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Binary SN Ring Systems and Related Heterocyclothiazenes

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Applied Quantum Chemistry

Abstract

A number of binary SN ring systems and heterocyclothiazenes have now been synthesized. The structure and properties of many of them appear to be well-characterized in terms of their π-electron systems. The occupancy of the π manifold can, however, be significantly different from their hydrocarbon analogues with profound implications for stability and reactivity. The further analysis of the π network in terms of fragments provides additional insight into formation and bonding. These features will be discussed in terms of the results of our “ab initio” Hartree-Fock-Slater calculations for orbital eigenvalues, overlap populations, charges, excitation energies and conformational energies for, among others, the systems S3N3 -, (H2P)S2N3, (H2P)2SN3 +, S4N2, S4N3 + and S4N4 2+.

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Author information

Authors and Affiliations

  1. Chemistry Department, University of Calgary, Calgary, Alberta, Canada, T2N 1N4

    W. G. Laidlaw

  2. Departamento de Química e Física Molecular, Instituto de Fisica e Quimica de São Carlos, Universidade de São Paulo, C.P. 369, São Carlos (SP), Brazil

    M. Trsic

Authors
  1. W. G. Laidlaw
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  2. M. Trsic
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Queen’s University, Kingston, Ontario, Canada

    Vedene H. Smith Jr.

  2. Department of Chemistry, University of California, Berkeley, California, USA

    Henry F. Schaefer III

  3. Institute for Molecular Science, Myodaiji, Okazaki, Japan

    Keiji Morokuma

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© 1986 D. Reidel Publishing Company, Dordrecht, Holland

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Laidlaw, W.G., Trsic, M. (1986). Binary SN Ring Systems and Related Heterocyclothiazenes. In: Smith, V.H., Schaefer, H.F., Morokuma, K. (eds) Applied Quantum Chemistry. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4746-7_18

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  • DOI: https://doi.org/10.1007/978-94-009-4746-7_18

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