Abstract
Organic synthesis remains of major interest for the production of a large number of compounds, especially in the pharmaceutical field or for high value added products. New synthetic methods are necessary for increasing the various selectivities associated with chemical transformations:
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i)
Chemioselectivity (selective transformation at one functional group of a polyfonctional molecule, i.e. oxidation of a primary hydroxyl in presence of a secondary one).
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ii)
Regioselectivity (i.e., control of the sense of HBr addition to a dis-symetric C=C double bond).
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iii)
Stereoselectivity (preferential formation of either one diastereomer or one enantiomer).
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Kagan, H.B. (1985). 4f-Elements on Organic Synthesis. In: Marks, T.J., Fragalà, I.L. (eds) Fundamental and Technological Aspects of Organo-f-Element Chemistry. NATO ASI Series, vol 155. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5406-9_2
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DOI: https://doi.org/10.1007/978-94-009-5406-9_2
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