Abstract
It is not the purpose of this chapter to enter into the details of scattering theory but rather to outline the principles and explain the applications to study of blends. All scattering experiments are based on the existence of variations in the homogeneity of the scattering medium. These may arise either because a few molecules of one type are embedded in a matrix of others as in dilute solutions, or because of concentration fluctuations in a high concentration mixture or from density fluctuations in a single component system. If these inhomogeneities also cause variation in the physical property relevant for scattering a particular type of radiation, a scattering pattern may result. These relevant properties are the polarisability (or refractive index) for light, the electron density for X-rays and the scattering length density (a nuclear property) for neutrons.
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References
Flory, P.J. Principles of Polymer Chemistry, (Ithaca, New York, Cornell University Press, 1953 ).
Glatter, O. and O. Kratky. Small Angle X-ray Scattering, ( London, Academic Press, 1982 ).
Huglin, M. Light Scattering from Polymer Solutions ( London, Academic Press, 1972 ).
Higgins, J.S. and A. Maconnachie. In Methods in Experimental Physics: Neutron Scattering ed. K. Skold and D.L. Price, (New York, Academic Press, to be published 1985 ).
Jacrot, B. Rep. Prog. Phys. 39 (1976) 911.
Einstein, A. Am. Phys. 33, (1910) 1275.
Debye, P. J.Chem.Phys. 31 (1959) 680.
Scholte, T.G. J.Pol.Sci. Part C 39., (1972) 281.
Derham, K.E., J. Goldsborough and M. Gordon. Pure Appl. Chem. 38, (1974) 97.
Koningsveld, R., L.A. Kleintjens and H.M. Schoffeleers. Pure Appl. Chem. 39, (1974) 1.
Chong, C.L. Ph.D. Thesis, Department of Chemical Engineering, Imperial College (1981).
Walsh, D.J., J.S. Higgins, and S. Rostami. Macromolecules 16, (1983) 388.
McMaster, L.P. Adv. Chem. Ser. 1432, (1975) 43.
Snyder, H.L., P. Meakin and S. Reich. Macromolecules 16, (1983) 753.
Cahn, J.W. Trans. Metabl. Soc. AIME 242 (1968) 166
van Aartsen, J.J. Eur. Pol. J. 6, (1970) 919
Debye, P., H.R. Anderson and H. Brumberger. J. Appl. Phys. 28, (1957) 679.
Richards, R.W. In Polymer Characterisaion I, ed. J.V. Dawkins (Appl. Sci. Publishers, 1980 ).
Sperling, L.H. Polymer Engineering and Science 24, 1 (1984).
Neutron Beam Facilities Available to Users, Scientific Secretariat, Institut Laue Langevin, 156X Centre de Tri, 38042 Grenoble, France.
Flory, P.J. J. Chem. Phys. 9, (1941) 660 and 10, 51 (1942).
Huggins, M.L. J. Phys. Chem. 46, (1942) 151 J. Amer. Chem. Soc. 64, (1942) 1712.
Zimm, B.H. J. Chem. Phys. 16, (1948) 1093.
Maconnachie, A., R.P. Kambour, D.M. White, S. Rostami and D.J. Walsh. Accepted by Macromolecules.
Russell, T.P. and R. Stein. J. Pol. Sci. Pol. Phys. 20, (1982) 1593.
Kruse, W.A., R.G. Kirste, J. Haas, B.J. Schmitt and D.J. Stein. Makromol. Chem. 177 (1976) 1145.
Jelenic, J., R.G. Kirste, B.J. Schmitt and S. Schmitt-Strecker. Makromol. Chem. 180 2057 (1979).
Warner, M., J.S. Higgins and A.J. Carter. Macromolecules 16, (1983) 1931.
Higgins, J.S. and A.J. Carter. Accepted by Macromolecules.
Allen, G., Z. Chai., C.L. Chong, J.S. Higgins and J. Tripathi. Polymer 25, (1984) 239.
Buckingham, A.D. and H.G.E. Hentschel. J. Pol. Sci. Pol. Phys. 18, (1980) 853.
Atkin, A.L., L.A. Kleintjens, R. Koningsveld and L.J. Fetters. Polymer Bulletin 9, (1982) 347.
Yang, H., G. Hadziioannou and R.S. Stein. J. Pol. Sci. Pol. Phys. 21, (1983) 159.
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© 1985 Martinus Nijhoff Publishers, Dordrecht
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Higgins, J.S. (1985). Light, Neutron and X-Ray Scattering Techniques for Studying Polymer Blends. In: Walsh, D.J., Higgins, J.S., Maconnachie, A. (eds) Polymer Blends and Mixtures. NATO ASI Series, vol 89. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-5101-3_5
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DOI: https://doi.org/10.1007/978-94-009-5101-3_5
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