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Polymer Stability in Aggressive Media

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Developments in Polymer Degradation—6

Summary

This chapter deals with the kinetic laws and the mechanism of hydrolytic degradation of polymers, particularly the heterochain polymers or those containing heteroatoms in the side groups. The following problems are discussed: catalysis in aggressive liquid media, such as solutions of acids, bases and salts; the reactivity and mechanisms of transformation of chemically unstable bonds in various polymers; specific features of the chemical degradation of polymers compared with that of low-molecular- compounds; diffusion of aggressive media in polymers; prediction of polymer stability in aggressive media; the influence of the medium on the mechanical properties of polymers. Examples are given of the use of hydrolytic degradation as a method of modification of polymeric products.

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References

  1. Moiseev, YU. V. and Zaikov, G. E., Khimicheskaya Stoikost’ Polymerov v Agressivnykh Sredakh, Moscow, Khimiya, 1979.

    Google Scholar 

  2. Alksnis, A. F., Zaikov, G. E. and Karlivan, V. P., Khimicheskaya Stoikost’ Poliefirov, Riga, Zinante, 1978.

    Google Scholar 

  3. Zaikov, G. E. and Privalova, L. G., Problemy ispol’zovaniya polymerov v khirurgii, In: Khimiya Nashimi Glazami, Moscow, Nauka, 1981, pp. 469–87.

    Google Scholar 

  4. Bochkov, A. F. and Zaikov, G. E., Chemistry of the O-Glycosidic Bond: Formation and Cleavage, Oxford, Pergamon Press, 1979.

