Abstract
The diffusion Kinetics of silver atoms in phases AgxNbS2 was studied in relation with their structures. The relatively low value of the chemical diffusion coefficient, \( \tilde{D} \) ≈ 10-6.5 cm2s-1 in second stage 6R-AgxNbS2, as compared to that in first stage 2H-AgxNbS2, \( \tilde{D} \) ≈ 10-4.5 cm2s-1, is attributed to the coupling of the diffusion kinetics with stage conversion in island type domains.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Boukamp, B.A. and G.A. Wiegers, Ionic and Electronic Processes in AgCrSe2. Solid State Ionics 9,10 (1983) 1193–1196.
Weppner, W. and R.A. Huggins. Determination of the Kinetic Properties of Mixed Conducting Electrodes and Application to the System of Li3Sb. J. Electrochem. Soc. 124 (1977) 1569–1578.
Patriarca, M. et al. Behaviour of Transition-Metal Disulphides as Intercalation Electrodes in Solid-State Cells. Solid State Ionics 6 (1982) 15–20.
Kaluarachchi, D. and R.P. Frindt. Intercalation Islands and Stase Conversion in Ag-TiS2,. Phys. Rev. B 28 (1983) 3663–3665.
Gerards, A.G., H. Roede, R.J. Haange, B.A. Boukamp and G.A. Wiegers. Structure and electrochemical properties of compounds in the system silver-titaniundisulfide, AgxTiS2, acc. for publ. in Synthetic Metals.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1985 Martinus Nijhoff Publishers, Dordrecht
About this chapter
Cite this chapter
Bouwmeester, H.J.M., Wiegers, G.A., Boukamp, B.A. (1985). Structure, Electrical and Electrochemical Properties of AgxNbS2 . In: Sequeira, C.A.C., Hooper, A. (eds) Solid State Batteries. NATO ASI Series, vol 101. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5167-9_37
Download citation
DOI: https://doi.org/10.1007/978-94-009-5167-9_37
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8786-5
Online ISBN: 978-94-009-5167-9
eBook Packages: Springer Book Archive