Abstract
The aim of this chapter is to provide a general overview of the structure/property behaviour of segmented copolymers, with the principal emphasis being on segmented elastomers. While the authors have emphasized the segmented urethanes, information regarding the segmented polyether/polyester materials, as well as some information on the segmented urethane-urea materials, is also provided. Where possible, contrast is made with the ‘long block’ ABA block copolymers discussed in several of the other chapters within this book. While the authors provide several comments concerning specific work of other researchers in the literature, caution should be taken with regard to readily applying the structure-property behaviour from one system to that of another of varied chemistry. Rather, it is hoped that the information provided by this chapter will induce some understanding of the general structure/property aspects that arise from the wide diversification of chemistry and processing variables that may influence the final behaviour of these materials.
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References
Treloar, L. R. G. (1974). Rubber Chem. Technol, 47 (3), 625.
Noshay, A. and McGrath, J. E. (Eds), (1973). Block Copolymers, Wiley, New York.
Lagasse, R. R. (1977). J. Appl. Polym. Sci, 21, 2489.
Brunette, C. M., Hsu, S. L, Rossman, M., MacKnight, W. J. and Schneider, N. S. (1981). Polym. Eng. Sci 21(11), 668; 21(3), 163.
Ono, K., Shimadu, H., Nishimuro, T., Yamashita, S., Okamoto, H. and Minoura, Y. (1977). J. Appl. Polym. Sci, 21, 3223.
Schneider, N. S. and Matton, R. W. (1977). Polym. Eng. Sci., 19(15), 1122.
Dole-Robbe, J. P. (1937). Bull. Soc. Chim. Fr, 3, 1978.
Graham, S. W. and Hercules, D. M. (1981). J. Bio. Med. Mat. Res, 15, 349.
Saunders, J. H. and Frisch, K. C. (1962). Polyurethanes, Chemistry and Technology, Part I, Interscience, New York.
Lee, L. J. (1981). Rubber Chem. Technol, 53, 542.
Meyer, D. A. (1964). In: Vulcanization of Elastomers, (Ed. G. Alliger and I. J. Sjothun), Reinhold, New York, lib.
Gruber, E. E. and Keplinger, O. C. (1959). Ind. Eng. Chem, 51 (2), 151.
Cluff, E. F. and Gladding, E. K. (1960). J. Appl. Polym. Sci, 3, 290.
Pattison, D. B. assignor to E. I. du Pont de Nemours and Co., US Patent 2 808 391, October 1, 1957.
Wright, P. and Cumming, A. P. C. (1969). Solid Polyurethane Elastomers, Gordon and Breach, New York.
Urs, S. V. (1962). Ind. Eng. Chem. Prod. Res. Dev, 1 (3), 199.
Schollenberger, C. S. and Dinbergs, K. (1978). J. Polym. Sci. Polym. Symp, 64, 351.
Schollenburger, C. S. (1969). In: Polyurethane Technology, Ch. X, ( Ed. P. F. Bruins) Interscience, New York.
Sung, C. S. P., Schneider, N. S., Matton, R. W. and Illinger, J. L. (1974). Poly. Prepr., Am. Chem. Soc., Polym. Chem. Div, 15 (1), 620.
MacKnight, W. J., Yang, M. and Kajiyama, T. (1968). Anal. Calorimetry, Proc. Am. Chem. Soc. Symp., 99.
Allport, D. C. and Mojaher, A. A. (1973). In:Block Copolymers, (Ed. D. C. Allport and W. H. James), Applied Science Publishers Ltd, London, Ch. 8C.
Bonart, R, Morbitzer, L. and Muller, H. (1968). J. Macromol. Sci., Phys, 3 (2), 337.
Hepburn, C. and Reynolds, R. J. W. (Eds), (1980). Elastomers: Criteria for Engineering Design, Applied Science Publishers Ltd, London, p. 323.
Ludwico et al. The Bayflex 110 Series Society of Automotive Engineers Car Meeting, Detroit, September 26.
Heikens, D., Meijers, A. and von Reth, P. H. (1968). Polymer, 9.
Bonart, R., Morbitzer, L. and Rinke, H. (1970). Kolloid-Z, 240, 807.
B. F. Goodrich Co, British Patent 1025 970 (15.7.63); Equip. Can. 739 034.
Critchfield, E. E, Koleske, J. V, Magnus, G. and Dodd, J. L. (1972). J. Elastoplast, 4, 22.
Pigott, K. A, Frye, B. F, Allen, K. R, Steingiser, S, Darr, W. C, Saunders, J. H. and Hardy, E. E. (1960). J. Chem. Eng. Data, 5, 391.
Hoeschele, G. K. and Witsiepe, W. K. (1973). Angew. Makromol. Chem 29/30,267.
Hoechele, G. K. (1974). Chimia, 28, 544.
Hoeschele, G. K. (1977). Angew. Makromol. Chem 58/59 299.
Cella, R. J. (1977). In: Encyclopedia of Polymer Science and Technology, (Ed. H. F. Mark et al.) Suppl. Vol. II, J. Wiley & Sons, New York, p. 485.