    Google Scholar 

  5. Lacey, R. N., J. Chem. Soc. (1960), 1633.

    Google Scholar 

  6. Fraenkel, G. and Franconi, C. J., J. Amer. Chem. Soc., 82 (1960), 4478.

    Article  Google Scholar 

  7. O’Connor, C., Quart. Rev., 24 (1970), 533.

    Google Scholar 

  8. Moiseev, YU. V., Batyukov, G. I. and Vinnik, M. I., Izvetiya AN SSSR, ser. fiz., 20 (1962), 1306.

    Google Scholar 

  9. Lockerente, R. S. De Nagy, O. B. and Bruylants, A., Org. Magn. Resen., 2 (1970), 179.

    Article  Google Scholar 

  10. Nechaev, P. P., Moiseev, YU. V. and Zaikov, G. E., Vysokomolek. Soed., A14 (1972), 1048.

    Google Scholar 

  11. Moiseev, YU. V., Markin, V. S. and Zaikov, G. E., Uspekhi Khimii, 45 (1976), 510.

    Google Scholar 

  12. Vinnik, M. I. and Medvetskaya, I. M., Zhurn. Fizicheskoy Khimii, 41 (1967), 1775.

    Google Scholar 

  13. Stidila, F. H., J. Org. Chem., 37 (1972), 178.

    Article  Google Scholar 

  14. Vinnik, M. I. and Moiseev, YU. V., Tetrahedron, 19 (1963), 1441.

    Google Scholar 

  15. Moiseev, YU. V., Bakhrakh, E. YA. and Vinnik, M. I. Zhurn. Fizicheskoy Khimii, 37 (1963), 784.

    Google Scholar 

  16. Orlov, I. G., Moiseev, Yu. V. and Vinnik, M. I., Reaktsionnaya Sposobnost’ Organicheskikh Soedineniy, 2 (1965), 180.

    Google Scholar 

  17. Nechaev, P. P., Moiseev, YU. V. and Zaikov, G. E., Intern. J. Chem. Kinetics, 6 (1974), 245.

    Article  Google Scholar 

  18. Nechaev, P. P., Moiseev, YU. V. and Zaikov, G. E., Vysokomolek. Soed., A15 (1973), 702.

    Google Scholar 

  19. Korshak, V. V., Tseitlin, G. M. and Pavlov, A. I., Doklady AN SSSR, 163 (1965), 116.

    Google Scholar 

  20. YAKUBOVICH, V. S., Doklady AN SSSR, 159 (1964), 630.

    Google Scholar 

  21. Kulagin, V. N., Tseitlin, G. M., MOISEEV, YU. V. and Zaikov, G. E., Izvestiya AN SSSR, ser. khim. (1974), 1770.

    Google Scholar 

  22. Donskikh, A. I., Kulagin, V. N., Moiseev, YU. V., Tseitlin, G. M. and Zaikov, G. E., Izvestiya AN SSSR, ser. khim. (1978), 562.

    Google Scholar 

  23. Siygur, Yu. R. and Khaldna, YU. L., Reaktsionnaya Sposobnost’ Organicheskikh Soedineniy, 7 (1970), 211, 412, 431.

    Google Scholar 

  24. Vinnik, M. I. and Librovich, N. B., Reaktsionnaya Sposobnost’ Organicheskikh Soedineniy, 7 (1970), 1221.

    Google Scholar 

  25. Khaldna, YU. L. and Rodima, T. K., Reaktsionnaya Sposobnost’ Organicheskikh Soedineniy, 10 (1973), 719.

    Google Scholar 

  26. Vinnik, M. I. and Librovich, N. B., Izvestiya AN SSSR, ser. khim. (1975), 2211.

    Google Scholar 

  27. Mathieu, J. and ALME, A., Printsipy Organicheskogo Sinteza, Moscow, Mir, 1964.

    Google Scholar 

  28. Edward, J., Chem. Ind. (London), (1955), 1102.

    Google Scholar 

  29. Armstrong, H. E. and Glover, W. H., Proc. Roy. Soc., 80 (1968), 312.

    Article  Google Scholar 

  30. Khalturinskii, N. A., Moiseev, YU. V. and Zaikov, G. E., Doklady AN SSSR, 198 (1971), 149.

    Google Scholar 

  31. Andrianov, K. A. and Yakushina, S. E., Vysokomolek. Soed., 7 (1965), 613.

    Google Scholar 

  32. Razumovskii, L. P., Moiseev, YU. V. and Zaikov, G. E., Izvestiya AN SSSR, ser. khim. (1973), 2448.

    Google Scholar 

  33. Razumovskii, L. P., Moiseev, YU. V. and Zaikov, G. E., Doklady AN SSSR, ser. (1975), 1502.

    Google Scholar 

  34. Flory, P. J., Principles of Polymer Chemistry, Ithaca, Cornell University Press, 1953.

    Google Scholar 

  35. Plate, N. A., Kinetika i Mekhanism Obrazovaniya i Prevrascheniya Makromolekul, Moscow, Nauka, 1958, p. 250.

    Google Scholar 

  36. Tutorskii, I. A., Novikov, S. A. and Dogadkin, B. A., Uspekhi Khimii, 35 (1966)), 191.

    Google Scholar 

  37. Entelis, S. G. and Tiger, R. P., Kinetika Reaktsii v Zhidkoy Faze, Moscow, Khimiya, 1972.

    Google Scholar 

  38. Emanuel, M. N., Zaikov, G. E. and Maizus, Z. K., Rol’ Sredy v Radikal’notsepnykh Reaktsiyakh Okisleniya Organicheskikh Soedinenii, Moscow, Nauka, 1973.

    Google Scholar 

  39. Emanuel, N. M., Zaikov, G. E. and Maizus, Z. K., Oxidation of Organic Compounds, Effect of Medium, Oxford, Pergamon Press, 1984.

