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Part of the book series: NATO ASI Series ((ASIC,volume 142))

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Abstract

Photophysics and photochemistry in the vacuum ultraviolet (VUV; energies greater than ~6 eV) is dominated, to one extent or another, by the presence of highly-excited (Rydberg, or R) states. Indeed, a large majority of questions in modern atomic and molecular physics impinge on the structure of Rydberg states and their continuum counterparts, questions as diverse as, for example, the nature of electron transfer in gaseous and condensed phases; the effects of electric and magnetic fields on highly-excited states; field-ionization of R states as a means of constructing weakfield detectors; the use of highly-excited states as tunable microwave sensors and in the construction of tunable microwave lasers; etc. This listing could obviously be extended; and, in fact, it is extended -- both in breadth and in depth -- in the following chapters in this volume.

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References

  1. S. P. McGlynn and G. L. Findley, J. Photochem. 17, 461 (1981)

    Article  CAS  Google Scholar 

  2. P. Hochmann, G. L. Findley and S. P. McGlynn, Z. Naturforsch. 35a, 595 (1980); Errata, Z. Naturforsch. 35a, 1431 (1980)

    CAS  Google Scholar 

  3. P. Hochmann, G. L. Findley and S. P. McGlynn, Z. Naturforsch. 35a, 595 (1980); Errata, Z. Naturforsch. 35a, 1431 (1980)

    Google Scholar 

  4. P. Hochmann, S. P. McGlynn and G. L. Findley, Int. J. Quantum Chem., Quantum Biol. Symp. 9, 173 (1982)

    CAS  Google Scholar 

  5. A. M. Langsjoen, P. Hochmann, P. Brint, S. P. McGlynn and G. L. Findley, Phys. Rev. A, submitted

    Google Scholar 

  6. See, for example, R. McWeeny and B. T. Sutcliffe, Methods of Molecular Quantum Mechanics( Academic Press, New York, 1969 )

    Google Scholar 

  7. H. -t. Wang, W. S. Felps, G. L. Findley, A. R. P. Rau and S. P. McGlynn, J. Chem. Phys. 67, 3940 (1977)

    Article  CAS  Google Scholar 

  8. For a recent, masterful summary, see: M. J. Seaton, Rep. Prog. Phys. 46, 167 (1983)

    Article  Google Scholar 

  9. . J. L. Dehmer and U. Fano, Phys. Rev. A2, 304 (1970)

    Google Scholar 

  10. M. J. Seaton, Proc. Phys. Soc. 88, 801, 815 (1966)

    Article  CAS  Google Scholar 

  11. K. T. Lu, Phys. Rev. A4, 579 (1971)

    Google Scholar 

  12. M. A. Baig, J. P. Connerade, J. Dagata and S. P. McGlynn, J. Phys. B 14, L25 (1981)

    Google Scholar 

  13. H. Beutler, Z. Phys. 93, 177 (1935)

    Article  Google Scholar 

  14. U. Fano, Phys. Rev. 124, 1866 (1961)

    Article  Google Scholar 

  15. U. Fano, Phys. Rev. A2, 353 (1970)

    Google Scholar 

  16. J. A. Dagata, G. L. Findley, S. P. McGlynn, J. P. Connerade and M. A. Baig, Phys. Rev. A24, 2485 (1981)

    Google Scholar 

  17. K. T. Lu and U. Fano, Phys. Rev. A2, 81 (1970)

    Google Scholar 

  18. J. P. Connerade, M. A. Baig and S. P. McGlynn, J. Phys. B 14, L67 (1981)

    Article  CAS  Google Scholar 

  19. Atabek and C. Jungen, in: Electron and Photon Interactions with Atoms, H. Kleinpoppen and M. R. C. McDowell, eds. ( Plenum, New York, 1976 )

    Google Scholar 

  20. D. Dill and Ch. Jungen, J. Phys. Chem. 84, 2116 (1980)

    Article  CAS  Google Scholar 

  21. Ch. Jungen and D. Dill, J. Chem. Phys. 73, 3338 (1980)

    Article  CAS  Google Scholar 

  22. S. Felps, P. Hochmann, P. Brint and S. P. McGlynn, J. Mol. Spectrosc. 59, 355 (1976)

    Article  CAS  Google Scholar 

  23. R. S. Mulliken, Phys. Rev. 57, 500 (1940)

    Article  CAS  Google Scholar 

  24. S. P. McGlynn, J. D. Scott, W. S. Felps and G. L. Findley, J. Chem. Phys. 72, 421 (1980)

    Article  CAS  Google Scholar 

  25. S. P. McGlynn, W. S. Felps and G. L. Findley, Chem. Phys. Lett. 78, 89 (1981)

    Article  Google Scholar 

  26. W. S. Felps, G. L. Findley and S. P. McGlynn, Chem. Phys. Lett. 81, 490 (1981)

    Article  CAS  Google Scholar 

  27. S. P. McGlynn, W. S. Felps, J. D. Scott and G. L. Findley, J. Chem. Phys. 73, 4925 (1980)

    Article  CAS  Google Scholar 

  28. W. S. Felps, J. D. Scott, G. L. Findley and S. P. McGlynn, J. Chem. Phys. 74, 4832 (1981)

    Article  Google Scholar 

  29. W. S. Felps, S. P. McGlynn and G. L. Findley, J. Mol. Spectrosc. 86, 71 (1981)

    Article  CAS  Google Scholar 

  30. H. J. Maria, J. L. Meeks, P. Hochmann, J. F. Arnett and S. P. McGlynn, Chem. Phys. Lett. _19, 309 (1973)

    Article  Google Scholar 

  31. S. Foster, P. Hochmann, W. S. Felps, H. -t. Wang and S. P. McGlynn, in: Chemical Spectroscopy and Photochemistry in the Vacuum Ultraviolet, C. Sandorfy, P. J. Ausloos and M. B. Robin, eds. ( D. Reidel, Dordrecht, 1974 )

