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Chemistry of Hydrocarbon Combustion pp 327–377Cite as

Pyrolytic reactions of hydrocarbons

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Abstract

The Principal chemical feedstock obtained by the processing of crude oil is naphtha, which, in Europe, is the prime source of petrochemicals such as ethylene, propene, butenes, aromatics, etc. An enormous and diverse chemical industry has grown up, relying on such petrochemicals [1,2]. These compounds are produced by the thermal reactions of hydrocarbons and for this reason pyrolysis is of the greatest importance. Significant variations in product distributions are possible, depending on the feed composition and pyrolysis conditions. The ability to adjust the selectivity of a process according to market fluctuations greatly increases the profitability of chemical plants and the design of units having flexibility requires extensive and precise kinetic equations and detailed product analyses for the thermal reactions of parent hydrocarbons and products.

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References

  1. Hucknall, D. J. (1974) Selective Oxidation of Hydrocarbons, Academic Press, London

    Google Scholar 

  2. Cullis, C. F. and Hucknall, D. J. (1982) in Catalysis, Vol. 5, Royal Society of Chemistry, London, p. 273

    Google Scholar 

  3. Rice, F. O. (1931) J. Am. Chem. Soc, 53, 1959

    Google Scholar 

  4. Rice, F. O. (1933) J. Am. Chem. Soc, 55, 3053

    Google Scholar 

  5. Kalinenko, R. A. and Nametkin, N. S. (1982) Kinet. Catal, 23, 254

    Google Scholar 

  6. Heffington, W. M., Parks, G. E., Sulzmann, K. G. P. and Penner, S. S. (1977) 16th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 997

    Google Scholar 

  7. Roth, P. and Just, Tb. (1975) Ber. Bunsenges. Phys. Chem, 79, 682

    Google Scholar 

  8. Tabayashi, K. and Bauer, S. H. (1979) Combust. Flame, 34, 63

    Google Scholar 

  9. Allara, D. L. and Shaw, R. (1980) J. Phys. Chem. Ref. Data, 9, 523

    Google Scholar 

  10. Baulch, D. L. and Duxbury, J. (1980) Combust. Flame, 37, 313

    Google Scholar 

  11. Olson, D. B. and Gardiner, W. C. Jr (1979) J. Phys. Chem, 83, 922

    Google Scholar 

  12. Kanan, K., Purnell, H. and Sepherad, A. (1983) Int. J. Chem Kinet, 15, 845

    Google Scholar 

  13. Skinner, G. B., Rogers, D. and Patel, K. B. (1981) Int. J. Chem. Kinet, 13, 481

    Google Scholar 

  14. Kanan, K., Purnell, H. and Smith, E. (1983) Int. J. Chem. Kinet, 15, 63

    Google Scholar 

  15. Simmie, J. M., Gardiner, W. C. Jr and Eusbank, C. S. (1982) J. Phys. Chem, 86, 799

    Google Scholar 

  16. Koike, T. and Gardiner, W. C. Jr (1980) J. Phys. Chem, 84, 2005

    Google Scholar 

  17. Jezequel, J. Y., Baronnet, F. and Niclause, M. (1978) J. Chim. Phys, 75, 773, 991

    Google Scholar 

  18. Juste, C., Scacchi, G. and Niclause, M. (1981) Int. J. Chem. Kinet, 13, 855

    Google Scholar 

  19. Davis, H. G. and Williamson, K. D. (1979) in Thermal Hydrocarbon Chemistry (ACS Adv. Chem. Ser, No. 183), American Chemical Society, Washington DC, p. 41

    Google Scholar 

  20. Baldwin, R. R., Hisham, M. W. M., Keen, A. and Walker, R. W. (1982) J. Chem. Soc., Faraday Trans. I, 78, 1165

    Google Scholar 

  21. Ebert, K. H., Ederer, H. J. and Isbarn, G. (1983) Int. J. Chem. Kinet, 15, 475

    Google Scholar 

  22. Isbarn, G., Ederer, H. J. and Ebert, K. H. (1981) in Modelling Chemical Reaction Systems(eds K. H. Elset, P. Deufhard and W. Jager), Springer-Verlag, Berlin, p. 235

    Google Scholar 

  23. Edelson, D. and Allara, D. L. (1980) Int. J. Chem. Kinet, 12, 605

    Google Scholar 

  24. Zalotai, L., Márta, F, Bérces, T. and Halász, D. (1979) Oxid. Commun, 1, 85

    Google Scholar 

  25. Notzold, D. and Algermissen, J. (1981) Combust. Flame, 40, 293

    Google Scholar 

  26. Hartig, R., Troe, J. and Wagner, H. Gg. (1963) J. Phys. Chem, 67, 709

    Google Scholar 

  27. Hartig, R., Troe, J. and Wagner, H. Gg. (1971) 13th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 147

    Google Scholar 

  28. Chen, C., Back, M. H. and Back, R. A. (1975) Can. J. Chem, 53, 3580

    Google Scholar 

  29. Chen, C., Back, M. H. and Back, R. A. (1976) Can. J. Chem, 54, 3175

    Google Scholar 

  30. Chen, C., Back, M. H. and Back, R. A. (1976) in Industrial and Laboratory Pyrolyses (ACS Symp. Ser, No. 32), American Chemical Society, Washington DC, p. 1

