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Photoelectron Spectroscopy of f-Element Organometallic Complexes

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Fundamental and Technological Aspects of Organo-f-Element Chemistry

Part of the book series: NATO ASI Series ((ASIC,volume 155))

Abstract

Photoelectron spectroscopy (p.e.s.) has had a remarkable impact on studies of the electronic structure of every kind of molecule since 1968. Its role has been confirmatory with respect to molecular orbital (MO) models and has presented a continuous stimulus for improvements of MO theoretical approaches.

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References

  1. This book.

    Google Scholar 

  2. Marks, T. J.; Ernst, R. D. in “Comprehensive Organometallic Chemistry”; Wilkinson, G. W.; Stone, F. G. A.; Abel, E. W., Eds. Pergamon Press: Oxford, 1982, Chapter 21.

    Google Scholar 

  3. “Actinides in Perspective”; Edelstein, N. H., Ed. Pergamon Press: Oxford, 1982.

    Google Scholar 

  4. “Organometallics of f-Elements”; Marks, T. J.; Fischer, R. D.; Eds. Reidel: Dordrecht, The Netherlands, 1979; p 421.

    Google Scholar 

  5. Ciliberto, E.; Condorelli, G.; Fagan, P. J.; Manriquez, J. M.; Fragalà, I.; Marks, T. J. J. Am. Chem. Soc. 1981, 103, 4755.

    Article  CAS  Google Scholar 

  6. Fragalà, I. L.; Goffart, J.; Granozzi, G.; Ciliberto, E. Inorg. Chem. 1983, 22, 216.

    Article  Google Scholar 

  7. Casarin, M.; Ciliberto, E.; Fragalà, I. L.; Granozzi, G. Inorg. Chim. Acta 1982, 64, L247.

    Article  CAS  Google Scholar 

  8. Down, A. J.; Egdell, R. G.; Orchard, A. F.; Thomas, P. D. P. J. Chem. Soc., Faraday Trans. 1978, 2.

    Google Scholar 

  9. Clark, J. P.; Green, J. C. J. Chem. Soc., Dalton Trans. 1978, 505.

    Google Scholar 

  10. Fragalà, I. L.; Condorelli, G.; Zanella, P.; Tondello, E. J. Organomet. Chem. 1976, 122, 357.

    Article  Google Scholar 

  11. Fragala, I. L.; Ciliberto, E.; Sienel, G.; Fischer, R. D.; Zanella, P. J. Organomet. Chem.. 1976, 120, C9.

    Article  CAS  Google Scholar 

  12. Fragalà, I. L.; Condorelli, G.; Tondello, E.; Cassol, A. Inorg. Chem. 1978, 17, 3175.

    Article  Google Scholar 

  13. Green, J. C.; Payne, P. M.; Streitwieser, A., Jr. Organometallics 1983, 2, 12, 1.

    Article  Google Scholar 

  14. Bruno, G.; Ciliberto, E.; Fischer, R. D.; Fragalà, I.; Spiegel, A. W. Organometallics 1982, 1, 1060.

    Article  CAS  Google Scholar 

  15. Ballard, R. E. “Photoelectron Spectroscopy and Molecular Orbital Theory”; Adam Hilger Ltd.: Bristol, 1978.

    Google Scholar 

  16. Rabalais, J. W. “Principles of Ultraviolet Photoelectron Spectroscopy”; Wiley: New York, 1977; p. 335.

    Google Scholar 

  17. Berkowitz, J. “Photoabsorption, Photoionization, and Photoelectron Spectroscopy”; Academic Press: New York, 1979.

    Google Scholar 

  18. Schwartz, E. M. in spivn“Application of Electronic Structure Theory”; Shaefer, F. H., Ed. Plenum Press: New York, 1977; Vol. 4, Chapter 9.

    Google Scholar 

  19. Böhm, M. C. J. Chem. Phys. 1983, 78 (12), 7044.

    Article  Google Scholar 

  20. Meyer, W., in ref. 4, Vol. 3, Chapter II.

    Google Scholar 

  21. Veillard, A.; Dermuynck, J., in ref. 4, Chapter 5.

    Google Scholar 

  22. Ellis, D. E., in ref. 1c, p 123 and references therein.

    Google Scholar 

  23. McLean, A. D.; Lee, Y. S. in “Current Aspects of Quantum Chemistry”; Carbo, R., Ed. Elsevier: Amsterdam, 1981; p. 219.

    Google Scholar 

  24. Hay, P. J. in “Relativstic Effects in Atoms, Molecules, and Solids”; Malli, G. L., Ed. Plenum Press: New York, 1983; p. 383.

    Google Scholar 

  25. Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195.