    Google Scholar 

  32. P. Hochmann and S. P. McGlynn, in: Vacuum Ultraviolet Radiation Physics, E. E. Koch, R. Haensel and C. Kunz, eds. ( Pergamon, Braunschweig, 1975 )

    Google Scholar 

  33. S. Chattopadhyay, P. Hochmann and S. P. McGlynn, J. Chem. Phys. 65, 3341 (1976)

    Article  CAS  Google Scholar 

  34. S. P. McGlynn, S. Chattopadhyay, P. Hochmann and H. -t. Wang, J. Chem. Phys. 68, 4738 (1978)

    Article  CAS  Google Scholar 

  35. J. H. Fock, P. Gürtler and E. E. Koch, Chem. Phys. 47, 87 (1980)

    Article  CAS  Google Scholar 

  36. G. L. Findley, P. Hochmann and S. P. McGlynn, Ann. Israel Phys. Soc. 6, 161, 164 (1983)

    Google Scholar 

  37. D. Spence, J. Chem. Phys. 66, 669 (1977); Phys. Rev. A15, 883 (1977)

    Google Scholar 

  38. J. D. Scott, W. S. Felps and S. P. McGlynn, Nuc. Instrum. Meth. 152, 231 (1978)

    Article  CAS  Google Scholar 

  39. J. D. Scott, W. S. Felps, G. L. Findley and S. P. McGlynn, J. Chem. Phys. 68, 4678 (1978)

    Article  CAS  Google Scholar 

  40. J. D. Scott, W. S. Felps and S. P. McGlynn, in: Proceedings of the Colloque International CNRS(kussois, France, 1982), J. de Physique (France), Colloque C2, Supplement 11 (1982)

    Google Scholar 

  41. J. D. Scott, W. S. Felps and S. P. McGlynn, in: Proceedings of the Colloque International CNRS(kussois, France, 1982), J. de Physique (France), Colloque C2, Supplement 11 (1982)

    Google Scholar 

  42. W. R. S. Garton and F. S. Tomkins, Astrophys. J. 158, 839 (1969)

    Article  Google Scholar 

  43. C. D. Harper and M. D. Levinson, Opt. Commun. 20, 107 (1977)

    Article  CAS  Google Scholar 

  44. J. P. Connerade, W. R. S. Garton, M. A. Baig, J. Hormes and S. P. McGlynn, unpublished

    Google Scholar 

  45. J. E. Bayfield, Phys. Rep. 51, 317 (1979)

    Article  CAS  Google Scholar 

  46. J. D. Scott, and B. R. Russell, J. Chem. Phys. 63, 3243 (1975)

    Google Scholar 

  47. G. C. Causley, J. D. Scott and B. R. Russell, Rev. Sci. Instrum. 48, 264 (1977)

    Article  CAS  Google Scholar 

  48. S. P. McGlynn and G. L. Findley, in: Proc. Workshop on Par VUV Spectroscopy and Photochemistry (Mülheim a.d. Ruhr, 1981), pp. 99–102

    Google Scholar 

  49. M. B. Robin, Higher Excited States of Polyatomic Molecules( Academic Press, New York, 1975 )

    Google Scholar 

  50. M. B. Robin and N. A. Kuebler, J. Mol. Spectrosc. 33, 274 (1970)

    Article  CAS  Google Scholar 

  51. I. Messing, B. Raz and J. Jortner, Chem. Phys. 23, 351 (1977)

    Article  CAS  Google Scholar 

  52. J. W. Lewis, R. V. Nauman, D. B. Bouler and S. P. McGlynn, J. Phys. Chem. 87, 3611 (1983)

    Article  CAS  Google Scholar 

  53. J. Jortner, in: Vacuum Ultraviolet Radiation Physics, E. E. Koch, R. Haensel and C. Kunz, eds. ( Pergamon, Braunschweig, 1974 ), p. 263

    Google Scholar 

  54. M. Fox, in: Concepts of Inorganic Photochemistry, A. W. Adamson and P. D. Fleischer, eds. ( Wiley-Interscience, New York, 1975 ), p. 333

    Google Scholar 

  55. G. L. Findley and S. P. McGlynn, Rev. Mod. Phys., to be published

    Google Scholar 

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Findley, G.L., Wilder, J.A., Hochmann, P., McGlynn, S.P. (1985). Photophysics of Highly-Excited States. In: McGlynn, S.P., Findley, G.L., Huebner, R.H. (eds) Photophysics and Photochemistry in the Vacuum Ultraviolet. NATO ASI Series, vol 142. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5269-0_1

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  • DOI: https://doi.org/10.1007/978-94-009-5269-0_1

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