    Google Scholar 

  31. Tardieu de Meleissye, J. and Delbourgo, R. (1969) Bull. Soc. Chim. Fr., 1108

    Google Scholar 

  32. Tardieu de Meleissye, J. and Delbourgo, R. (1970) Bull. Soc. Chim. Fr., 60

    Google Scholar 

  33. Schneider, I. A. and Margulescu, I. G. (1968) Z. Phys. Chem, 237, 81

    Google Scholar 

  34. Lin, M. C. and Back, M. H. (1966) Can. J. Chem, 44, 505

    Google Scholar 

  35. Scacchi, G., Martin, R. and Niclause, M. (1971) Bull. Soc. Chim. Fr., 731

    Google Scholar 

  36. Pratt, G. L. and Rogers, D. (1979) Chem. Soc., Faraday Trans. I, 75, 1089

    Google Scholar 

  37. Baulch, D. L. and Duxbury, J. (1980) Combust. Flame, 37, 313

    Google Scholar 

  38. Billaud, F., Baronnet, F. and Niclause, M. (1980) J. Chim. Phys., Phys. Chim. Biol, 11, 357

    Google Scholar 

  39. Decarreau, J. F., Deschamps, B., Scacchi, G. and Niclause, M. (1974) J. Chim. Phys., Phys. Chim. Biol, 71, 554

    Google Scholar 

  40. Olson, D. B. and Gardiner, W. C., Jr (1979) J. Phys. Chem, 83, 922

    Google Scholar 

  41. Volkan, A. G. and April, G. C. (1977) Ind. Eng. Chem., Process Des. Dev, 16, 429

    Google Scholar 

  42. Raseev, S., Iorgulescu, C. and Besnea, D. (1980) Rev. Chim. (Bucarest), 31, 336

    Google Scholar 

  43. Koenig, M., Reiher, T., Radeck, D. and Nowack, S. (1980) Chem. Tech. (Leipzig), 32, 249

    Google Scholar 

  44. Bradley, J. N. (1979) J. Chem. Soc., Faraday Trans. I, 75, 2819

    Google Scholar 

  45. Kao, W.-L. and Yeh, C. (1977) J. Phys. Chem, 81, 2304

    Google Scholar 

  46. Pratt, G. and Rogers, D. (1979) Chem. Soc., Faraday Trans. I, 75, 1107

    Google Scholar 

  47. Juste, C., Scacchi, G. and Niclause, M. (1981) Int. J. Chem. Kinet, 13, 855

    Google Scholar 

  48. Hautmann, D. J., Santoro, R. J., Dryer, F. L. and Glassmann, I. (1982) Int. J. Chem. Kinet, 13, 149

    Google Scholar 

  49. Layokun, S. K. and Slater, D. H. (1979) Ind. Eng. Chem., Prod. Res. Dev, 18, 232

    Google Scholar 

  50. Layokun, S. K. (1979) Ind. Eng. Chem., Prod. Res. Dev., 18, 241

    Google Scholar 

  51. Leathard, D. A. and Purnell, J. H. (1968) Proc. R. Soc. Lond. A, 305, 517

    Google Scholar 

  52. Lifshitz, A. and Frenklach, M. (1975) J. Phys. Chem, 79, 686

    Google Scholar 

  53. Herriot, G. E., Eckert, R. E. and Albright, L. F. (1972) A.I.Ch.E. J, 18, 84

    Google Scholar 

  54. Taylor, J. E. and Kulich, D. M. (1976) in Industrial and Laboratory Pyrolyses (ACS Symp. Ser, No. 32) (eds L. F. Albright and B. L. Crynes), American Chemical Society, Washington, DC, p. 72

    Google Scholar 

  55. Martin, R., Niclause, M. and Dzierzynski, M. (1962) C.R. Acad. Sci. Paris, 254, 1786

    Google Scholar 

  56. Martin, R., Niclause, M. and Dzierzynski, M. (1964) J. Chim. Phys., 61, 286, 790, 802

    Google Scholar 

  57. Karnaukhova, L. I. and Stepukhovich, A. D. (1975) Russ. J. Phys. Chem, 49, 323

    Google Scholar 

  58. Karnaukhova, L. I. and Stepukhovich, A. D. (1979) Zh. Fiz. Khim, 53, 2617

    Google Scholar 

  59. Purnell, J. H. and Quinn, C. P. (1962) Proc. R. Soc. Lond. A, 270, 267

    Google Scholar 

  60. Pacey, P. D. and Purnell, J. H. (1972) Int. J. Chem. Kinet., 4, 657

    Google Scholar 

  61. Hughes, D. H., Marshall, R. M. and Purnell, J. H. (1974) J. Chem. Soc., Faraday Trans. I, 70, 594

    Google Scholar 

  62. Pratt, G. L. and Rogers, D. (1979) J. Chem. Soc., Faraday Trans. I, 75, 2688

    Google Scholar 

  63. Blakemore, J. E., Barker, J. R. and Corcoran, W. H. (1973) Ind. Eng. Chem. Fundam, 12, 147

    Google Scholar 

  64. Martin, R., Niclause, M. and Scacchi, G. (1976) in Industrial and Laboratory Pyrolyses (ACS Symp. Ser, No. 32) (eds L. F. Albright and B. L. Crynes), American Chemical Society, Washington DC, p. 37

