Skip to main content

Electronic Spectroscopy of Semiconductor Clusters

  • Chapter
Homogeneous and Heterogeneous Photocatalysis

Part of the book series: NATO ASI Series ((ASIC,volume 174))

  • 548 Accesses

Abstract

Semiconductor clusters (crystallites) of 20–30Å diameter are synthesized and stabilized using liquid phase arrested precipitation reactions. Their electronic states are characterized via in situ absorption and luminescence spectroscopy. The clusters, although crystalline, are too small to have the bulk semiconductor band gap. The physical nature of their electronic states is discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J. Jortner, Ber. Bungenges Phys. Chem. 88, 188 (1984).

    Google Scholar 

  2. R. L. Whetten, D. M. Cox, D. J. Trevor, and A. Kaldor Phys. Rev. Lett. 54, 1494 (1985).

    Article  CAS  Google Scholar 

  3. D. E. Powers et al., J. Phys. Chem. 86, 2556 (1982).

    Article  CAS  Google Scholar 

  4. V. E. Bondybey and J. H. English, J. Chem. Phys. 76, 2165 (1982).

    Article  CAS  Google Scholar 

  5. R. Rossetti and L. Brus, J. Phys. Chem. 86, 4470 (1982).

    Article  CAS  Google Scholar 

  6. R. Rossetti, S. Nakahara, and L. E. Brus, J. Chem. Phys. 79, 1086 (1983).

    Article  CAS  Google Scholar 

  7. L. E. Brus, J. Chem. Phys. 80, 4403 (1984).

    Article  CAS  Google Scholar 

  8. R. Rossetti, J. L. Ellison, J. M. Gibson, and L. E. Brus J. Chem. Phys. 80, 4464 (1984).

    Article  CAS  Google Scholar 

  9. R. Rossetti, R. Hull, J. M. Gibson and L. E. Brus, J. Chem. Phys. 82, 552 (1985).

    Article  CAS  Google Scholar 

  10. R. Rossetti, R. Hull, J. M. Gibson, and L. E. Brus, “Hybrid Electronic Properties Between the Molecular and Solid State Limits: Lead Sulfide and Silver Halide Crystallites,” J. Chem. Phys. (August 1985).

    Google Scholar 

  11. A. Henglein, Ber. Bungenges Phys. Chem. 86, 301 (1982).

    CAS  Google Scholar 

  12. A. Fojtik, H. Weller, U. Koch and A. Henglein, Ber. Bungenges Phys. Chem. 88, 969 (1984).

    CAS  Google Scholar 

  13. J. J. Ramsden and M. Grätzel, J. Chem. Soc. Faraday Trans. I, 80, 919 (1984).

    Article  CAS  Google Scholar 

  14. A. J. Nozik, F. Williams, M. T. Nenadovic, T. Rajh, and O. I. Micic J. Phys. Chem. 89, 397 (1985).

    Article  Google Scholar 

  15. T. Harris and L. E. Brus, unpublished data.

    Google Scholar 

  16. D. G. Thomas, J. J. Hopfield and W. M. Augustyniak, Phys. Rev. 140A, 202 (1965).

    Article  Google Scholar 

  17. K. Era, S. Shionoya, Y. Washizawa, and H. Ohmatsu J. Phys. Chem. Solids 29, 1843 (1968).

    Google Scholar 

  18. K. Era, S. Shionoya, and Y. Washizawa, J. Phys. Chem. Solids 41, 1827 (1968).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1986 D. Reidel Publishing Company

About this chapter

Cite this chapter

Brus, L. (1986). Electronic Spectroscopy of Semiconductor Clusters. In: Pelizzetti, E., Serpone, N. (eds) Homogeneous and Heterogeneous Photocatalysis. NATO ASI Series, vol 174. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4642-2_5

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-4642-2_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-277-2221-8

  • Online ISBN: 978-94-009-4642-2

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics