Skip to main content

Part of the book series: Developments in Hydrobiology ((DIHY,volume 39))

Abstract

This review article covers the processes affecting trace metals in deposited sediments. The sediment-water system can be divided in three parts: the oxic layer, the anoxic layer and the oxic-anoxic interface. Available data show that trace metals like Cu, Zn and Cd occur as sulphides in marine and estuarine anoxic sediments. Calculations show that organic complexation is unlikely and the dominant species are sulphide and bisulphide complexes. Chromium and arsenic are probably present as adsorbed species on the sediments; their concentrations in the pore waters, therefore depend on the concentrations in the sediments. The oxic-anoxic interface plays the major role in the potential flux of trace metals from the sediments, however this interface is not well studied at present. Changes from an anoxic to an oxic environment as occurs during dredging and land disposal of contaminanted sediments may cause a remobilization of some trace metals.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 74.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Abdullah, M. I. B. Reusch-Berg, 1981. Metal species in sediments and interstitial waters. Proceedings of the International Conference on Heavy Metals in the Environment. Amsterdam, CEP Consultants Ltd., Edinburgh, pp. 669–673.

    Google Scholar 

  • Avnimelech, Y., J. R. McHenry J. D. Ross, 1983. Decomposition of organic matter in lake sediments. Environ. Sci. Technol. 18: 5–11.

    Article  Google Scholar 

  • Baccini, P. T. Joller, 1981. Transport processes of copper and zinc in a high eutrophic and meromictic lake. Schweiz Z. Hydrol. 43: 176–199.

    CAS  Google Scholar 

  • Balistrieri, L. S. J. W. Murray, 1983. Metal-solid interactions in the marine environment: estimating apparent equilibrium constants. Geochim. Cosmochim. Acta 47: 1091–1098.

    Article  CAS  Google Scholar 

  • Batley, G. E. M. S. Giles, 1980. A solvent displacement technique for the separation of sediment interstitial waters. In Contaminants and sedments. R. A. Baker (ed.), Ann Arbor Sci. Publ., Ann Arbor, Michigan, pp. 101–117.

    Google Scholar 

  • Berner, R. A., 1981. A new geochemical classification of sedimentary environment. J. Sediment Petrol. 51: 359–365.

    CAS  Google Scholar 

  • Boulegue, J., C. J. Lord T. M. Church, 1982. Sulphur speciation and associated trace metals (Fe, Cu) in the pore waters of Great Marsh, Delaware. Geochim. Cosmochim. Acta 46: 453–464.

    Article  CAS  Google Scholar 

  • Bourg, C. A. M., 1983. Role of fresh water/sea water mixing on trace metal adsorption phenomena. In Trace metals in sea water. C. S. Wong, E. Boyle, K. W. Bruland, J. D. Burton E. D. Goldberg (eds.), Plenum Publ., N.Y., pp. 195–208.

    Google Scholar 

  • Boyle, E. A., S. S. Huested S. P. Jones, 1981. On the distribution of copper, nickel and cadmium in surface waters of the North Atlantic and North Pacific Ocean. J. Geophys. Res. 89: 8048–8066.

    Article  Google Scholar 

  • Bruland, K. W. & R. P. Franks, 1983. Mn, Ni, Zn and Cd in the Western Atlantic. In Trace Metals in Seawater. C. S. Wong, E. Boyle, K. W. Bruland, J. D. Burton E. D. Goldberg (eds.), Plenum, N.Y. pp. 395–414.

    Google Scholar 

  • De Kock, W. C., 1983. Accumulation of cadmium and PCB by Mytilus edulis L., transplanted from pristine water into pollution. Can. J. Fish aquat. Sci. 40: 282–294.

    Article  Google Scholar 

  • Duinker, J. C. R. F. Nolting, 1977. Dissolved copper, zinc and cadmium in the Southern Bight of the North Sea. Mar. Poll. Bull. 8: 68–71.

    Google Scholar 

  • Emerson, S. G. Widmer, 1978. Early diagenesis in anaerobic lake sediments II. Thermodynamic and kinetic factors controlling the formation of iron phosphate. Geochim. Cosmochim. Acta 42: 1307–1316.

    Article  CAS  Google Scholar 

  • Emerson, S., L. Jacobs B. Tebo, 1983. The behavior of trace metals in anoxic water: solubilities at the oxygen-hydrogen sulphide interface. In Trace metals in sea water. C. S. Wong, E. Boyle, K. W. Bruland, J. D. Burton E. D. Goldberg (eds.), Plenum Publ., N.Y. pp. 579–608.