    Google Scholar 

  65. Illes, V. (1971) Acta Chim (Budapest), 67, 339

    Google Scholar 

  66. Konar, R. S., Marshall, R. M. and Purnell, J. H. (1973) Int. J. Chem. Kinet, 5, 1007

    Google Scholar 

  67. Koike, T. and Morinaga, K. (1982) Bull. Chem. Soc. Jpn, 55, 690

    Google Scholar 

  68. Bradley, J. N. (1974) Proc. R. Soc. Lond. A, 337, 199

    Google Scholar 

  69. Pratt, G. L. and Rogers, D. (1980) J. Chem. Soc., Faraday Trans. I, 76, 1694

    Google Scholar 

  70. Halstead, M. P., Konar, R. S., Leathard, D. A., Marshall, R. M. and Purnell, J. H. (1969) Proc. R. Soc. Lond. A, 310, 525

    Google Scholar 

  71. Engel, J., Combe, A., Letort, M. and Niclause, M. (1957) C. R. Acad. Sci. Paris, 244, 453

    Google Scholar 

  72. Baronnet, F., Come, G. M. and Niclause, M. (1974) J. Chim. Phys, 71, 1214

    Google Scholar 

  73. Baronnet, F., Dzierzynski, M., Come, G. M., Martin, R. and Niclause, M. (1971) Int. J. Chem. Kinet, 3, 197

    Google Scholar 

  74. Rondeau, J. A., Come, G. M. and Large, J. F. (1976) in Industrial and Laboratory Pyrolyses (ACS Symp. Ser, No. 32) (eds L. F. Albright and B. L. Crynes), American Chemical Society, Washington DC, p. 131

    Google Scholar 

  75. Bradley, J. N. and West, K. O. (1976) J. Chem. Soc., Faraday Trans. I, 72, 8

    Google Scholar 

  76. Pacey, P. D. and Wimalasena, J. H. (1980) J. Phys. Chem, 84, 2221

    Google Scholar 

  77. Allara, D. L. and Edelson, D. (1975) Int. J. Chem. Kinet, 7, 479

    Google Scholar 

  78. Zykova, G. I. and Stepukhovich, A. D. (1970) Kinet. Katal, 11, 1371

    Google Scholar 

  79. Frey, F. E. and Hepp, H. J. (1933) Ind. Eng. Chem, 25, 441

    Google Scholar 

  80. Illes, V., Welther, K. and Pleszkats, I. (1973) Acta Chim. Acta Sci. Hung, 78, 357

    Google Scholar 

  81. Illes, V., Pleszkats, I. and Szepesy, L. (1973) Acta Chim. Acta Sci. Hung, 78, 259

    Google Scholar 

  82. Szepesy, I., Illes, V., Welther, K. and Simon, J. (1973) Acta Chim. Acta Sci. Hung, 78, 341

    Google Scholar 

  83. Chrysochoos, J. and Bryce, W. A. (1965) Can. J. Chem, 43, 2092

    Google Scholar 

  84. Billaud, F., Baronnet, F. and Niclause, M. (1982) React. Kinet. Catal. Lett, 19, 125

    Google Scholar 

  85. Iosif, I., Bozesanu, M., Ionescu, N. I. and Pop, G. (1980) Rev. Chim. (Bucharest), 31, 321

    Google Scholar 

  86. Gorokhovskii, A. V. and Stepukhovich, A. D. (1981) Kinet. Catal, 22, 647

    Google Scholar 

  87. Mellottee, H., Tardieu de Maleiysse, J. and Delbourgo, R. (1969) Bull. Soc. Chim. Fr., 448

    Google Scholar 

  88. Boyd, M. L., Wu, Y.-M. and Back, M. H. (1969) Can. J. Chem, 46, 2415

    Google Scholar 

  89. Simon, M. and Back, M. H. (1969) Can. J. Chem, 47, 251

    Google Scholar 

  90. Halstead, M. P. and Quinn, C. P. (1968) Trans. Faraday Soc, 64, 103

    Google Scholar 

  91. Kunugi, T., Sakai, T., Soma, K. and Sasaki, Y. (1969) Ind. Eng. Chem. Fundam.,374; (1968) Kogyo Kagaku Zasshi, 71, 689

    Google Scholar 

  92. Haraguchi, T., Nakashiro, F. and Sakai, W. (1972) Kagaku Kogaku 36 1223; Chem. Abstr., 78, 45947r

    Google Scholar 

  93. Sakai, T., Soma, K., Tominaga, H. and Kunugi, T. (1970) in Refining Petroleum for Chemicals (ACS Adv. Chem. Ser, No. 97), American Chemical Society, Washington DC, p. 68

    Google Scholar 

  94. Back, M. H. and Martin, R. (1979) Int. J. Chem. Kinet, 11, 757

    Google Scholar 

  95. Ayranci, G. and Back, M. H. (1981) Int. J. Chem. Kinet, 13, 879

    Google Scholar 

  96. Jachimowski, C. J. (1977) Combust. Flame, 29, 55

    Google Scholar 

  97. Just, Th., Roth, P. and Damm, R. (1977) 16th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 961

    Google Scholar 

  98. Kiefer, J. H., Kapsalis, S. A., Al-Alami, M. Z. and Budach, K. A. (1983) Combust. Flame, 51, 79

    Google Scholar 

  99. Tanzawa, T. and Gardiner, W. C. Jr (1980) Combust. Flame, 39, 241

    Google Scholar 

  100. Westbrook, C. K., Dryer, F. L. and Schug, K. P. (1982) 19th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 153