    Article  Google Scholar 

  26. Weber, J.; Berthou, H.; Jorgensen, C. K. Chem. Phys. 1977, 26, 69.

    Article  CAS  Google Scholar 

  27. Thornton, G.; Edelstein, N. M.; Rösch, N.; Egdell, R. G.;Woodwark, D. R. J. Chem. Phys. 1979, 70, 5218

    Article  CAS  Google Scholar 

  28. Thornton, G.; Rösch, N.; Edelstein, N. M. Inorg. Chem. 1980, 19, 1304.

    Article  CAS  Google Scholar 

  29. Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237.

    Article  Google Scholar 

  30. Rösch, N. Inorg. Chim. Acta 1984, 94, 297.

    Article  Google Scholar 

  31. Clark, D. W.; Warren, K.D. J. Organomet. Chem. 1976, 122C, 28.

    Google Scholar 

  32. Le-Min, L.; Jing-Quing, R.; Guang-Xiau, X.; Yiu-Zen, W. Int. J. Quant. Chem. 1983, 23, 1305.

    Article  Google Scholar 

  33. Bacon, A. D.; Zemer, M.C. Theoret. Chim. Acta 1979, 53, 21

    Article  CAS  Google Scholar 

  34. Zerner, M. C.; Loew, G. H.; Kirchner, R. F.; Mueller-Westerhoff, U. T. J. Am. Chem. Soc. 1980, 102, 589.

    Article  CAS  Google Scholar 

  35. Tatsumi, K.; Hoffmann, R. Inorg. Chem. 1980, 19, 2656.

    Article  CAS  Google Scholar 

  36. Pyykkö, P.; Lohr, L. L. Inorg. Chem. 1981, 20, 1950.

    Article  Google Scholar 

  37. Cox, P. A.; Evans, S.; Orchard, A. F.; Richardson, N.V.; Roberts, P. J. J. Chem. Soc., Faraday Discuss. 1972, 32.

    Google Scholar 

  38. Cox, P. A. Struct. Bonding 1975, 34, 59.

    Google Scholar 

  39. Cox, P. A.; Baer, Y.; Jorgensen, C. K. Chem. Phys. Lett. 1973, 22, 433.

    CAS  Google Scholar 

  40. Ruscic, B.; Goodman, G. L.; Berkowitz, J. J. Chem. Phys. 1983, 78(9), 5443.

    Article  CAS  Google Scholar 

  41. Gelius, V. in “Electron Spectroscopy”; Shirley, D. A., Ed. North-Holland Publishing Co.: Amsterdam, 1972; p. 311.

    Google Scholar 

  42. Egdell, R. C. Ph.D. Thesis, Oxford, 1979.

    Google Scholar 

  43. Fragalà, I.; Ciliberto, E.; Rösch, N.; Streitwieser, A., Jr.; Kinsley, S. A. J. Am. Chem. Soc., submitted.

    Google Scholar 

  44. Ciliberto, E.; Bursten, B. E.; Casarin, M.; Ellis, D. E.; Fragalà, I.; Marks, T. J. J. Am. Chem. Soc., submitted.

    Google Scholar 

  45. Miller, S. S.; Day, V. W.; Marks, T. J., manuscript in preparation.

    Google Scholar 

  46. Koelling, D. D.; Ellis, D. E.; Barlet, R. J. J. Chem. Phys. 1976, 65, 3331.

    Article  CAS  Google Scholar 

  47. Boring, M.; Moskowitz, J. W. Chem. Phys. Lett. 1976, 38, 185, and references therein.

    Article  CAS  Google Scholar 

  48. Martensson, N.; Malmquist, P. A.; Svensson, S. Chem. Phys. Lett. 1983, 100, 375;

    Article  Google Scholar 

  49. Martensson, N.; Malmquist, P. A.; Svensson, S.; Johansson, E. J. Chem. Phys. 1984, 80, 5458.

    Article  Google Scholar 

  50. Larsson, S.; Tse, J. S.; Esquivel, J. L.; Tan Kai, A. Chem. Phys. Lett. 1984, 109, 43.

    Google Scholar 

  51. Hoffmann, R.; Radom, L.; Pople, J. A.; von Schleyer, P.; Hehre, W. J.; Salem, L. J. Am. Chem. Soc. 1972, 94, 6221, and references therein.

