4–6, (Plenum, New York, 1972).
R. Taylor and O. Kennard, Acc. Chem. Res. 17, 320 (1984).
G.C. Pimentel and A.D. McClellan, “The Hydrogen Bond,” (Freeman, San Francisco, 1960).
T.C. English and J.C. Zorn, “Methods of Experimental Physics,” Vol. 3 (2nd Edition), D. Williams, ed. (Academic Press, Inc., New York, 1972).
T.J. Balle, E.J. Campbell, M.R. Keenam and W.H. Flygare, J. Chem. Phys. 71, 2723 (1979).
Z. Kisiel, A.C. Legon and D.J. Milien, Proc. R. Soc. London A 381 , 419 (1982).
G.T. Fraser, D.D. Nelson, Jr., A. Charo and W. Klemperer, J. Chem. Phys., to be published.
S.A. Clough, Y. Beers, G.P. Klein and L.S. Rothman, J. Chera. Phys. 59, 2254 (1973).
M.D. Marshall and J.S. Muenter, J. Mol. Spect. 85, 322 (1981).
J.S. Muenter and W. Klemperer, J. Chem. Phys. 52, 6033 (1970).
J.S. Muenter, J. Mol. Spec. 55, 490 (1975).
W.L. Ebenstein and J.S. Muenter, J. Chem. Phys. 80, 3989 (1984).
T.R. Dyke, K.M. Mack and J.S. Muenter, J. Chem. Phys. 66, 498 (1977).
K.I. Peterson and W. Klemperer, J. Chem. Phys. 81, 3842 (1984).
T.R. Dyke, Top. Current Chem. 120, 85 (Spring-Verlag, N.Y., 1984).
T.A. Fisher, K.I. Peterson and W. Klemperer, work in progress.
K.I. Peterson and W. Klemperer, J. Chem. Phys., manuscript in preparation.
P.D. Aldrich, A.C. Legon and W.H. Flygare, J. Chem. Phys. 75, 2126 (1981).
A.J. Fillery-Travis, A.C. Legon and L.C. Willoughby, Chem. Phys. Lett. 98, 369 (1983).
C.R. Quade, J. Chem. Phys. 47, 1073 (1967).
M.J. Frisch, J.A. Pople and J.E. Del Bene, J. Chem. Phys. 78, 4063 (1983).
G.T. Fraser, K.R. Leopold and W. Klemperer, J. Chem. Phys. 80, 1423 (1984).
G.T. Fraser, K.R. Leopold, D.D. Nelson, Jr., A. Tung and W. Klemperer, J. Chem. Phys. 80, 3073 (1984).
B.J. Howard, private communication.
G.T. Fraser, K.R. Leopold and W. Klemperer, J. Chem. Phys. 81, 2577 (1984).
G.T. Fraser, D.D. Nelson, Jr. and W. Klemperer, work in progress.
Z. Latajka and S. Scheiner, J. Chem. Phys. 81, 407 (1984) and references therein.
R.L. DeLeon and J.S. Meunter, J. Chem. Phys. 72, 6020 (1980).
The 10 K rotational temperature of the van der Waals dimers is suggested by previous microwave studies of weakly bound complexes. See, for example, K.R. Leopold, G.T. Fraser and W. Klemperer, J. Chem. Phys. 80, 1039 (1984).
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Peterson, K.I., Fraser, G.T., Nelson, D.D., Klemperer, W. (1985). Intermolecular Interactions Involving First Row Hydrides: Spectroscopic Studies of Complexes of HF, H2O, NH3, and HCN. In: Bartlett, R.J. (eds) Comparison of Ab Initio Quantum Chemistry with Experiment for Small Molecules. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5474-8_8
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DOI: https://doi.org/10.1007/978-94-009-5474-8_8
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