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Molecular Ions in Astrophysics and in the Laboratory

  • Chapter
Molecular Astrophysics

Part of the book series: NATO ASI Series ((ASIC,volume 157))

Abstract

Singly-charged molecular cations are present in stellar and planetary atmospheres, in comets, and in the interstellar medium. Laboratory studies of molecular ions are required to support astrophysical observation and interpretation. The range of such investigations is discussed and techniques are presented for the study of radiative and nonradiative transitions in molecular ions. Astrophysical applications are made of the results of several different types of laboratory studies. A discussion is also given concerning the possible formation and direct or indirect observation of doubly-charged molecular cations in astrophysical situations.

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References

  1. Dalgarno, A. and McCray, R.A., 1973, Ap. J. 181, 95.

    Article  ADS  Google Scholar 

  2. Exarhos, G.H., Mayer, J. and Klemperer, W., 1981, Phil. Trans. R. Soc. Lond. A303, 503.

    Article  ADS  Google Scholar 

  3. Vardya, M.S., 1967, Mem. Roy. Astron. Soc. 71, 249

    ADS  Google Scholar 

  4. Sarre, P.J., 1980, J. Chim. Phys. 77, 769.

    Google Scholar 

  5. Vardya, M.S. and Krishna Swamy, K.S. 1980, Chem. Phys. Lett. 73, 616.

    Article  ADS  Google Scholar 

  6. Leach, S.,1979, J. Chim. Phys. 76, 1043.

    Google Scholar 

  7. Leach, S., 1980, J. Chim. Phys. 77, 585.

    Google Scholar 

  8. Stebbings, R.F., and Dunning, F.B. (editors), “Rydberg states of atoms and molecules”, 1983, Cambridge Univ. Press, Cambridge U.K.

    Google Scholar 

  9. Ferguson, E.E., Fehsenfeld, F.C. and Albritton, D.L., 1979 in “Gas Phase Ion Chemistry” (ed. M.T. Bowers), Academic, N.Y. Vol. 1, pp. 45–82.

    Google Scholar 

  10. Woods, R.C., 1983 in “Molecular Ions: Spectroscopy, Structure and Chemistry” (eds. T.A. Miller and V.E. Bondybey), North-Holland, Amsterdam, pp. 11–47.

    Google Scholar 

  11. Saykally, R.J., 1984, this volume.

    Google Scholar 

  12. Jacox, M., 1978, Rev. Chem. Interned. 2, pp. 1–36.

    Article  Google Scholar 

  13. Andrews, L., 1983, in “Molecular Ions: Geometric and Electronic Structures” (eds. J. Berkowitz and K.O. Groenveld), Plenum, N.Y., pp. 153–182 and 183–215.

    Google Scholar 

  14. Cossart, D., J. Chim. Phys. 76, 1045.

    Google Scholar 

  15. Cossart, D., J. Chim. Phys. 78, 703.

    Google Scholar 

  16. Brown, R.D., Godfrey, P.D., McGilvery, D.C., and Crofts, J.G., 1981, Chem. Phys. Lett. 84, 437

    Article  ADS  Google Scholar 

  17. Winn, J.S., 1983, in “Molecular Ions: Geometric and Electronic Structures” (eds. J. Berkowitz and K.O. Groenveld), Plenum, pp. 53–67.

    Google Scholar 

  18. Miller, T.A., and Bondybey, V.E., 1980, J. Chim. Phys. 77, 695.

    Google Scholar 

  19. Allison, J., Kondow, T., and Zare, R.N., 1979, Chem. Phys. Lett 64, 202.

    Article  ADS  Google Scholar 

  20. Johnson, M.A., Zare, R.N., Rostas, J., and Leach, S., 1984, J. Chem. Phys. 80, 2407.

    Article  ADS  Google Scholar 

  21. Mchlmann, G.R., and de Heer, F.J., 1977, Phys. Scripta 16, 51.

    Article  ADS  Google Scholar 

  22. Erman, P., 1984, this volume.

    Google Scholar 

  23. Maier, J.P., Ochsner, M., and Thommen, F., 1983, Faraday Disc. Chem. Soc. 75, 77.

    Article  Google Scholar 

  24. Leach, S., 1985, in “Photophysics and Photochemistry in the Vacuum Ultraviolet”, (S. McGlynn, G. Findley and R. Huebner, eds.) Reidel, Dordrecht, p. 297.