    Google Scholar 

  101. Laidler, K. J. and Wojciechowski, B. W. (1960) Proc. R. Soc. Lond. A, 259, 257

    Google Scholar 

  102. Amano, A. and Uchiyame, M. (1964) J. Phys. Chem, 68, 1133

    Google Scholar 

  103. Sakakibara, Y. (1964) Bull. Chem. Soc. Jpn, 37, 1262, 1268

    Google Scholar 

  104. Kallend, A. S., Purnell, J. H. and Shurlock, B. C. (1967) Proc. R. Soc. Lond. A, 300, 120

    Google Scholar 

  105. Mellottee, H., Tardieu de Maleissye, J. and Delbourgo, R. (1969) Bull Soc. Chi. Fr., 2652

    Google Scholar 

  106. Kunugi, T., Sakai, T., Soma, K. and Sasaki, Y. (1980) Ind. Eng. Chem. Fundam., 9,314

    Google Scholar 

  107. Kunugi, T., Soma, K. and Sakai, T. (1970) Ind. Eng. Chem. Fundam, 9, 319

    Google Scholar 

  108. Simon, M. and Back, M. H. (1970) Can. J. Chem, 48, 317

    Google Scholar 

  109. Simon, M. and Back, M. H. (1973) Can. J. Chem, 51, 2934

    Google Scholar 

  110. Sims, J., Kershenbaum, L. and Shroff, J. (1971) Ind. Eng. Chem., Process Des. Dev, 10, 265

    Google Scholar 

  111. Laidler, K. J. and Loucks, L. F. (1972) in Comprehensive Chemical Kinetics Vol. 5 eds C. H. Bamford and C. F. H. Tipper), Elsevier, Amsterdam, p. 1

    Google Scholar 

  112. Ghaly, M. A. and Crynes, B. L. (1976) in Industrial and Laboratory Pyrolyses (ACS Symp. Ser, No. 32), American Chemical Society, Washington DC, p. 218

    Google Scholar 

  113. Mellottee, H. and Delbourgo, R. (1970) Bull. Soc. Chim. Fr., 3473

    Google Scholar 

  114. Shibatani, H. and Kinoshita, H. (1973) Nippon Kagaku Kaishi, 1005

    Google Scholar 

  115. Leftin, H. P. (1979) in Thermal Hydrocarbon Chemistry (ACS Adv. Chem. Ser, No. 183), American Chemical Society, Washington DC, p. 21

    Google Scholar 

  116. Powers, D. R. and Corcoran, W. H. (1976) in Industrial and Laboratory Pyrolyses04CS Symp. Ser, No. 32), American Chemical Society, Washington DC, p. 117

    Google Scholar 

  117. Murgulescu, I. G. and Bica, I. (1974) Rev. Roum. Chim, 19, 1941

    Google Scholar 

  118. Leftin, H. P. and Cortes, A. (1972) Ind. Eng. Chem., Process Des. Dev, 11, 613

    Google Scholar 

  119. Miller, D. B. (1963) Ind. Eng. Chem., Prod. Des. Dev., 2, 221

    Google Scholar 

  120. Vinnitskii, O. M., Rumyantsev, A. N., Musaev, I. A., Sanin, P. I. and Lavrovskii, K. P. (1973) Neftekh, 13, 528

    Google Scholar 

  121. Rebick, C. (1979) in Thermal Hydrocarbon Chemistry (ACS Adv. Chem. Ser, No. 183), American Chemical Society, Washington DC, p. 1

    Google Scholar 

  122. Sakai, T., Nohara, D. and Kunugi, T. (1976) in Industrial and Laboratory Pyrolyses (ACS Symp. Ser, No. 32), American Chemical Society, Washington DC, p. 152

    Google Scholar 

  123. Polak, L. S. (1971) Proc. 8th World Petrol. Congr, Vol. 4, Appl. Sci. Publ. Ltd., London, p. 347

    Google Scholar 

  124. Nagy, Z. S., Kovacs, A. and Sebestyen, Z. (1970) Ger. Offen. 1 943 823; Chem. Abstr, 72, 92015w

    Google Scholar 

  125. Cullis, C. F., Minkoff, G. J. and Nettleton, M. A. (1962) Trans. Faraday Soc, 58, 1117

    Google Scholar 

  126. Minkoff, G. J., Newitt, D. M. and Rutledge, P. (1957) J. Appl. Chem, 1, 406

    Google Scholar 

  127. Cullis, C. F. and Franklin, N. H. (1964) Proc. R. Soc. Lond. A, 280, 139

    Google Scholar 

  128. Badger, G. M., Lewis, G. E. and Napier, I. M. (1960) J. Chem. Soc., 2825

    Google Scholar 

  129. Stehling, F. C., Frazee, J. D. and Anderson, R. C. (1957) 6th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 247

    Google Scholar 

  130. Stehling, F. C., Frazee, J. D. and Anderson, R. C. (1962) 8th Symp. (Int.) on Combustion, Williams and Wilkins, Baltimore, p. 775

