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Frontier Elements: Connections with f-Elements

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Fundamental and Technological Aspects of Organo-f-Element Chemistry

Part of the book series: NATO ASI Series ((ASIC,volume 155))

Abstract

In the last decade organo-f-element chemistry has developed almost explosively. Especially organometallic compounds with carbocyclic ligands of the cyclopentadienyl type (Cp = η5-C5H5, Cp* = η5-C5(CH3)5, and other substituted cyclopentadienyls) have attracted a great deal of attention. This field now gives a clear picture of systematic investigations on the synthesis and reactivity of certain classes of compounds of both 4f- and 5f-elements. It appears that particularly the chemistry of the M-C bond (CO insertion and/or coupling reactions, olefin interactions, activation of C-H bonds) and in general the perspectives for applications of organo-f-elements compounds in catalysis and in stoichiometric reactions are very exciting [1,2].

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References

  1. T.J. Marks and R.D. Ernst, in F.G.A. Stone, G. Wilkinson and E.W. Abel: Comprehensive Organometallic Chemistry, Vol. 3, Pergamon Press, London, 1982, 173.

    Chapter  Google Scholar 

  2. H. Schumann, Angew. Chemie, 1984, 96, 475.

    Article  CAS  Google Scholar 

  3. W.J. Evans, J. Organomet. Chem., 1983, 250, 217.

    Article  CAS  Google Scholar 

  4. M. Bottrill, P.S. Gavens, J.W. Kelland and J. McMeeking, in F.G.A. Stone, G. Wilkinson and E.W. Abel: Comprehensive Organometallic Chemistry, Vol. 3, Pergamon Press, London, 1982, 217.

    Google Scholar 

  5. D.J. Cardin, M.F. Lappert, C.L. Raston and P.I. Riley in F.G.A. Stone, G. Wilkinson and E.W. Abel: Comprehensive Organometallic Chemistry, Vol. 3, Pergamon Press, London, 1982, 549.

    Chapter  Google Scholar 

  6. E.J.M. de Boer and J.H. Teuben, J. Organomet. Chem., 1977, 140, 41.

    Article  Google Scholar 

  7. E.J.M. de Boer and J.H. Teuben, J. Organomet. Chem., 1978, 153, 53.

    Article  Google Scholar 

  8. E.J.M. de Boer and J.H. Teuben, J. Organomet. Chem., 1979, 166, 193.

    Article  Google Scholar 

  9. E. Klei and J.H. Teuben, J. Organomet. Chem., 1980, 188, 97.

    Article  CAS  Google Scholar 

  10. E. Klei and J.H. Teigen and J.H. Teuben, J. Organomet. Chem., 1981, 209, 297.

    Article  CAS  Google Scholar 

  11. E. Klei and J.H. Teuben, J. Organomet. Chem., 1981, 222, 79.

    Article  CAS  Google Scholar 

  12. E. Klei, J.H. Teuben, H.J. de Liefde Meijer, E.J. Kwak and A.P. Bruins, J. Organomet. Chem., 1982, 224, 327.

    Article  CAS  Google Scholar 

  13. H.A. Martin and F. Jellinek, J. Organomet. Chem., 1967, 8, 115.

    Article  CAS  Google Scholar 

  14. J.H. Teuben and H.J. de Liefde Meijer, J. Organomet. Chem., 1972, 46, 313.

    Article  CAS  Google Scholar 

  15. E. Klei, Thesis, Groningen, 1981.

    Google Scholar 

  16. H.H. Brintzinger, J. Am. Chem. Soc., 1967, 89, 6871.

    Article  CAS  Google Scholar 

  17. P.L. Watson, J. Chem. Soc., Chem. Commun., 1980, 652.

    Google Scholar 

  18. J. Holton, M.F. Lappert, D.G.H. Ballard, R. Pearce, J.L. Atwood and W.E. Hunter, J. Chem. Soe., Dalton Trans., 1979, 45.