    Google Scholar 

  25. Curtis, L.J., and Erman, P., 1977, J. Opt. Soc. Am. 67, 1218.

    Article  ADS  Google Scholar 

  26. Moseley, J., and Durup, J., 1980, J. Chim. Phys. 77, 673.

    Google Scholar 

  27. Cosby, P.C., Möller, R., and Helm, H., 1983, Phys. Rev. A28, 766.

    Google Scholar 

  28. Cosby, P.C., Moseley, J.T., Peterson, J.R., and Ling, J.H., 1978, J. Chem. Phys. 69, 2771.

    Article  ADS  Google Scholar 

  29. Rabelais, J.W., 1977, “Principles of Ultraviolet Photoelectron Spectroscopy”, Wiley, N.Y.

    Google Scholar 

  30. Brion, C.E., and Hamnett, A., 1981, Adv. Chem. Phys. 45, 2.

    Google Scholar 

  31. Herzberg, G., 1971, Quart. Rev. Chem. Soc. 25, 201.

    Article  Google Scholar 

  32. Bondybey, V.E., English, J.H., and Miller, T.A., 1980, J. Chem. Phys. 81, 455.

    Google Scholar 

  33. Leach, S., 1976, in “Spectroscopy of the Excited State”, (ed. B. di Bartolo), Plenum, N.Y., pp. 369–375.

    Google Scholar 

  34. Klapstein, D., Leutwyler, S., Maier, J.P., Cossart-Magos, C., Cossart, D., and Leach, S., 1984, Mol. Phys. 51, 413.

    Article  ADS  Google Scholar 

  35. Rosenstock, H.M., 1968, Adv. Mass Spectrom. 4, 523.

    Google Scholar 

  36. Herzberg, G., 1966, “Electronic Spectra of Polyatomic Molecules”, Van Nostrand, N.Y.

    Google Scholar 

  37. Gelbart, W.M., 1977, Ann. Rev. Phys. Chem. 28, 323.

    Article  ADS  Google Scholar 

  38. Freed, K.F., 1976, Top. Appl. Phys. 15, 23

    Article  Google Scholar 

  39. Avouris, P., Gelbart, W.M., and El Sayed, M.A., Chem. Revs. 77, 793.

    Google Scholar 

  40. Leach, S., Dujardin, G., and Taieb, G., 1980, J. Chim. Phys. 77, 705.

    Google Scholar 

  41. Chesnavich, W.J., and Bowers, M.T., 1979, in “Gas Phase Ion Chemistry” Vol. 1 (M.T. Bowers, ed.) Academic, N.Y., pp. 119–151.

