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Proton and Lithium Ion Conductors Based Upon the AM IV2 (PO4)3 Type Structure

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Solid State Batteries

Part of the book series: NATO ASI Series ((NSSE,volume 101))

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Abstract

Superion conductors based upon either Li+ or H+ as the principal conductor and which are stable at high temperatures are attractive for a number of reasons. The ions are light in weight and hence should show improved energy density in battery devices (1). Temperature stable proton conductors would fine ready use in medium temperature H2-O2 fuel cells. In addition the mechanism of conduction of these ions is interesting from a theoretical standpoint. We have concentrated our present efforts on the three dimensional conductors of the A+M IV2 (PO4)3 type which are related to NASICON (2).

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References

  1. Scrosati, B. Recent Advances in Lithium Solid-State Batteries. J. Applied Electrochemistry 2 (1972) 231.

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  2. Hong, H.Y-P. Crystal Structures and Crystal Chemistry in the System Na1+xZr2SixP3-xO12. Materials Research Bulletin 11 (1976) 173.

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  4. Alberti, G. in Inorganic Ion Exchange Materials, A. Clearfield, Ed. ( CRC Press, Boca Raton, Fl., 1983. pg. 98 ).

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  5. Clearfield, A., B.D. Roberts and M.A. Subramanian. Preparation of (NH4)Zr2(P04)3 and HZr2(PO4)3. Materials Research Bulletin 19 (1984) 219.

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  6. Subramanian, M.A., B.D. Roberts and A. Clearfield. Or the Proton Conductor (H3O)Zr2(PO4)3, Materials Research Bulletin, in press.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, Texas, 77843, USA

    A. Clearfield, M. A. Subramanian, B. D. Robert & R. Subramanian

Authors
  1. A. Clearfield
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  2. M. A. Subramanian
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  3. B. D. Robert
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  4. R. Subramanian
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Editor information

Editors and Affiliations

  1. Instituto Superior Técnico, Technical University of Lisbon, 1096, Lisboa Codex, Portugal

    C. A. C. Sequeira

  2. Materials Development Division, AERE Harwell, OX11 ORA, Oxfordshire, UK

    A. Hooper

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© 1985 Martinus Nijhoff Publishers, Dordrecht

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Clearfield, A., Subramanian, M.A., Robert, B.D., Subramanian, R. (1985). Proton and Lithium Ion Conductors Based Upon the AM IV2 (PO4)3 Type Structure. In: Sequeira, C.A.C., Hooper, A. (eds) Solid State Batteries. NATO ASI Series, vol 101. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5167-9_30

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  • DOI: https://doi.org/10.1007/978-94-009-5167-9_30

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8786-5

  • Online ISBN: 978-94-009-5167-9

  • eBook Packages: Springer Book Archive

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