    Google Scholar 

  19. D. Ytsma, J.G. Hartsuiker and J.H. Teuben, J. Organomet. Chem., 74, 239.

    Google Scholar 

  20. G.W.M. Visser and J.H. Teuben, J. Organomet. Chem., 1978, 144, 81.

    Article  CAS  Google Scholar 

  21. J.H. Teuben, J. Organomet. Chem., 1973, 57, 159.

    Article  CAS  Google Scholar 

  22. J.W. Lauher and R. Hoffmann, J. Am. Chem. Soc., 1976, 98, 1729.

    Article  CAS  Google Scholar 

  23. J.H. Teuben, J. Organomet. Chem., 1974, 69, 241.

    Article  CAS  Google Scholar 

  24. G. Fachinetti, C. Floriani, A. Chiesi-Villa and G. Guastini, J. Am. Chem. Soc., 1979, 101, 1767.

    Article  CAS  Google Scholar 

  25. L.P. Battaglia, M. Nasdelli, C. Pelizzi, G. Predieri and G.P. Chiusoli, J. Organomet. Chem., 1983, 259, 301.

    Article  CAS  Google Scholar 

  26. M.L.H. Green and C.R. Lucas, J. Chem. Soc., Dalton Trans., 1972, 1000.

    Google Scholar 

  27. E.J.M. de Boer, Thesis, Groningen, 1979.

    Google Scholar 

  28. E.J.M. de Boer, L.C. Ten Cate, A.G.J. Staring and J.H. Teuben, J. Organomet. Chem., 1979, 181, 61.

    Article  Google Scholar 

  29. F. van Bolhuis, E.J.M. de Boer and J.H. Teuben, J. Organomet. Chem., 1979, 170, 299.

    Article  Google Scholar 

  30. J.H. Teuben, E.J.M. de Boer, A.H. Klazinga and E. Klei, J. Mol. Catal., 1981, 13, 107.

    Article  CAS  Google Scholar 

  31. F. Sato, S. Iijima and M. Sato, J. Chem. Soc., Chem. Commun., 1981, 180.

    Google Scholar 

  32. F. Sato, H. Uchiyama, K. Ida, Y. Kobayashi and M. Sato, J. Chem. Soc., Chem. Commun., 1983, 921.

    Google Scholar 

  33. E. Klei and J.H. Teuben, J. Organomet. Chem., 1981, 214, 53.

    Article  CAS  Google Scholar 

  34. M.E. Thompson and J.E. Bercaw, Pure Appl. Chem., 1984, 56, 1.

    Article  CAS  Google Scholar 

  35. P.L. Watson, J. Chem. Soo., Chem. Commun., 1983, 276.

    Google Scholar 

  36. B. Hessen, J. Blenkers and J.H. Teuben, to be published.

    Google Scholar 

  37. F.W. van der Weij, H. Scholtens and J.H. Teuben, J. Organomet. Chem., 1977, 127, 299.

    Article  Google Scholar 

  38. J.E. Bercaw, R.H. Marvich, L.G. Bell and H.H. Brintzinger, J. Am. Chem. Soc., 1972, 94, 1219.

    Article  CAS  Google Scholar 

  39. R.D. Sanner, D.M. Duggan, T.C. McKenzie, R.E. Marsh and J.E. Bercaw, J. Am. Chem. Soc., 1976, 98, 8358.

    Article  CAS  Google Scholar 

  40. J.M. Manriques, D.R. McAlister, E. Rosenberg, A.M. Shiller, K.L. Williamson, S.I. Chan and J.E. Bercaw, J. Am. Chem Soc., 1978, 100, 3078.