Cella, R. J. (1973). J. Polym. Sci., Polym. Symp, 42, 727.
Wolfe, J. R. (1974). Rubber Chem. Technol, 50 (4), 688.
Wegner, G., Fujii, T., Meyer, W., and Lieser, G. (1978). Angew. Makromol Chem, 74 (1204), 295.
Schollenberger, C. S., and Dinbergs, K. J. (1979). Elastoplastics, 11, 58.
Schollenberger, C. S. and Dinbergs, K. J. (1973). Elastoplastics, 5, 222.
Schneider, N. S, Dusablon, L. V, Snell, E. W. and Prosser, R. A. (1969). J. Macromol Sci.-Phys, 3 (4), 623.
Allport, D. C. and Mohajer, A. A. (1973). In: Block Copolymers, (Ed. D. C. Allport and W. H. James), Applied Science Publishers Ltd, Londong, Ch. 5C.
Trappe, G. (1968). In: Advances in Polyurethane Technology, (Ed. J. M. Buirt), John Wiley and Sons, New York.
West, J. C. and Cooper, S. L. (1978). In: Science and Technology of Rubber, (Ed. F. R. Eirich), Academic Press Inc., New York, Ch. 13.
Fridman, I. D., Thomas, E. L., Lee, L. J. and Macosko, C. W. (1980). Polymer, 21, 393.
Castro, J. M., Macosko, C. W., Critchfield, F. W., Steinle, E. C. and Tackett, L. P. (1980). Elastoplastics, 12, 3.
Lee, L. J. and Macosko, C. W. (1978). Soc. Plast. Eng., ANTEC Papers, 24, 155.
Case, L. C. (1958). J. Polym. Set, 29, 455.
Macosko, C. W. and Miller, D. R. (1976). Macromol, 9, 199.
Lee, L. J., Ottino, J. M. and Macosko, C. W. (1979). Soc. Plast. Eng, 25, 439.
Becker, W. E. (Ed.), (1979). Reaction Injection Molding, Van Nostrand Reinhold Company, New York.
Dow Chemical Company, US Patent 4 269 945.
Bonart, R. and Muller, E. H. (1974). J. Macromol Sci. Phys, 10, 177.
Bogarchuk, Y. M., Rappaport, L. Y., Nikitin, V. N. and Apukthina, N. P. (1965). Polym. Sci, USSR, 7, 859.
Ophir, Z. and Wilkes, G. L. (1980). J. Polym. Sci, Phys, 18, 1469.
Weisfeld, L. B., Little, J. R. and Walstenholme, W. E. (1962). J. Polym. Sci, 56, 455.
Morbitzer, L. and Hespe, H. (1972). J. Appl Polym. Sci, 16, 2697.
Apukthina, N. P., Zimine, M. G., Novoselok, F. B. and Myulla, B. E. (1972). Tr. Meshdunar, Konf. Kauch. Rezine, 77.
Morbitzer, L. and Bonart, R. (1969). Kolloid-Z, 232, 764.
Eastman Kodak Co. British Patent 1 118 731 (29.6.64).
B. F. Goodrich Co. US Patent 2 871 218 (1.12.55).
Bayer, O., Muller, E., Peterson, S., Piepenbrink, H. F. and Windemath, E. (1950). Rubber Chem. Tech, 23, 812; (1950). Agnew. Chem, 62, 157.
Union Carbide, Belgian Patent 649, 619 (24.6.63, 28.5.64).
Yilgor, I., Shah’aban, A., Steckle, W. P., Jr. Tyagi, D., Wilkes, G. L. and McGrath, J. E. Segmented organo siloxane copolymers, I. Synthesis of siloxane — urea copolymers, Polymer (in press).
Tyagi, D., Yilgor, I., McGrath, J. E. and Wilkes, G. L. Segmented organo siloxane copolymers, II. Thermal and mechanical properties of siloxane — urea copolymers, Polymer (in press).
Bonart, R. (1968). J. Macromol Sci., Phys, 2 (1), 115.
Bonart, R., Morbitzer, L. and Hentze, G. (1969). J. Macromol Sci., Phys, 3 (2), 337.
Bonart, R, Morbitzer, L. and Muller, E. H. (1974). J. Macromol Sci., Phys, 9, 447.
Blackwell, J., Nagarajan, M. R. and Hoitiuk, T. B. (1982). Polymer, 23, 950.
Peebles, L. H. (1976). Macromolecules, 9, 58.
Harrell, L. L. (1969). Macromolecules, 2 (6), 607.
Samuel, S. L. and Wilkes, G. L. (1971). J. Polym. Sci, 11 (5), 369.
Ng, H. N, Allegrezza, A. E, Seymour, R. W. and Cooper, S. L. (1973). Polymer, 14, 255.
Gianflauio, L., Sumida, Y. and Vogl, D. (1980). Angew. Makromol Chem 87, 1
Samuels, S. L. and Wilkes, G. L. (1978). J. Polym. Sci., Polym Symp, 43, 149.