    Google Scholar 

  131. Ogura, H. (1977) Bull. Chem. Soc. Jpn, 50, 1044

    Google Scholar 

  132. Ogura, H. (1977) Bull. Chem. Soc. Jpn, 50, 2051

    Google Scholar 

  133. Gay, I. D., Kistiakowsky, G. B., Michael, J. V. and Niki, H. (1965) J. Chem. Phys, 43, 1720

    Google Scholar 

  134. Bonne, U., Homann, K. H. and Wagner, H. Gg. (1965) 10th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 503

    Google Scholar 

  135. Cundall, R. B., Fussey, D. E., Harrison, A. J. and Lampard, D. (1979) J. Chem. Soc., Faraday Trans. I, 74, 1403

    Google Scholar 

  136. Palmer, H. B. and Dormish, F. L. (1964) J. Phys. Chem, 68, 1553

    Google Scholar 

  137. Silcocks, C. G. (1957) Proc. R. Soc. Lond. A, 242, 411

    Google Scholar 

  138. Back, M. H. (1971) Can. J. Chem, 49, 2119

    Google Scholar 

  139. Cullis, C. F. and Read, I. A. (1970) Trans. Faraday Soc, 66, 920

    Google Scholar 

  140. Tanzawa, T. and Gardiner, W. C. Jr (1979) 17th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 563

    Google Scholar 

  141. Skinner, G. B. and Sokolowski, E. M. (1960) J. Phys. Chem, 64, 1952

    Google Scholar 

  142. Tanzawa, T. and Gardiner, W. C. Jr (1980) J. Phys. Chem, 84, 236

    Google Scholar 

  143. Skinner, G. B. and Sokolowski, E. M. (1960) J. Phys. Chem, 64, 1028

    Google Scholar 

  144. Munson, M. S. B. and Anderson, R. C. (1963) Carbon, 1, 51

    Google Scholar 

  145. Hou, K. C. and Anderson, R. C. (1963) J. Phys. Chem, 67, 1579

    Google Scholar 

  146. Hou, K. C. and Palmer, H. B. (1965) J. Phys. Chem, 69, 858

    Google Scholar 

  147. Zdonik, S. B., Green, E. J. and Hallee, L. P. (1967) Oil Gas J., 64

    Google Scholar 

  148. Fabuss, B. M., Katesjian, R., Smith, J. O. and Satterfield, C. N. (1964) Ind. Eng. Chem., Process Des. Dev, 3, 248

    Google Scholar 

  149. Virk, P. S., Korosi, A. and Woebcke, H. N. (1979) in Thermal Hydrocarbon Chemistry (ACS Adv. Chem. Ser., No. 183) American Chemical Society, Washington DC, p. 67

    Google Scholar 

  150. Asaba, T. and Fujii, N. (1971) 13th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 155

    Google Scholar 

  151. Fujii, N. and Asaba, T. (1973) 14th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 433

    Google Scholar 

  152. Graham, S. C., Homer, J. B. and Rosenfeld, J. L. J. (1975) Proc. R. Soc. Lond. A, 344, 259

    Google Scholar 

  153. Hou, K. C. and Palmer, H. B. (1965) J. Phys. Chem., 69, 863

    Google Scholar 

  154. Smith, R. D. and Johnson, A. L. (1983) Combust. Flame, 51, 1

    Google Scholar 

  155. Kern, R. D., Singh, H. J., Esslinger, M. A. and Winkeler, P. W. (1982) 19th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 1351

    Google Scholar 

  156. Swarc, O. M. (1948) J. Chem. Phys., 16, 128

    Google Scholar 

  157. Brade, A. T. and Steacie, E. W. R. (1954) Can. J. Chem., 32, 1142

    Google Scholar 

  158. Takeuchi, T., Sakaguchi, M. and Togashi, Y. (1966) Bull. Chem. Soc. Jpn., 39, 1437

    Google Scholar 

  159. Ebert, K. H., Ederer, H. J. and Schmidt, P. S. (1978) in Chemical Reaction Engineering - Houston (ACS Symp. Ser., No. 65), American Chemical Society, Washington DC, p. 313

    Google Scholar 

  160. Brooks, C. T., Peacock, S. J. and Reuben, B. G. (1982) J. Chem. Soc., Faraday Trans. I, 78, 3187

    Google Scholar 

  161. Palmer, H. B. and Cullis, C. F. (1965) in The Chemistry and Physics of Carbon, Vol. 1, Marcel Dekker, New York, p. 265

    Google Scholar 

  162. Gaydon, A. G. and Wolfhard, H. G. (1970) Flames, Their Structure, Radiation and Temperature, 3rd edn, Chapman and Hall, London, p. 175

    Google Scholar 

  163. Albright, L. F. et al. (1979) in Thermal Hydrocarbon Chemistry (ACS Adv. Chem. Ser., No. 183), American Chemical Society, Washington DC, p. 175

    Google Scholar 

  164. Albright, L. F., McConnell, C. F. and Welther, K. (1979) in Thermal Hydrocarbon Chemistry (ACS Adv. Chem. Ser., No. 183), American Chemical Society, Washington DC, p. 175

    Google Scholar 

  165. Albright, L. F. and Yu, Y.-H. C. (1979) in Thermal Hydrocarbon Chemistry (ACS Adv. Chem. Ser., No. 183) American Chemical Society, Washington DC, p. 193