    Article  Google Scholar 

  41. S.A. Cohen, P.R. Auburn and J.E. Bercaw, J. Am. Chem. Soc., 1983, 105, 1136.

    Article  CAS  Google Scholar 

  42. J.E. Bercaw, J. Am. Chem. Soc., 1974, 96, 5087.

    Article  CAS  Google Scholar 

  43. H. Brookhart and M.L.H. Green, J. Organomet. Chem., 1983, 250, 395.

    Article  CAS  Google Scholar 

  44. J.H. Teuben and P. Buwalda, unpublished results.

    Google Scholar 

  45. C.P. Boekel, J.H. Teuben and H.J. de Liefde Meijer, J. Organomet. Chem., 1975, 102, 161.

    Article  CAS  Google Scholar 

  46. C. McDade, J.C. Green and J.E. Bercaw, Organometallics, 1982, 1, 1629.

    Article  CAS  Google Scholar 

  47. M.J. Calhorda, A.R. Dias, M.S. Salema and J.A. Marinko Simoes, J. Organomet. Chem., 1983, 255, 81.

    Article  CAS  Google Scholar 

  48. J.H. Teuben and K.H. den Haan, to be published.

    Google Scholar 

  49. P.L Watson and D.C. Roe, J. Am. Chem. Soc., 1982, 104, 6471.

    Article  CAS  Google Scholar 

  50. F. Bottomley, I.J.B. Lin and P.S. White, J. Am. Chem. Soc., 1981, 103, 703.

    Article  CAS  Google Scholar 

  51. J.E. Bercaw, Adv. Chem. Ser., 1978, No. 67, 136.

    Google Scholar 

  52. J. Blenkers, H.J. de Liefde Meijer and J.H. Teuben, J. Organomet. Chem., 1981, 218, 383.

    Article  CAS  Google Scholar 

  53. R.P. Beatty, S. Datta and S.S. Wreford, Inorg. Chem., 1979, 11, 3139.

    Article  Google Scholar 

  54. G. Wilkinson and J.M. Birmingham, J. Am. Chem. Soc., 1954, 76, 6210.

    Article  CAS  Google Scholar 

  55. J. Holton, M.F. Lappert, D.G.H. Ballard, R. Pearce, J.L. Atwood and W.E. Hunter, J. Chem. Soo., Dalton Trans., 1979, 54.

    Google Scholar 

  56. W.J. Evans, J.H. Meadows, A.L. Wayda, W.E. Hunter and J.L. Atwood, J. Am. Chem. Soc., 1982, 104, 1190.

    Google Scholar 

  57. M.F. Lappert, A. Singh, J.L. Atwood and W.E. Hunter, J. Chem. Soc., Chem. Commun., 1981, 1191.

    Google Scholar 

  58. P.L. Watson, J. Am. Chem. Soc., 1983, 105, 6491.

    Article  CAS  Google Scholar 

  59. P.L. Watson, J. Am. Chem. Soc., 1982, 104, 337.

    Article  CAS  Google Scholar 

  60. K.H. den Haan, J.L. de Boer, J.H. Teuben, A.L. Spek and B. Kojić-Prodić, to be published.

    Google Scholar 

  61. T.J. Marks, NATO-ASI on Organo-f-Element Chemistry, Maratea, Sept. 1984.

    Google Scholar 

  62. G.J. Olthof and F. van Bolhuis, J. Organomet. Chem., 1976, 122, 47.

    Article  CAS  Google Scholar 

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Author information

Authors and Affiliations

  1. Laboratorium voor Anorganische Chemie, Rijksuniversiteit Groningen, Nijenborgh 16, 9747 AG, Groningen, The Netherlands

    Jan H. Teuben

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  1. Jan H. Teuben
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Editors and Affiliations

  1. Department of Chemistry, Northwestern University, Evanston, Illinois, USA

    Tobin J. Marks

  2. Department of Chemistry, University of Catania, Catania, Italy

    Ignazio L. Fragalà

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© 1985 D. Reidel Publishing Company

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Teuben, J.H. (1985). Frontier Elements: Connections with f-Elements. In: Marks, T.J., Fragalà, I.L. (eds) Fundamental and Technological Aspects of Organo-f-Element Chemistry. NATO ASI Series, vol 155. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5406-9_6

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  • DOI: https://doi.org/10.1007/978-94-009-5406-9_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8887-9

  • Online ISBN: 978-94-009-5406-9

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