    Google Scholar 

  42. Lorquet, J.C., Dehareng, D., Sannen, C., and Raseev, G., 1980, J. Chim. Phys. 77, 719.

    Google Scholar 

  43. Dujardin, G., Govers, T., and Leach, S., to be published.

    Google Scholar 

  44. Dujardin, G., Leach, S., Dutuit, O., Guyon, P-M., and Richard-Viard, M., 1984, Chem. Phys. 88, 339.

    Article  Google Scholar 

  45. Baer, T., 1979, in “Gas Phase Ion Chemistry”, Vol. 1 (M.T. Bowers, ed.), Academic, N.Y. pp. 153–196.

    Google Scholar 

  46. Smith, D., and Adams, N.G., 1985, this volume.

    Google Scholar 

  47. Rowe, B., 1985, this volume.

    Google Scholar 

  48. Field, F.H., 1968, Adv. Mass Spectrom. 4, 645.

    Google Scholar 

  49. Harrison, A.G., 1983, “Chemical Ionization Mass Spectrometry”, C.R.C. Press, Boca Raton.

    Google Scholar 

  50. Govers, T.R., Guyon, P-M., Baer, T., Cole, K., Frohlich, H., and Lavollee, M., 1984, Chem. Phys. 87, 373.

    Article  Google Scholar 

  51. McLafferty, F.W., 1980, “interpretation of Mass Spectra”, 3rd edition, Univ. Sci. Books, Calif.

    Google Scholar 

  52. Calvert, J.G., and Pitts, J.N., Jr., 1966, “Photochemistry”, Wiley, N.Y.

    Google Scholar 

  53. Horani, M., and Leach, S., 1959, Comptes Rendus Ac. Sci. (Paris) 248, 2196.

    Google Scholar 

  54. Horani, M., and Leach, S., 1961, J. Chim. Phys. 58, 825.

    Google Scholar 

  55. Horani, M., 1967, J. Chim. Phys. 64, 331.

    Google Scholar 

  56. Cossart, D., 1974, These d’Etat, Universite Paris-Sud, Orsay.

    Google Scholar 

  57. Leach, S., and Dujardin, G., 1983, Laser Chem. 2, 285.

    Article  Google Scholar 

  58. Eland, J.H.D., Devoret, M., and Leach, S., 1976, Chem. Phys. Lett. 43, 97.

    Article  ADS  Google Scholar 

  59. Dujardin, G., Leach, S., and Taieb, G., 1980, Chem. Phys. 46, 407.

    Article  Google Scholar 

  60. Maier, J.P., and Thommen, F., 1980, Chem. Phys. 51, 319.

    Article  ADS  Google Scholar 

  61. Winkoun, D., Dujardin, G., and Leach, S., 1984, Can. J. Phys., in press

    Google Scholar 

  62. Dujardin, G., Leach, S., Dutuit, O., Govers, T., and Guyon, P.-M., 1983, J. Chem. Phys. 79, 644.

    Article  ADS  Google Scholar 

  63. Gauyacq, D., and Horani, M., 1978, Can. J. Phys. 56, 587.

    Article  ADS  Google Scholar 

  64. Ferlet, R., Roueff, E., Horani, M., and Rostas, J., 1983, Astron. Astrophys. 125, L5.

    ADS  Google Scholar 

  65. Horani, M., Leach, S., and Rostas, J., 1963, Vie Conf. Int. Phenom. Ionisation dans les Gaz, Vol. 1 (S.E.R.M.A.) p. 45.

    Google Scholar 

  66. Horani, M., Leach, S., and Rostas, J., 1967, J. Molec. Spectrosc. 23, 115.

    Article  ADS  Google Scholar 

  67. Rostas, J., Horani, M., Brion, J., Daumont, D., and Malicet, J., 1984, Mol. Phys. 52, 1431.

    Article  Google Scholar 

  68. Edwards, C.P., Maclean, C.S., and Sarre, P. J., 1984, Mol. Phys. 52, 1453.

    Article  Google Scholar 

  69. Horani, M., Rostas, J., and Roueff, E., 1984, Astron. Astrophys., submitted.

    Google Scholar 

  70. Oppenheimer, M., and Dalgarno, A., 1974, Ap. J. 187, 231.

    ADS  Google Scholar 

  71. Dalgarno, A., 1981, Phil. Trans. Roy. Soc. (London) A303, 513.

    ADS  Google Scholar 

  72. Huebner, W.F., 1985, this volume.

    Google Scholar 

  73. Dixon, R.N., Duxbury, G., Horani, M., and Rostas, J., 1971, Mol. Phys. 22, 977.

    Article  ADS  Google Scholar 

  74. Duxbury, G., Horani, M., and Rostas, J., 1972, Proc. Roy. Soc. Lond. A331 , 109.

    ADS  Google Scholar 

  75. Herbig, G.H., 1976, in “The Study of Comets”, I.A.U. Colloq. N° 25 (ed. B. Donn, M. Mumma, W. Jackson, M. A’Hearn and R. Harrington) NASA SP-393, p. 136.