    Article  CAS  Google Scholar 

  52. DeFrees, D. J.; Bartmess, J. E.; Jhong, K. K.; McIver, R. T., Jr.; Hehre, W. J. J. Am. Chem. Soc. 1977, 99, 6451.

    Article  CAS  Google Scholar 

  53. Ellis, D. E.; Rosen, A.; Gubanov, V. A. J. Chem. Phys. 1982, 77, 4051, and references therein.

    Article  CAS  Google Scholar 

  54. Green, J. C.; Kelly, M. F.; Long, J. A.; Kannelakopulos, B.; Yarrow, I. J. Organomet. Chem. 1981, 212, 329.

    Article  CAS  Google Scholar 

  55. Bursten, B. E.; Casarin, M.; Di Bella, S.; Fang, A.; Fragalà, I. Inorg. Chem., submitted.

    Google Scholar 

  56. Averill, F. W.; Ellis, D. E. J. Chem. Phys. 1973, 59, 6411.

    Article  Google Scholar 

  57. Rose, A.; Ellis, D. E.; Adachi, H.; Averill, F. W. J. Chem. Phys. 1976, 65, 3629, and references therein.

    Article  Google Scholar 

  58. Doretti, L.; Zanella, P.; Faraglia, G.; Faleschini, I. J. Organomet. Chem. 1972, 43, 339.

    Article  CAS  Google Scholar 

  59. Kannellakopulos, B.; Aderhold, C.; Donberger, E. J. Organomet. Chem. 1974, 66, 447.

    Article  Google Scholar 

  60. Bagnall, K.; Edward, J.; Tempest, A. C. J. Chem. Soc., Dalton Trans. 1978, 2956.

    Google Scholar 

  61. Ernst, R. D.; Kennelly, W. J.; Secaur-Day, C.; Day, V. W.; Marks, T. J. J. Am. Chem. Soc. 1979, 10, 1656.

    Google Scholar 

  62. Manriquez, J. M.; Fagan, P. M.; Marks, T. J. J. Am. Chem. Soc. 1978, 100, 3939.

    Article  CAS  Google Scholar 

  63. duini, A. L.; Edelstein, N. M.; Jamerson, J. E.; Reynolds, J. G.; Schmid, K.; Takats, J. Inorg. Chem. 1981, 20, 2470.

    Article  Google Scholar 

  64. Arduini, A. L.; Jamerson, J. D.; Takats, J. Inorg. Chem. 1981, 20, 2474.

    Article  CAS  Google Scholar 

  65. Arduini, A. L.; Takats, J. Inorg. Chem. 1981, 20, 2480.

    Article  CAS  Google Scholar 

  66. Bursten, B. E.; Fang, A. J. Am. Chem. Soc. 1983, 105, 6495.

    Article  CAS  Google Scholar 

  67. Ciliberto, E.; Malito, J.; Arduini, A. L.; Fragala, I.; Takats, J. Organometallics, to be submitted.

    Google Scholar 

  68. Zanella, P.; DePaoli, G.; Bombieri, G.; Zanotti, G.; Rossi, R. J. Organomet. Chem. 1977, 142, C21.

    Article  CAS  Google Scholar 

  69. Harris, D. H.; Lappert, M. F.; Pedley, J. B.; Sharp, G. J. J. Chem. Soc., Dalton Trans. 1976, 945.

    Google Scholar 

  70. Lappert, M. F.; Pedley, J. B.; Sharp, G. J.; Bradley, D. C. J. Chem. Soc., Dalton Trans. 1976, 1737.

    Google Scholar 

  71. Gibbins, S. G.; Lappert, M. F.; Pedley, J. B.; Sharp, G. J. J. Chem. Soc., Dalton Trans. 1976, 72.

    Google Scholar 

  72. Wittel, K.; McGlynn, S. P. Chem. Rev. 1977, 77, 745

    Article  CAS  Google Scholar 

  73. Ajò, D.; Ciliberto, E.; Fragalà, I.; Granozzi, G.; J. Mol. Struct. 1980, 62, 189.

    Article  Google Scholar 

  74. Cauletti, C.; Furlani, C. J. Chem. Soc., Dalton Trans. 1977, 1068.

    Google Scholar 

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Author information

Authors and Affiliations

  1. Dipartimento di Chimica, Universita di Catania, V.1e Andrea Doria 6, 95125, Catania, Italy

    Ignazio L. Fragalà & Antonio Gulino

Authors
  1. Ignazio L. Fragalà
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  2. Antonio Gulino
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Northwestern University, Evanston, Illinois, USA

    Tobin J. Marks

  2. Department of Chemistry, University of Catania, Catania, Italy

    Ignazio L. Fragalà

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© 1985 D. Reidel Publishing Company

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Fragalà, I.L., Gulino, A. (1985). Photoelectron Spectroscopy of f-Element Organometallic Complexes. In: Marks, T.J., Fragalà, I.L. (eds) Fundamental and Technological Aspects of Organo-f-Element Chemistry. NATO ASI Series, vol 155. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5406-9_9

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  • DOI: https://doi.org/10.1007/978-94-009-5406-9_9

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8887-9

  • Online ISBN: 978-94-009-5406-9

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