    Google Scholar 

  • Emerson, S., S. Kaihorn, L. Jacobs, B. M. Tebo, K. H. Nealson R. A. Rosson, 1982. Environmental oxidation rate of manganese (II) bacterial catalysis. Geochim. Cosmochim. Acta 46: 1073–1079.

    Article  CAS  Google Scholar 

  • Förstner, U. W. Salomons, 1982. Trace element speciation in surface waters: interaction with particulate matter. In Trace elements speciation in surface waters and its ecological implications. G. G. Leppard (ed.), Plenum Publ., N.Y. pp. 245–273.

    Google Scholar 

  • Gardner, L. R., 1974. Chemical models for sulphate reduction in closed anaerobic marine environments. Geochim. Cosmochim. Acta 38: 1297–1302.

    Article  CAS  Google Scholar 

  • Hallberg, R. O., 1978. Metal-organic interaction at the redoxcline. In Environmental Geochemistry and Microbiology. W. E. Krumbein (ed.), Ann Arbor Sei Publ., Ann Arbor, Michigan, pp. 947–953.

    Google Scholar 

  • Hunt, C. D.& D. L. Smith, 1983. Remobilization of metals from polluted marine sediments. Can. J. Fish aquat. Sci. 40: 132–142.

    Article  Google Scholar 

  • Jacobs, L. S. Emerson, 1982. Trace metal solubility in an anoxic fjord. Earth Planet Sci. Lett. 60: 237–252.

    Google Scholar 

  • Jones, J. G., 1982. Activities of aerobic and anaerobic bacteria in lake sediments and their effect on the water column. In Sediment microbiology. D. B. Nedwell C. M. Brown (eds.), Academic Press, London, pp. 107–145.

    Google Scholar 

  • Kerdijk, H. W. Salomons, 1985. Influence of NTA on adsorption processes in river systems ( in preparation).

    Google Scholar 

  • Kremling, K., 1983a. The behavior of Zn, Cd, Cu, Ni, Co, Fe and Mn in anoxic Baltic Waters. Mar. Chem. 13: 87–108.

    Article  CAS  Google Scholar 

  • Kremling, K., 1983b. Trace metal fronts in European shelf waters. Nature (London) 303: 225–227.

    Article  CAS  Google Scholar 

  • Lee, F. Y. &J. A. Kittrick, 1984a. Elements associated with the cadmium phase in a harbor sediment as determined with the electron beam microprobe. J. environ. Qual. 13: 337–340.

    Article  CAS  Google Scholar 

  • Lee, F. Y. &J. A. Kittrick, 1984b. Electron microprobe analysis of elements associated with zinc and copper in an oxidizing and an anaerobic soil environment. J. environ. Qual. 48: 548–554.

    CAS  Google Scholar 

  • Lu, J. C. S.& K. Y. Chen, 1977. Migration of trace metals in interfaces of sea water and polluted surficial sediments. Environ. Sei. Technol. 11: 174–181.

    Article  CAS  Google Scholar 

  • Luther, G. W., A. L. Meyerson, J. J. Krajewski & R. Hires, 1980. Metal sulphides in estuarine sediments. J. Sediment Petrol. 50: 1117–1120.

    CAS  Google Scholar 

  • Lyons, W. B., K. M. Wilson, P. B. Armstrong, G. M. Smith H. E. Gaudette, 1980. Trace metal pore water geochemistry of nearshore Bermuda carbonate sediments. Oceanol. Acta 3: 363–366.

    CAS  Google Scholar 

  • Martin, J. H., G. A. Knauer R. M. Gordon, 1983. Silver dis-tributions and fluxes in north-east Pacific waters. Nature (London) 305: 306–309.

    Article  CAS  Google Scholar 

  • Moffett, J. W.& R. G. Zika, 1983. Oxidation kinetics of Cu(I) in seawater: implications for its existence in the marine en-vironment. Mar. Chem. 13: 239–251.

    Article  CAS  Google Scholar 

  • Odum, E. P., 1984. The Mesocosm. Bioscience 34: 558–562.

    Article  Google Scholar 

  • Perry, R., P. W. W. Kirk, T. Stephenson & J. N. Lester, 1984. Environmental aspects of the use of NTA as a detergent builder. Water Res. 18: 255–276.