Wilkes, G. L., Samuels, S. L. and Crystal, R. (1974). J. Macromol Sci., Phys, 10, 203.
Seymour, R. W. and Cooper, S. L. (1973). Macromolecules, 6, 48.
Estes, G. M., Seymour, R. W. and Cooper, S. L. (1971). Macromolecules, 4, 452.
Cooper, S. L. and Seymour, R. W. (1973). In: Block and Graft Copolymers, (Ed. J. J. Burke and V. Weiss), Syracuse Univ. Press, New York.
Ishihara, H., Kimura, I., Saito, K. and Ono, H. (1974). J. Macromol Sci., Phys, B10, 591.
Pimentel, G. C. and McClellan, A. L. (1960). The Hydrogen Bond, Freeman, San Francisco.
Hannon, M. J. and Koenig, J. L. (1969). J. Polym. Sci., Part A2, 7, 1005.
Senich, G. A. and MacKnight, W. J. (1980). Macromolecules, 13, 106.
Sung, C. S. P. (1980). In: Polymer Alloys— II, (Ed. D. Klempner and K. C. Frisch), Plenum Publ. Co., New York.
Wilkes, G. L. and Abouzahr, S. (1981). Macromolecules, 14, 456.
Bonart, R. and Muller, E. H. (1974). J. Macromol Sci,, Phys, 10, 177.
Blackwell, J. and Gardner, K. H. (1979). Polymer, 20, 13.
Koberstein, J. and Stein, R. S. Private communication.
Koutsky, J. A., Hien, N. V. and Cooper, S. L. (1970). J. Polym. Sci., Part B, 8 (5), 353.
Fridman, I. D. and Thomas, E. L. (1980). Polymer, 21, 388.
Lilaonitkul, A., West, J. C. and Cooper, S. L. (1976). J. Macromol Sci. Phys, B12 (4), 563.
Shen, M., Mehra, U., Niinomi, M., Koberstein, J. T. and Cooper, S. L. (1974). J. Appl Phys, 45 (10), 4182.
West, J. C, Lilaonitkul, A, Cooper, S. L., Mehra, U. and Shen, M. (1974). Polym. Prep. Am. Chem. Soc, 15 (2), 191.
Chang, P. and Wilkes, G. L. (1975). J. Polym. Sci, 13, 455.
Schneider, N. S, Desper, C. R, Illinger, J. L, King, A. O. and Barr, D. (1975). J. Macromol. Sci, B11, 527.
Kimura, I, Ishihara, H. and Ono, H. (1971). IUPAC Macromol. Prepr, 23 (1), 525.
Kimura, I, Ishihara, H, Ono, H, Yoshihara, N., Nomura, S. and Kawai, H. (1973). Macromolecules, 7, 355.
Mody, P. and Wilkes, G. L. (1981). J. Appl. Polym. Sci, 26, 2853.
Cooper, S. L. and Tobolsky, A. V. (1967). J. Appl. Polym. Sci, 11, 1361.
Holden, G,Bishop, E. T. and Legge, N. R. (1969). J. Polym. Sci, C26, 37.
Kimball, M. E. and Fielding-Russel, G. S. (1977). Polymer, 18, 1777.
Nishi, T. (1973) J. Appl. Polym. Sci., Appl. Polym. Symp.,20 , 353
Fulcher, K. U. and Corbett, G. E. (1975). Br. Polym. J, 7, 225.
Miller, G. W. (1971). J. Appl. Polym. Sci, 15, 39.
Ophir, Z. H. and Wilkes, G. L. (1978). Adv. Chem. Series, 176, 53.
Assink, R. A. and Wilkes, G. L. (1977). Polym. Eng. Sci, 17, 606.
Abouzahr, S. and Wilkes, G. L. (1980). Polym. Prep. Amer. Chem. Soc, 21 (2), 193.
Joseph, E., Wilkes, G. L. and Park, K. (1981). J. Appl. Polym. Sci, 26, 3355.
Bagrodia, S, Wilkes, G. L., Humphries, W. and Wildnauer, R. (1975). J. Polym. Lett, 13, 321.
Wildnauer, R. and Wilkes, G. L. (1975). J. Appl. Phys, 46, 4148.
Hesketh, T. R. and Cooper, S. L. (1977). Org. Coatings Plast. Chem., Am. Chem. Soc, 37, 509.
Hesketh, T. R, VanBogart, J. W. C. and Cooper, S. L. (1980). Polym. Eng. Sci, 20 (3), 190.
Jacques, C. H. M. (1977). In: Polymer Alloys, Blends, Blocks, Grafts, and Interpenetrating Networks, (Ed. D. Klempner and K. C. Frisch), Plenum Press, New York.
Abouzahr, S., Wilkes, G. L. and Ophir, Z. (1982). Polymer, 23, 1079.
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Abouzahr, S., Wilkes, G.L. (1985). Segmented Copolymers with Emphasis on Segmented Polyurethanes. In: Folkes, M.J. (eds) Processing, Structure and Properties of Block Copolymers. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4936-2_5
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DOI: https://doi.org/10.1007/978-94-009-4936-2_5
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