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Tailored Metal Catalysts pp 141–182Cite as

The Preparation of Heterogeneous Catalysts from Mononuclear Carbonyl Complexes on Inorganic Supports

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Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 7))

Abstract

The first reported use of a mononuclear transition metal carbonyl complex to prepare a supported metal catalyst was by Baker and Bernstein in 1951 [1], who prepared an active nickel hydrogenation catalyst by decomposing Ni(CO)4 on glass supports. Terenin and Roev [2] subsequently decomposed the carbonyls of chromium, iron and nickel on an alumina support to produce what was considered at the time to be zero-valent metal, although their IR spectra of adsorbed CO and NO show evidence for oxidized species as well. Parkyns [3] demonstrated that the decomposition of Ni(CO)4 on an alumina support produced zero-valent nickel which was however readily oxidized upon exposure to O2. About the same time, catalysts prepared from the Group VI carbonyl complexes Mo(CO)6 and W(CO)6 on various oxide supports were shown to be highly active for the olefin metathesis reaction [4].

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  1. Chemistry Department, University of Auckland, Private Bay, Auckland, New Zealand

    R. F. Howe

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  1. Department of Chemistry, Faculty of Science, The University of Tokyo, Japan

    Yasuhiro Iwasawa

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Howe, R.F. (1986). The Preparation of Heterogeneous Catalysts from Mononuclear Carbonyl Complexes on Inorganic Supports. In: Iwasawa, Y. (eds) Tailored Metal Catalysts. Catalysis by Metal Complexes, vol 7. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5261-4_3

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  • DOI: https://doi.org/10.1007/978-94-009-5261-4_3

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