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Organoactinide Complexes Containing Classical Ligands

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Book cover Fundamental and Technological Aspects of Organo-f-Element Chemistry

Part of the book series: NATO ASI Series ((ASIC,volume 155))

Abstract

Although the main concern of organometallic chemistry is the nature and the reactivity of metal-to-carbon bonds, organometallic complexes containing classical ligands (ligands with donor atoms other than carbon) nevertheless occupy a very important place in this area of chemistry. In a synthetic sense, the substitution of X (a classical ligand) for R (an unspecified organic group) is the traditional and still very important entry into organometallic compounds. Derivatization of mixed MXnRm compounds is one of the responsible factors for the rich variety of organometallic compounds presently known. Classical ligands can also be used to increase the stability of organometallic molecules by saturating the coordination sphere of the metal either by simple adduct formation or by judicious choice of a raultidentate or sterically demanding ligand. However, what may be the most interesting aspect of such complexes is that they offer the opportunity to study the mutual influence of X and R on the nature of their respective bonding capabilities and reactivity characteristics. The purpose of this chapter is to summarize the synthesis, properties and reactivity of organoactinide compounds with classical ligands. The coverage is not intended to be exhaustive but builds on two excellent previous reviews dealing with organo-f-element compounds (1,2). Organolanthanide compounds with classical ligands will be found in the chapter by H. Schumann.

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  1. Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada, T6G 2G2

    Josef Takats

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  1. Josef Takats
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  1. Department of Chemistry, Northwestern University, Evanston, Illinois, USA

    Tobin J. Marks

  2. Department of Chemistry, University of Catania, Catania, Italy

    Ignazio L. Fragalà

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Takats, J. (1985). Organoactinide Complexes Containing Classical Ligands. In: Marks, T.J., Fragalà, I.L. (eds) Fundamental and Technological Aspects of Organo-f-Element Chemistry. NATO ASI Series, vol 155. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5406-9_5

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  • DOI: https://doi.org/10.1007/978-94-009-5406-9_5

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