    Google Scholar 

  40. Emanuel, N. M. and Zaikov, G. E., Vysokomolek. Soed., 10A (1968), 1475.

    Google Scholar 

  41. Zaikov, G. E., Uspekhi Khimii, 44 (1975), 1805.

    Google Scholar 

  42. Berlin, AL. and Enikolopov, N. S., Vysokomolek. Soed., A10 (1968), 1475.

    Google Scholar 

  43. Ivanova, L. V., Moiseev, YU. V. and ZAIKOV, G. E., Izvestiya AN SSSR, ser. khim. (1970), 2501.

    Google Scholar 

  44. Ivanova, L. V., Moiseev, YU. V. and Zaikov, G. E., Vysokomolek. Soed., A14 (1972), 1057.

    Google Scholar 

  45. Ivanova, L. V., Moiseev, YU. V. and Zaikov, G. E., Vysokomolek. Soed., A16 (1974), 1831.

    Google Scholar 

  46. Iordanskii, A. L., Moiseev, YU. V. and Zaikov, G. E., Vysokomolek. Soed., A14 (1972), 801.

    Google Scholar 

  47. Iordanskii, A. L., Moiseev, YU. V. and Zaikov, G. E., Vysokomolek. Soed., A16 (1974), 849.

    Google Scholar 

  48. Markin, V. S., Zaikov, G. E. and Moiseev, YU. V., Vysokomolek. Soed., A12 (1970), 2174.

    Google Scholar 

  49. Zaikov, G. E., Iordanskii, A. L. and Markin, V. S., Diffuziya Elektrolitov v Polimerakh, Moscow, Khimiya, 1983.

    Google Scholar 

  50. Manin, V. N. and Gromov, A. N., Phiziko-khimicheskaya Stoikost’ Polimernykh Materialov v Usloviakh Ekspluatatsii, Leningrad, Khimiya, 1980.

    Google Scholar 

  51. Artsis, M. I., Chalykh, A. E. and Zaikov, G. E., Vysokomolek. Soed., A15 (1973), 63.

    Google Scholar 

  52. Iordanskii, A. L., Moiseev, Yu. V., Zaikov, G. E., Vysokomolek. Soed., A16 (1974), 849.

    Google Scholar 

  53. Iordanskii, A. L., Moiseev, Yu. V. AND Zaikov, G. E., Doklady An Sssr, 219 (1974), 316.

    Google Scholar 

  54. Artsis, M. I., Chalykh, A. E. AND Zaikov, G. E., Vysokomolek. Soed., A17 (1975), 128.

    Google Scholar 

  55. Iordanskii, A. L., Moiseev, Yu. V. and Zaikov, G. E., Vysokomolek. Soed., A16 (1974), 2248.

    Google Scholar 

  56. Iordanskii, A. L. and Zaikov, G. E., Diffuziya Nash Drug i Nedrug, MOSCOW, Znaniye, 1982.

    Google Scholar 

  57. Shterenzon, A. L., Reitlinger, S. A. and Topina, L, P., Trudy III Mezhdunarodnogo Kongressa po Korrozii Metallov, MOSCOW, Mir, 1968, pp. 130–41.

    Google Scholar 

  58. Bershtein, V. A. and Egorova, L. M., Vysokomolek. Soed., A19 (1977), 1260.

    Google Scholar 

  59. Nechaev, P. P., Moiseev, Yu. V. and Zaikov, G. E., Vysokomolek. Soed., A14 (1972), 1048.

    Google Scholar 

  60. Razumovskii, L. P., Moiseev, Yu. V. and Zaikov, G. E., Vysokomolek. Soed., A19 (1977), 1358.

    Google Scholar 

  61. Moiseev, Yu. V. and Zaikov, G. E., 17th Symposium on Macromolecules, Prague, 1977, p. 27.

    Google Scholar 

  62. Rudakova, T. E., Moiseev, YU. V. and Zaikov, G. E., Vysokomolek. Soed., A16 (1974), 1356; A14 (1972), 449; A17 (1975), 1797.

