Abstract
Ab initio molecular orbital calculations have been carried out to provide insight into the structural and mechanistic aspects of doubly bonded group 4B compounds. The effects of substituents on the structures, stability, and reactivity are especially emphasized.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
For recent comprehensive reviews, see: (a) Gusel′nikov, L. E.; Nametkin, N. S, Chem. Rev. 1979, 79, 529.
Coleman, B.; Jones, M. Rev. Chem. Intermed. 1981, 4, 297.
Bertrand, G.; Trinquier, G.; Mazerolles, P. J. Organomet. Chem. Library 1981. 12, 1.
Schaefer, H. F. Acc. Chem. Res. 1982, 15, 283.
Brook, A. G.; Abdesaken, F.; Gutekunst, B.; Gutekunst, G Kallury, R. K. J. Chem. Soc., Chem. Commun. 1981, 191.
Brook, A. G.; Nyburg, S. C.; Abdesaken, F.; Gutekunst, B.; Gutekunst, G.; Kallury, P. K. M. R.; Poon, Y. C.; Chang, Y. -M.; Wong-Ng, W. J. Am. Chem. Soc. 1982, 104, 5667.
West, R.; Fink, M. J.; Michl, J. Science (Washington, D.C.) 1981, 214, 1343.
For a currest review, see: West, R. Science (Washington, D.C.) 1984, 225, 1109.
Hanamura, M.; Nagase, S.; Morokuma, K. Tetrahedron Lett. 1981, 22, 1813.
Olbrich, G.; Potzinger, P.; Reimann, B.; Walsh, R. Organometallics 1984, 3, 1267
Snyder, L. C.; Wasserman, Z. R. J. Am. Chem. Soc. 1979, 101, 5222.
Poirier, R. A.; Goddard, J. D. Chem. Phys. Lett. 1981, 80, 37.
Krogh-Jespersen, K. J. Phys. Chem. 1982, 86, 1495.
Lischka, H.; Kohler, H. -J. Chem. Phys. Lett. 1982, 85, 467
J. Am. Chem. Soc. 1982, 104, 5889.
Trinquier, G.; Malrieu, J. -P.; Riviere, P. J. Am. Chem. Soc. 1982, 104, 4529.
Nagase, S.; Kudo, T. J. Mol. Struct., THEOCHEM 1983, 103, 35.
Nagase, S.; Kudo, T. Organometallics 1984, 3, 1320.
Nagase, S.; Kudo, T. unpublished results.
Fink, M. J.; Michalczyk, M. J.; Haller, K. J.; West, R.; Michl, J. Organometallics 1984, 3, 793.
Masamune, S.; Murakami, S.; Snow, J. T.; Tobita, H.; Williams, D. J. Organometallics 1984, 3, 333.
Gordon, M. S. Chem. Phys. Lett. 1978, 54, 9.
Goddard, J. D.; Yoshioka, Y.; Schaefer, H. F. J. Am. Chem. Soc. 1980, 102, 7644.
Yoshioka, Y.; Schaefer, H. F. J. Am. Chem. Soc. 1981, 103, 7366.
Trinquier, G7T~Malrieu, J. -P. J. Am. Chem. Soc. 1981, 103, 6313.
Köhler, H. J.; Lischka, H. J. Am. Chem. Soc. 1982, 104, 5884.
Kudo, T.; Nagase, S. J. Organomet. Chem. 1983, 253, C23.
Kudo, T.; Nagase, S. J. Phys. Chem. 1984, 88, 2833.
Kudo, T.; Nagase, S. Chem. Phys. Lett. 1981, 84, 375.
Trinquier, G.; Barthelat, J. -C.; Satge, J. J. Am. Chem. Soc. 1982, 104, 5931.
Trinquier, G.; Pelissier, M.; Saint-Roch, B.; Lavayssiere, H. J. Organomet. Chem. 1981, 214, 169.
Gordon, M. S. J. Chem. Soc. 1982, 104, 4352.
Conlin, R. T.; Wood, D. L. J. Am. Chem. Soc. 1981, 103, 1843.