    Google Scholar 

  76. Wehinger, P.A., Wyckoff, S., Herbig, G.H., Herzberg, G., and Lew, H., 1974, Ap. J., 190, L43.

    Article  ADS  Google Scholar 

  77. Cosmovici, C.B., Barbieri, C., Bonoli, C., Bortoletto, F., and Hamzaoglu, E., 1982, Astron. Astrophys. 114, 373.

    ADS  Google Scholar 

  78. Cosmovici, C.B., and Ortolani, S., 1984, Nature 310, 122.

    Article  ADS  Google Scholar 

  79. Dujardin, G., and Leach, S., 1981, J. Chem. Phys. 75, 2521.

    Article  ADS  Google Scholar 

  80. Devoret, M., 1976, Thèse Dr. 3e cycle, Univ. Paris-Sud, Orsay.

    Google Scholar 

  81. Dujardin, G., and Leach, S., 198U, Can. J. Chem., submitted.

    Google Scholar 

  82. Braitbart, O., Castellucci, E., Dujardin, G., and Leach, S., 1983, J. Phys. Chem. 87, 4799.

    Article  Google Scholar 

  83. Dujardin, G., Leach, S., Taieb, G., Maier, J.P., and Gelbart, W.M., 1980, J. Chem. Phys. 73, 4987.

    Article  ADS  Google Scholar 

  84. Herzberg, G., 1980, in “Interstellar Molecules”, I.A.U. Symposium 87 (ed. B.H. Andrews) p, 231.

    Google Scholar 

  85. Gauyacq, D., Horani, M., Leach, S., and Rostas, J., 1975, Can. J. Phys. 53, 2040.

    Article  ADS  Google Scholar 

  86. Gauyacq, D., Larcher, C., and Rostas, J., 1979, Can. J. Phys. 57, 1634.

    Article  ADS  Google Scholar 

  87. Barth, C.A., Fastie, W.G., Hord, C.W., Pearce, J.B., Kelly, K.K., Stewart, A.I., Thomas, G.E., Anderson, G.P., and Raper, O.F., 1969, Science 76, 1004.

    Article  ADS  Google Scholar 

  88. Barth, C.A., Hord, C.W., Pearce, J.B., Kelly, K.K., Anderson, P., and Stewart, A.I., 1971, J. Geophys. Res. 76, 2213.

    Article  ADS  Google Scholar 

  89. Stewart, A.I., 1972, J. Geophys. Res. 77, 54.

    Article  ADS  Google Scholar 

  90. Stewart, A.I., Barth, C.A., Hord, C.W., and Lane, A.L., 1972, Icarus 167, 469.

    Article  ADS  Google Scholar 

  91. Dalgarno, A., Degges, T.C., and Stewart, A.I., 1970, Science 167, 1490.

    Article  Google Scholar 

  92. Dalgarno, A., and Degges, T.C., 1971, in “Planetary Atmospheres”, I.A.U. Symposium N° 40 (eds. C. Sagan, T.C. Owen and H. J. Smith), Springer Verlag, N.Y., pp. 337–345.

    Google Scholar 

  93. McConnell, J.C., 1973, in “Physics and Chemistry of Upper Atmospheres” (ed. B.M. McCormac), Reidel, Dordrecht, pp. 309–334.

    Google Scholar 

  94. Leach, S., 1977, 1980, “Les Spectres des Molecules Simples au Laboratoire et en Astrophysique”, 21st Int. Colloq. Astrophys. Liege, pp. 403–421.

    Google Scholar 

  95. Nier, A.O., Hanson, W.B., Seiff, A., McElroy, M.B., Spencer, N.W., Duckett, R.J., Knight, T.C.D., and Cook, W.S., 1976, Science 193, 786.