    Google Scholar 

  166. Lahaye, J., Badie, P. and Ducret, J. (1977) Carbon, 15, 87

    Google Scholar 

  167. Tesner, P. A. (1979) Combust. Explos. Shock Waves, 15, 111

    Google Scholar 

  168. Arthur, J. R. and Napier, D. H. (1955) 5th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 303

    Google Scholar 

  169. Arthur, J. R., Commins, B. T., Gilbert, J. A. S., Lindsay, A. J. and Napier, D. H. (1958) Combust. Flame, 2, 267

    Google Scholar 

  170. Arthur, J. R., Kapur, P. K. and Napier, D. H. (1952) Nature, 169, 572

    Google Scholar 

  171. Dearden, P. and Long, R. (1968) Appl. Chem., 18, 243

    Google Scholar 

  172. Chakraborty, B. B. and Long, R. R. (1968) Combust. Flame, 12, 226, 237

    Google Scholar 

  173. Spengler, G. and Haupt, G. (1969) Erdoel Kohle, Erdgas, Petrochem., 22, 679

    Google Scholar 

  174. Wagner, H. Gg (1979) 17th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 3

    Google Scholar 

  175. Homann, K. H. and Wagner, H. Gg. (1968) Proc. R. Soc. Lond. A, 307, 141

    Google Scholar 

  176. Homann, K. H. (1972) in Proc. 4th Materials Research Symp., Gaithersburg MD, (NBS Spec. Publ. No. 357), US Govt Printing Office, Washington DC, p. 144

    Google Scholar 

  177. Homann, K. H. (1968) Angew. Chem., 1, 414

    Google Scholar 

  178. Schirmer, R. M. (1971) in Emissions from Continuous Combustion Systems (eds W. Cornelius and W. G. Agnew), Plenum Press, London

    Google Scholar 

  179. Friswell, N. J. (1979) Combust. Sci. Technol., 19, 119

    Google Scholar 

  180. Driscoll, J. F., Mann, D. M. and McGregor, W. K. (1979) Combust. Sci. Technol., 20, 41

    Google Scholar 

  181. Payne, K. G. and Weinberg, F. J. (1959) Proc. R. Soc. Lond. A, 250, 316

    Google Scholar 

  182. Place, E. R. and Weinberg, F. J. (1966) Proc. R. Soc. Lond. A, 289, 192

    Google Scholar 

  183. Tse, R. S., Michaud, P. and Delfau, J.-L. (1978) Nature, 272, 153

    Google Scholar 

  184. Delfau, J.-L., Michaud, P. and Barassin, A. (1979) Combust, Sci. Technol., 20, 165

    Google Scholar 

  185. Michaud, P., Delfau, J.-L. and Barassin, A. (1981) 18th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 443

    Google Scholar 

  186. Bowser, R. J. and Weinberg, F. J. (1976) Combust. Flame, 27, 21

    Google Scholar 

  187. Homann, K. H. (1979) Ber. Bunsenges. Phys. Chem., 83, 738

    Google Scholar 

  188. Prado, G. D. and Howard, J. B. (1978) in Evaporation and Combustion of Fuels (ACS Adv. Chem. Ser., No. 166) (ed. J. T. Zung), American Chemical Society, Washington DC, p. 153

    Google Scholar 

  189. Flossdorf, J., Jost, W. and Wagner, H. Gg. (1974) Ber. Bunsenges. Phys. Chem., 78, 378

    Google Scholar 

  190. Street, J. C. and Thomas, A. (1953) Fuel, London, 34, 4

    Google Scholar 

  191. Schug, K. P., Manheimer-Timnat, Y., Yaccarino, P. and Glassman, I. (1980) Combust. Sci. Technol., 22, 235

    Google Scholar 

  192. Magnussen, B. F. and Hjertager, B. H. (1975) 15th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 1415

    Google Scholar 

  193. Wright, F. J. (1969) 12th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 867

    Google Scholar 

  194. Blazowski, W. S. (1980) Combust. Sci. Technol., 21, 97

    Google Scholar 

  195. Gosling, A. J., Lampard, D. and Fussey, D. E. (1973) in Combustion Institute European Symposium (ed. F. J. Weinberg), Academic Press, London, p. 388

    Google Scholar 

  196. Fussey, D. E., Gosling, A. J. and Lampard, D. (1978) Combust. Flame, 32, 181

    Google Scholar 

  197. Jones, A. R. (1973) in Combustion Institute European Symposium (ed. F. J. Weinberg), Academic Press, London, p. 376

    Google Scholar 

  198. Millikan, R. G. (1962) J. Phys. Chem., 66, 794; (1961) J. Opt. Soc. Am., 51, 535, 698

    Google Scholar 

  199. MacFarlane, J. J., Holderness, F. H. and Whitcher, F. S. E. (1964) Combust. Flame, 8, 215

    Google Scholar 

  200. Redcliff, S. W. and Appleton, J. P. (1971) Combust. Sci. Technol., 3, 255

    Google Scholar 

  201. Calcote, H. F. and Olson, D. B. (1982) Combust. Sci. Technol., 28, 315

    Google Scholar 

  202. Bonne, U. and Wagner, H. Gg. (1965) Ber. Bunsenges. Phys. Chem., 69, 35

    Google Scholar 

  203. Smith, E. C. W. (1940) Proc. R. Soc. Lond. A, 174, 110

    Google Scholar 

  204. Flossdorf, J. (1968) Dissertation, Universitat Gottingen

    Google Scholar 

  205. Homann, K. H., Morgeneyer, W. and Wagner, H. Gg. (1973) Combustion Institute European Symposium (ed. F. J. Weinberg), Academic Press, London, p. 394

