Abstract
Alkali cation exchanged X- and Y-type zeolites are employed to promote the reactions of aniline derivatives with alkylating agents in organic solvent. The N-alkylation is accelerated by the cooperative function of the acid and base sites on the potassium cation exchanged X- and Y-type zeolites to give the N-monoalkylated product in very high selectivity. Especially the use of the zeolite is found to be effective for N-alkylation of deactivated aromatic amines like nitroaniline. The highly selective N-monoalkylation is attributed to the reaction occurring inside the homogeneous narrow cavities of zeolites.
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© 1984 D. Reidel Publishing Company
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Onaka, M., Ishikawa, K., Izumi, Y. (1984). Selective N-Monoalkylation of Aniline Derivatives by Use of Alkali Cation Exchanged X- And Y-Type Zeolites. In: Atwood, J.L., Davies, J.E.D., Osa, T. (eds) Clathrate Compounds, Molecular Inclusion Phenomena, and Cyclodextrins. Advances in Inclusion Science, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5376-5_40
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DOI: https://doi.org/10.1007/978-94-009-5376-5_40
Publisher Name: Springer, Dordrecht
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