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Integration of Fundamental Polymer Science and Technology pp 198–203Cite as

Photopolymerization of Diacrylates

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Synopsis

Experiments show that during the bulk polymerization of diacrylates at room temperature (i) the volume shrinkage cannot keep up with the chemical conversion; this explains the light intensity dependence of ultimate conversion; (ii) inhomogeneity persists far beyond the gel point; (iii) pendant double bonds initially show an enhanced reactivity due to local concentration effects; (iv) the size of domains of crystallizable monomer decreases strongly with increasing crosslink density.

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References

  1. Broer, D.J., Lippits, G.J.M., and Zwiers, R.J.M., posters presented at this meeting.

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Author information

Authors and Affiliations

  1. Philips Research Labs., P.O.Box 80 000, 5600 JA, Eindhoven, The Netherlands

    G. M. M. Van de Hei, G. F. C. M. Lijten & G. F. C. M. Lijten

Authors
  1. J. G. Kloosterboer
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  2. G. M. M. Van de Hei
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  3. G. F. C. M. Lijten
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Editor information

Editors and Affiliations

  1. DSM Central Research, Geleen, The Netherlands

    L. A. Kleintjens

  2. Eindhoven University of Technology, The Netherlands

    P. J. Lemstra

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© 1986 Elsevier Applied Science Publishers Ltd

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Kloosterboer, J.G., Van de Hei, G.M.M., Lijten, G.F.C.M. (1986). Photopolymerization of Diacrylates. In: Kleintjens, L.A., Lemstra, P.J. (eds) Integration of Fundamental Polymer Science and Technology. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4185-4_25

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  • DOI: https://doi.org/10.1007/978-94-009-4185-4_25

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8359-1

  • Online ISBN: 978-94-009-4185-4

  • eBook Packages: Springer Book Archive

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