    Google Scholar 

  206. Haynes, B. S., Jander, H. and Wagner, H. Gg. (1980) Ber. Bunsenges. Phys. Chem., 84, 585

    Google Scholar 

  207. D’Allessio, A., Di Lorenzo, A., Sarofim, A. M., Beretta, F., Masi, S. and Venitozzi, C. (1975) 15th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 1427

    Google Scholar 

  208. D’Allessio, A., Di Lorenzo, A., Borghese, A., Beretta, F. and Masi, S. (1977) 16th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 695

    Google Scholar 

  209. Mie, G. (1908) Ann. Phys., Vierte Folge, 25, 377

    Google Scholar 

  210. Feugier, A. (1972) Combust. Flame, 19, 249

    Google Scholar 

  211. Kistiakowsky, G. B. and Michael, J. V. (1964) J. Chem. Phys., 40, 1447

    Google Scholar 

  212. Driscoll, J. F., Mann, D. M. and McGregor, W. K. (1979) Combust. Sci. Technol., 20, 41

    Google Scholar 

  213. Minchin, S. T. (1931) J. Inst. Petrol., 17, 102

    Google Scholar 

  214. Minchin, S. T. (1935) Proc. World Petrol. Congr., Vol. 2, p. 738

    Google Scholar 

  215. Clark, A. E., Hunter, T. C. and Garner, F. H. (1946) J. Inst. Petrol. Tech., 32, 627

    Google Scholar 

  216. Schalla, R. L. and McDonald, G. E. (1953) Ind. Eng. Chem., 45, 1497

    Google Scholar 

  217. Schalla, R. L. and McDonald, G. E. (1955) 5th Symp. (Int.) on Combustion, Reinhold, New York, p. 316

    Google Scholar 

  218. Tsygankova, E. I., Tesner, P. A., Gilyazetdinov, L. P. and Lezhnev, N. N. (1975) Russ. J. Phys. Chem., 49, 481

    Google Scholar 

  219. Magnussen, B. F. (1975) 15th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh

    Google Scholar 

  220. Prado, G. P., Lee, M. L., Hites, R. A., Hoult, D. P. and Howard, J. B. (1977) 16th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 649

    Google Scholar 

  221. Gollahalli, S. R. and Brznstowski, T. A. (1973) 14th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 1333

    Google Scholar 

  222. Coats, C. M. and Williams, A. (1979) 17th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 611

    Google Scholar 

  223. Graham, S. C., Homer, J. B. and Rosenfeld, J. L. (1975) Proc. R. Soc. Lond. A, 344, 259

    Google Scholar 

  224. Knorre, V. G., Kamenshchikova, V. I., Lyakhov, A. G. and Snagireva, D. T. (1980) Combust. Explos. Shock Waves, 16, 212

    Google Scholar 

  225. Lester, T. W. and Wittig, S. L. K. (1977) 16th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 671

    Google Scholar 

  226. Frenklach, M., Taki, S., Li Kwok Cheong, C. K. and Matula, R. A. (1983) Combust. Flame, 51, 37

    Google Scholar 

  227. Homann, K. H., Mochizuki, M. and Wagner, H. Gg. (1963) Z. Phys. Chem., 37, 299

    Google Scholar 

  228. Homann, K. H. and Wagner, H. Gg. (1965) Ber. Bunsenges. Phys. Chem., 69, 20

    Google Scholar 

  229. Homann, K. H. and Wagner, H. Gg. (1967) 11th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 371

    Google Scholar 

  230. Fenimore, C. P. and Jones, G. N. (1968) Combust. Flame, 12, 196

    Google Scholar 

  231. Long, R. and Tompkins, E. E. (1969) 12th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 625

    Google Scholar 

  232. Mayo, P. J. and Weinberg, F. J. (1970) Proc. R. Soc. Lond. A, 319, 351

    Google Scholar 

  233. Howard, J. B. (1969) 12th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 877

    Google Scholar 

  234. Miller, W. J. (1973) 14th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 307

    Google Scholar 

  235. Calcote, H. F. (1959) 8th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 184

    Google Scholar 

  236. Peeters, J. and Vinckier, C. (1975) 15th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 969

    Google Scholar 

  237. Klemm, R. F. and Blades, A. T. (1966) Nature, 212, 920

    Google Scholar 

  238. Zavitsanos, P. D. and Brewer, L. E. (1967) J. Chem. Phys., 47, 3093

    Google Scholar 

  239. Goodings, J. M., Bohme, D. K. and Sugden, T. M. (1977) 16th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 891