    Article  ADS  Google Scholar 

  96. Leach, S., Devoret, M., and Eland, J.H.D., 1978, Chem. Phys. 33, 113.

    Article  Google Scholar 

  97. Leach, S., Stannard, P.R., and Gelbart, W.M., 1978, Mol. Phys. 36, 1119.

    Article  ADS  Google Scholar 

  98. Fox, J.L., and Dalgarno, A., 1979, J. Geophys. Res. 7315.

    Google Scholar 

  99. Swings, P., 1969, Proc. Am. Philos. Soc. 113, 229.

    ADS  Google Scholar 

  100. Polyakova, G.N., Fogel, Y.M., and Chiu, Y.M., 1963, Sov. Astron. AJ 7, 276.

    ADS  Google Scholar 

  101. Festou, M.C., Feldman, P.D., and Weaver, H.A. 1982, Ap. J. 256, 331.

    Article  ADS  Google Scholar 

  102. Tsai, B.P., and Eland, J.H.D., 1980, Int. J. Mass Spectrom. Ion Phys. 36, 143.

    Article  Google Scholar 

  103. See references 14–18 cited in reference 43.

    Google Scholar 

  104. Carroll, P.K., 1958, Can. J. Phys. 36, 1585.

    Article  ADS  Google Scholar 

  105. Bearman, G.H., Ranjbar, F., Harris, H.H., and Leventhal, J.J., 1976, Chem. Phys. Lett. 42, 335.

    Article  ADS  Google Scholar 

  106. Kemp, D.L., and Cooks, R.G., 1978 in “Collision Spectroscopy” (ed. R.G. Cooks), Plenum, N.Y., pp. 257–288.

    Google Scholar 

  107. Nikol’skij, G.M., in Handbuch der Physik (S. Flugge ed.), 1982, Vol. 49/6, Geophysik III, Part 6, pp. 309–377.

    Google Scholar 

  108. Lyon, I.C., Peart, B., West, J.B., Kingston, A.E., and Dolder, K., 1984, J. Phys. B17, L345.

    ADS  Google Scholar 

  109. Appell, J., 1978 in “Collision Spectroscopy” (ed. R.G. Cooks) Plenum, N.Y., pp. 227–256.

    Google Scholar 

  110. Daly, N.R., and Powell, R.E., 1966, Proc. Phys. Soc. (London) 89, 273.

    Article  ADS  Google Scholar 

  111. Kieffer, L.J., and Dunn, G.H., 1966, Rev. Mod. Phys. 38, 1.

    Article  ADS  Google Scholar 

  112. Falk, R.A., and Dunn, G.H., 1983, Phys. Rev. A27, 754.

    Google Scholar 

  113. Watson, W.D., and Kunz, A.B., 1975, Ap. J. 201, 165.

    Article  ADS  Google Scholar 

  114. Capone, L.A., Prasad, S.S., Huntress, W.T., Whitten, R.C., Dubach, J., and Santhanam, K., 1981, Nature 293, 45.

    Article  ADS  Google Scholar 

  115. Speller, C.V., Fitaire, M., and Pointu, A.M., 1982, Nature 300, 507.

    Article  ADS  Google Scholar 

  116. Cayrel, R., and Felenbock, P., (eds.), “Haute Resolution Spectrale en Astrophysique: Applications au Telescope Spatial”, 2e Colloque National du Conseil Frangais du Telescope Spatial, Orsay 10–12 March, 1981.

    Google Scholar 

  117. Field, G.B., (guest editor), “Special Issue: New Instruments for Astronomy”, 1982, Physics Today 35, N° 11, pp. 25–67.

    Google Scholar 

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Leach, S. (1985). Molecular Ions in Astrophysics and in the Laboratory. In: Diercksen, G.H.F., Huebner, W.F., Langhoff, P.W. (eds) Molecular Astrophysics. NATO ASI Series, vol 157. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5432-8_13

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  • DOI: https://doi.org/10.1007/978-94-009-5432-8_13

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