Abstract
We review the approximate relationships between Raman intensities and derivatives of the dynamic dipole polarizabilities. Calculations on N2, CO, HCl and Cl2 show that the approximations made when Raman intensities are expressed in terms of polarizability derivatives may lead to as much as a 10% error (HCl). However, this error is in most cases rather small compared with the error that is introduced if static rather than dynamic polarizabilities are used.
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© 1986 D. Reidel Publishing Company
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Jäpelt, A., Svendsen, E.N., Oddershede, J. (1986). Relationship Between Raman Intensities and Derivatives of the Dipole Polarizability. In: Jørgensen, P., Simons, J. (eds) Geometrical Derivatives of Energy Surfaces and Molecular Properties. NATO ASI Series, vol 166. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4584-5_22
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DOI: https://doi.org/10.1007/978-94-009-4584-5_22
Publisher Name: Springer, Dordrecht
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