    Google Scholar 

  240. Goodings, J. M., Bohme, D. K. and Ng, C.-W. (1979) Combust. Flame, 36, 27

    Google Scholar 

  241. Goodings, J. M., Bohme, D. K. and Ng, C.-W. (1979) Combust. Flame, 36, 45

    Google Scholar 

  242. Gardner, M. P., Vinckier, C. and Bayes, K. D. (1975) Chem. Phys. Lett., 31, 318

    Google Scholar 

  243. Vinckier, C., Gardner, M. P. and Bayes, K. D. (1977) 16th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 881

    Google Scholar 

  244. Vinckier, C., Gardner, M. P. and Bayes, K. D. (1977) J. Phys. Chem., 81, 2137

    Google Scholar 

  245. Tanner, S. D., Goodings, J. M. and Bohme, D. K. (1981) Can. J. Chem., 59, 1760

    Google Scholar 

  246. Goodings, J. M., Tanner, S. D. and Bohme, D. K. (1982) Can. J. Chem., 60, 2766

    Google Scholar 

  247. Wersborg, B. L., Yeung, A. C. and Howard, J. B. (1975) 15th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 1439

    Google Scholar 

  248. Homann, K. H. (1979) Ber. Bunsenges. Phys. Chem., 83, 738

    Google Scholar 

  249. Michaud, P., Delfau, J.-L. and Barassin, A. (1981) 18th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 443

    Google Scholar 

  250. Delfau, J.-L., Michaud, P. and Barassin, A. (1979) Combust. Sci. Technol., 20, 165

    Google Scholar 

  251. Calcote, H. F. (1972) in Ion Molecule Reactions, Vol. 2, (ed. J. L. Franklin), Butterworths, London, p. 679

    Google Scholar 

  252. Howard, J. B. and Prado, G. P. (1980) Combust. Sci. Technol., 22, 189

    Google Scholar 

  253. Thomas, A. (1969) 12th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 886

    Google Scholar 

  254. Cullis, C. F. (1975) in Petroleum Derived Carbons (ACS Symp. Ser., No. 21) (eds M. L. Deviney and T. M. O’Grady), American Chemical Society, Washington DC, p. 348

    Google Scholar 

  255. Gaydon, A. G. and Fairbairn, A. R. (1955) 5th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 324.

    Google Scholar 

  256. Johnson, G. L. and Anderson, R. C. (1962) Proc. 5th Conf. on Carbon, Vol. I, Pergamon, London, p. 395

    Google Scholar 

  257. Tesner, P. A. (1960) Disc. Faraday Soc., 30, 170

    Google Scholar 

  258. Tesner, P. A., Snagiriova, T. D. and Knorre, V. G. (1971) Combust. Flame, 17, 253

    Google Scholar 

  259. Tesner, P. A. and Al’tshulcr, B. N. (1969) Dokl. Phys. Chem., 187, 555

    Google Scholar 

  260. Hudson, J. L. and Heicklen, J. (1968) Carbon, 6, 105

    Google Scholar 

  261. Cullis, C. F., Hucknall, D. J. and Shepherd, J. V. (1973) Proc. R. Soc. Lond. A, 335, 525

    Google Scholar 

  262. Laufer, A. H. and Bass, A. M. (1979) Phys. Chem., 83, 310

    Google Scholar 

  263. Lange, W. and Wagner, H. Gg. (1975) Ber. Bunsenges. Phys. Chem., 79, 165

    Google Scholar 

  264. Stein, S. E., Golden, D. M. and Benson, S. W. (1977) J. Phys. Chem., 81, 314

    Google Scholar 

  265. Stein, S. E. (1978) J. Phys. Chem., 82, 566

    Google Scholar 

  266. Calcote, H. F. (1981) Combust. Flame, 42, 215

    Google Scholar 

  267. Smyth, K. C., Lias, S. G. and Ausloos, P. (1982) Combust. Sci. Technol., 28, 147

    Google Scholar 

  268. Jensen, D. E. (1973) Combustion Institute European Symposium (ed. F. J. Weinberg), Academic Press, London, p. 382

    Google Scholar 

  269. Graham, S. C. (1977) 16th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 663

    Google Scholar 

  270. Graham, S. C. (1981) Proc. R. Soc. Lond. A, 377, 119

    Google Scholar 

  271. Harris, S. J. and Weiner, A. M. (1983) Combust. Sci. Technol., 31, 155

    Google Scholar 

  272. Cotton, D. H., Friswell, N. J. and Jenkins, D. R. (1971) Combust. Flame, 17, 87

    Google Scholar 

  273. Feugier, A. (1973) Combustion Institute European Symposium 1973 (ed. F. J. Weinberg), Academic Press, London, p. 406

    Google Scholar 

  274. Feugier, A. (1981) in Combustion in Reactive Systems (Prog, in Aeronautics and Astronautics, Vol. 76) (eds J. R. Bowen, N. Manson, A. K. Oppenheim and R. I. Solokhin) Am. Inst, of Aeronautics and Astronautics, New York, p. 178

    Google Scholar 

  275. Bulewicz, E. M., Evans, D. G. and Padley, P. J. (1975) 15th Symp. (Int.) on Combustion, Combustion Institute, Pittsburgh, p. 1461

    Google Scholar 

  276. Salooja, K. C. (1973) Combustion Institute European Symposium 1973 (ed. F. J. Weinberg) Academic Press, London, p. 400

    Google Scholar 

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Hucknall, D.J. (1985). Pyrolytic reactions of hydrocarbons. In: Chemistry of Hydrocarbon Combustion. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4852-5_6

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