Abstract
The inclusion polymerization of diene monomers with different sizes and shapes in apocholic acid canals was studied under γ-ray irradiation. It was found that the sizes and shapes of monomers profoundly influenced the microstructures of the corresponding polymers obtained. Thus, polybutadiene contained a significant amount of 1, 2-units like usual radical polymerization in solution. Polyisoprene consisted of a mixture of head-to-tail and head-to-head (tail-to-tail) addition. The introduction of two methyl groups into butadiene led to the synthesis of polymers with almost exclusively head-to-tail, 1,4-trans structure.
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References
K.Takemoto and M.Miyata:J.Macromol.Sci.Rev.Macromol.Chem. C18,83 (1980).
M.Miyata and K.Takemoto:J Polym. Sci., Polym.Lett.Ed. 13,221(1975).
M.Miyata and K.Takemoto:J.Polym. Sci.,Polym. Syrrp.55, 279 (1976).
M.Miyata,Y.Kitahara and K.Takemoto:Polym.Bul1. 2,671(1980).
M.Miyata and K.Takemotoz:Polym.J.9,111(1977).
M.Miyata,Y.Kitahara and K.Takemotor:Poiym.J. 13,111(1981).
M.Miyata,Y.Kitahara and K.Takemotoz:Makromol.Chem. 184,1771(1983).
S.C.DeSanctis and E.Giglio:Acta Cryst.B35,2650(1979).
A.W.Devor and H.W. Mar low:J. Am.Chem. Soc.68,2101(1946).
R.Greenwald,M.Chaykovsky and E.J.Corey:J.Org.Chem. 28,1128(1963).
H.M.Frey,A.M.Lamont and R.Walsh:J.Chem.Soc. A 2642(1971).
C.F.Allen and A. Bell:Organic Synthesis, Coll.Vol.3, p. 312, John Wiley & Sons,New York(1955).
H.M.Frey and R.J.Ellis:J.Chem.Soc. 4770(1965).
L.P.Kyrides:J.Am.Chem.Soc. 55,3431(1933).
G.B.Bachman and C.G.Goebel:J.Am.Chem.Soc. 64,787(1942).
D.Morero,A.Santambrogio,L.Porri and F.Ciampelli:Chim. Ind. (Milan) 41,758(1959).
M.W.Duch and D. M. Grant:Macromolecules3, 165 (1970).
Y.Araki,T.Yoshimoto,T.Imanari and M.Takeuchi:Kobunshi Kagaku29, 397 (1972).
P. J.Pollock,L. J.Elyash and T.W.Dewitt:J.Polym. Sci. 15, 87 (1955).
E.R.Dolinskaya,A.S.Khatchaturov,I.A.Poletayeva and V.A.Kormer:Makromol.Chem.179, 409 (1978).
G.Audisio,A.Silvani and L.Zetta:Macromolecules 17,29(1984).
D.Blondin,J.Regis and J.Prud’homme:Macromolecules 7,187(1974).
M.Farina,G.Audisio and M.T.Gramegnai:Macromolecules 5,617(1972).
D.Cuzin,Y.Chauvin and G.Lefebvrez:Europ.Polym.J. 3,581(1967).
J.F.Brown and D.M.White:J.Am.Chem. Soc. 82,5671,5678(1960). 398
M.Lahav,L.Leiserowitz,R.Popovitz-Biro and C.P.Tang:J.Am.Chem.Soc. 100,2542(1978).
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© 1984 D. Reidel Publishing Company
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Miyata, M., Kitahara, Y., Osaki, Y., Takemoto, K. (1984). Inclusion Polymerization of Various Diene Monomers in Apocholic Acid Canals. In: Atwood, J.L., Davies, J.E.D., Osa, T. (eds) Clathrate Compounds, Molecular Inclusion Phenomena, and Cyclodextrins. Advances in Inclusion Science, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5376-5_43
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DOI: https://doi.org/10.1007/978-94-009-5376-5_43
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