    Article  CAS  Google Scholar 

  • Reuther, R., R. F. Wright & U. Förstner, 1981. Distribution and chemical forms of heavy metals in sediment cores from two Norwegian lakes affected by acid precipitation. In Proceedings of the International Conference on Heavy Metals in the Environment. Amsterdam, CEP Consultants Ltd., Edinburgh, pp. 318–312.

    Google Scholar 

  • Salomons, W. & U. Förstner, 1980. Trace metal analysis on pol-luted sediments. II. Evaluation of environmental impact. Env. Technol. Lett. 1: 506–517.

    Article  CAS  Google Scholar 

  • Salomons, W.& W. Eysink, 1981. Pathways of mud and particulate trace metals from rivers to the Southern North Sea. In Holocene Marine Sedimentation in the North Sea Basin. S. D. Nio, R. T. E. Schuettenhelm T. C. W. E. van Weering (eds.), Spec. Publ. Int. Assoc. Sediment 5: 429–450.

    Google Scholar 

  • Salomons, W. &R. A. Gerritse, 1981. Some observations on the occurrence of phosphorus in sediments from Western Europe. Science Tot. Environ. 17: 34–49.

    Google Scholar 

  • Salomons, W.& H. Kerdijk, 1983. Metal cycling in Lakes. In Proceedings of the International Conference on Heavy Metals in the Environment. Heidelberg, CEP Consultants Ltd., Edinburgh, pp. 880–883.

    Google Scholar 

  • Salomons, W.& U. Förstner, 1984. Metals in the Hydrocycle. Springer-Verlag, Berlin, Heidelberg, New York. 349 pp.

    Google Scholar 

  • Salomons, W.& P. Baccini. 1985. Chemical Speciation and metal transport in lakes. Dahlem Konferenzen: The Importance of Chemical Speciation in Environmental Processes. Springer Verlag. Berlin, Heidelberg, New York.(in press).

    Google Scholar 

  • Salomons, W., W. van Driel, H. Kerdijk & R. Boxma, 1982. Help! Holland is plated by the Rhine. In Effects of waste disposal on groundwater. Proc. Exeter. Symp. IAHS 139: 255–269.

    Google Scholar 

  • Santschi, P., 1985. The MERL mosocosm approach for studying sediment-water interactions and ecotoxicology. Env. Technol. Lett. (in press).

    Google Scholar 

  • Skei, J., 1983. Geochemical and sedimentological considerations of a permanently anoxic fjord-Framvaren, South Norway. Sediment. Geol. 36: 131–145.

    Article  CAS  Google Scholar 

  • Spencer, D. W. &P. G. Brewer, 1971. Vertical advection diffu¬sion and redox potentials as controls on the distribution of manganese and other trace metals dissolved in waters of the Black Sea. J. Geophys. Res. 76: 5877–5892.

    Article  CAS  Google Scholar 

  • Spencer, D. W., P. G. Brewer P. L. Sachs, 1972. Aspects of the distribution and trace elements composition of suspended matter in the Black Sea. Geochim. Cosmochim. Acta 36: 71–86.

    Article  CAS  Google Scholar 

  • Schwarzenbach, G., 1961. The general, selective and specific formation of complexes by metal cations. In Advances in Inorganic Radiochemistry, Vol. 3. H. J. Emelens A. G. Sharpe (eds.), Academic Press, New York, pp. 265.

    Google Scholar 

  • Stumm, W. & P. Baccini, 1978. Man-made perturbation of lakes. In Lakes-chemistry, geology and physics. A. Lerman (ed.), Springer-Verlag, Berlin, Heidelberg, New York. pp. 91–126.

    Google Scholar 

  • Van den Berg, C. M. G. & S. Dharmvanij, 1984. Organic complexation of zinc in estuarine interstitial and surface water samples. Limnol. Oceanogr. 29: 1025–1036.

    Article  Google Scholar 

  • Windom, H., G. Wallace, R. Smith, N. Maeda, R. Dulmage R. Storti, 1983. Behavior of copper in southeastern United States estuaries. Mar. Chem. 12: 183–193.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1987 Dr W. Junk Publishers, Dordrecht

About this paper

Cite this paper

Salomons, W., de Rooij, N.M., Kerdijk, H., Bril, J. (1987). Sediments as a source for contaminants?. In: Thomas, R.L., Evans, R., Hamilton, A.L., Munawar, M., Reynoldson, T.B., Sadar, M.H. (eds) Ecological Effects of In Situ Sediment Contaminants. Developments in Hydrobiology, vol 39. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-4053-6_3

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-4053-6_3

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8299-0

  • Online ISBN: 978-94-009-4053-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics