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The Capacity of the Metal/Liquid Electrolyte Interphase: Contribution of the Metal

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Trends in Interfacial Electrochemistry

Part of the book series: NATO ASI Series ((ASIC,volume 179))

Abstract

The jellium model for metals is reviewed. The polarizability of the electronic plasma in the surface region increases the double layer capacity. The model is complemented by a model for the electrolyte solution, which is represented as an ensemble of hard sphere ions and dipoles. The relation of the model to experimental data, and possible extensions, are discussed.

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Author information

Authors and Affiliations

  1. Institut für physikalische Chemie der Universität Düsseldorf, D 4000, Düsseldorf, Germany

    Wolfgang Schmickler

Authors
  1. Wolfgang Schmickler
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Faculty of Sciences, University of Porto, Porto, Portugal

    A. Fernando Silva

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© 1986 D. Reidel Publishing Company, Dordrecht, Holland

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Schmickler, W. (1986). The Capacity of the Metal/Liquid Electrolyte Interphase: Contribution of the Metal. In: Silva, A.F. (eds) Trends in Interfacial Electrochemistry. NATO ASI Series, vol 179. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4694-1_16

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  • DOI: https://doi.org/10.1007/978-94-009-4694-1_16

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8587-8

  • Online ISBN: 978-94-009-4694-1

  • eBook Packages: Springer Book Archive

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