    Google Scholar 

  63. Pyatakina, N. K., Moiseev, YU. V. and ZAIKOV, G. E., Vysokomolek. Soed., A13 (1971), 200.

    Google Scholar 

  64. Artsis, M. I. and Chalykh, A. E., Tesisy Doklada ha Vsesoyuznoy Konferentsiipo Vysokomolekulyarnym Soedineniyam, Kazan, 1973, pp. 17 - 18.

    Google Scholar 

  65. Ivanova, L. V., Tesisy Doklada nd Konferentsii po Khimii Atsetaley, Frunze, 1971, p. 5.

    Google Scholar 

  66. Allock, H. R., J. Macromol. Sci., C, 4 (1970), 149.

    Article  Google Scholar 

  67. Methin, I. A., Piotrovskii, K. B. and Yuzhelevskii, YU. A., Zhurnal Prikladnoy Khimii, 48 (1975), 1108.

    Google Scholar 

  68. Minsker, K. S., Kolesov, S. V. and Zaikov, G. E., Destruktsiya i Stabilizatsiya Polimerov na Osnove Polivinilkhlorida, MOSCOW, Nauka, 1982.

    Google Scholar 

  69. Rudakova, T. E., Moiseev, Yu. V., Porchkhidze, A. D., Kazantseva, V. V. and Askadskii, A. A., Vysokomolek. Soed., A22 (1980), 449.

    Google Scholar 

  70. Porchkhidze, A. D., Rudakova, T. E., Moiseev, Yu. V., Kazantseva, V. V. and Askadskii, A. A., Vysokomolek. Soed., A22 (1980), 783.

    Google Scholar 

  71. Rudakova, T. E., Moiseev, Yu. V., Porchkhidze, A. D. and Zaikov, G. E., Sonderdruck aus Kunstojfe-Fortschrittsberichte, Vol. 5, Munich-Vienna, Carl Hanzer Verlag, 1979, pp. 25 – 32.

    Google Scholar 

  72. Tikhomirova, N. I., Kazantseva, A. A., Teyesakunya, G., Rudakova, T. E. and Askadskii, A. A., Vysokomolek. Soed., A20 (1978), 1543.

    Google Scholar 

  73. Askadskii, A. A., Deformatsiya Polymerov, Moscow, Khimiya, 1973.

    Google Scholar 

  74. Zaikov, G. E. and Razumovskii, S. D., Vysokomolek. Soed., A23 (1981), 513.

    Google Scholar 

  75. Rudakova, T. E., Zaikov, G. E. and Moiseev, Yu. V., 1., A17 (1975), 1791.

    Google Scholar 

  76. Pashkyavichus, V. V., Moiseev, Yu. V. and Zaikov, G. E., Nauchnoissle- dovate’skiye Trudy Lit. Nil Teksti’noy Promyshlennosti, 3 (1974), 165.

    Google Scholar 

  77. Machulis, A. N. and Tornau, E. E., Diffusionnaya Stabilizatizatsiya Polymerov, Vilnus, Mintis, 1974.

    Google Scholar 

  78. Zaikov, G. E., Markin, V. S. and Iordanskii, A. L., Plasticheskiye Massy (1982), 38.

    Google Scholar 

  79. Zaikov, G. E. and Nechaev, P. P., Vysokomolek. Soed., A26 (1984), 3.

    Google Scholar 

  80. Razumovskii, L. P., Markin, V. S. and Zaikov, G. E., Vysokomolek. Soed., A26 (1984), 5.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow, USSR

    G. E. Zaikov

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  1. G. E. Zaikov
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Editors and Affiliations

  1. Chemistry Department, The University, Glasglow, UK

    N. Grassie

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© 1985 Springer Science+Business Media Dordrecht

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Zaikov, G.E. (1985). Polymer Stability in Aggressive Media. In: Grassie, N. (eds) Developments in Polymer Degradation—6. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4940-9_3

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  • DOI: https://doi.org/10.1007/978-94-009-4940-9_3

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8689-9

  • Online ISBN: 978-94-009-4940-9

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