Abstract
New photoresponsive crown ethers (1H+) having a crown ring and an ammoniumalkyl (H3N+(CH2)n-, n=4,6,10) group attached to the two sides of an azobenzene have been synthesized. Photo-responsive properties (thermal isomerization, metal extraction, membrane transport, etc.) were examined, and the results were compared with those of other photoresponsive crown ethers and complexons.
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© 1984 D. Reidel Publishing Company
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Shinkai, S., Ishihara, M., Ueda, K., Manabe, O. (1984). On-Off-Switched Crown-Metal Complexation by Photoinduced Intramolecular Tail(Ammonium)-Biting. In: Atwood, J.L., Davies, J.E.D., Osa, T. (eds) Clathrate Compounds, Molecular Inclusion Phenomena, and Cyclodextrins. Advances in Inclusion Science, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5376-5_10
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DOI: https://doi.org/10.1007/978-94-009-5376-5_10
Publisher Name: Springer, Dordrecht
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