Drahnak, T. J.; Michl, J.; West, R. J. Am. Chem. Soc. 1981, 103, 1845.
See also: Reisenauer, H. P.; Mihm, G.; Maier, G. Angew. Chem. Int. Ed. Engl. 1982, 21, 854.
Arrington, C. A.; West, R.; Michl, J. J. Am. Chem. Soc. 1983, 105, 6176.
Walsh, R. J. Chem. Soc., Chem. Commun. 1982, 1415
Conlin, R. T.; Gill, R. S. J. Am. Chem. Soc. 1983, 105, 618.
Conlin, R. T.; Kwak, Y. -W. Organometallics 1984, 3, 918.
Pau, C. F.; Pietro, W. J.; Hehre, W. J. J. Am. Chem. Soc. 1983, 105, 16.
Nagase, S.; Kudo, T. J. Chem. Soc., Chem. Commun. 1984, 141.
Nagase, S.; Kudo, T. J. Chem. Soc., Chem. Commun. 1984, 1392.
Nagase, S.; Kudo, T. Organometallies 1984, 3, 324.
Barton, T. J.; Jacobi, S. A. J. Am. Chem. Soc. 1980, 102, 7979.
Barton, T. J.; Burns, S. A.; Burns, G. T. Organometallics 1982, 1, 210.
Sekiguchi, A.; Ando, W. Tetrahedron Lett. 1983, 24, 2791.
Sakurai, H.; Nakadaira, Y.; Sakaba, H. Organometallies 1983, 2, 1484.
Sakurai, H.; Sakaba, H.; Nakadaira, Y. J. Am. Chem. Soc. 1982, 104, 6158.
Wulff, W. D.; Goure, W. F.; Barton, T. J. J. Am. Chem. Soc. 1978, 100, 6236.
Kudo, T.: Nagase, S. J. Am. Chem. Soc. submitted for publication.
Nagase, S.; Kudo, T. J. Chem. Soc., Chem. Commun. 1983, 363.
Nagase, S.; Kudo, T. to be published.
Wiberg, N. J. Organomet. Chem. 1984, 273, 141.
Kudo, T.; Nagase, S. J. Am. Chem. Soc. 1985, 89, 0000.
Nagase, S.; Kudo, T. to be published.
Davidson, I. M. T.; Dean, C. E.; Lawrence, F. T. J. Chem. Soc., Chem. Commun. 1981, 52.
For the validity for preventing dimerization, see: Morokuma, K. IMS Ann. Rev. 1984, 13.
De Young, D. J.; M. J.; West, R. Organometallics, in press (private communication from Prof. West)
Yoshifuji, M.; Shima, I.; Inamoto, N.; Hirotsu, K.; Higuchi, T. J. Am. Chem. Soc. 1981, 103, 4587.
For a current review, see: Cowley, A. H. Acc Chem. Res. 1984, 17, 386.
Ito, K.; Nagase, S. to be published.
Morokuma, K.; Kato, S.; Kitaura, K.; Ohmine, I.; Sakai, S.; Obara, S. IMS library program (WF10-8), 1980.
An IMS version (WF10-24) of the GAUSSIAN80 series of programs by: Binkley, J. S.; Whiteside, R. A.; Krishnan, R.; Seeger, R.; DeFrees, D. J.; Schlegel, H. B.; Topiol, S.; Kahn, L. R.; Pople, J. A. QCPE 1981, 10, 406.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1986 D. Reidel Publishing Company, Dordrecht, Holland
About this paper
Cite this paper
Nagase, S., Kudo, T., Ito, K. (1986). Structures, Stability, and Reactivity of Doubly Bonded Compounds Containing Silicon or Germanium. In: Smith, V.H., Schaefer, H.F., Morokuma, K. (eds) Applied Quantum Chemistry. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4746-7_17
Download citation
DOI: https://doi.org/10.1007/978-94-009-4746-7_17
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8609-7
Online ISBN: 978-94-009-4746-7
eBook Packages: Springer Book Archive