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HNO2, NO2 and NO Measurements in Automobile Engine Exhaust by Optical Absorption

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Monitoring of Gaseous Pollutants by Tunable Diode Lasers

Part of the book series: Air Pollution Research Reports ((APRR))

Summary

Exhaust gases of automobile engines (Diesel- and spark ignition types) were analyzed for nitrogen compounds (NO, NO2, HNO2, and CH3 ONO), SO2 and CH2O by differential optical absorption spectroscopy (DOAS). Detection limits of the technique ranged from 0.1 to 2.2ppm at absorption path lengths of 0.15 to 1.5m. Maximum HNO2 concentrations were reached at medium load operations and ranged from 0.15% to 3% of total NOX emitted for spark ignition and Diesel- engines, respectively.

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References

  1. Fahmy, O.G. arid M.J. Fahray (1976). Mutagenicity of N-a-Acetoxyethyl-N-ethylnitrosamine and N, N-Diethylnitrosamine in relation to the mechanism of metabolic activation of dialkylnitrosamines. Cancer Res., 36, 4504–4512

    CAS  Google Scholar 

  2. Perner, D. and U. Piatt (1979). Detection of nitrous acid in the atmosphere by differential optical absorption. Geophys. Res. Lett., 6, 917–920.

    Article  CAS  Google Scholar 

  3. Piatt, U., D. Perner, G.W. Harris, A.M. Winer and J.N. Pitts, Jr. (1980). Observations of nitrous acid in an urban atmosphere by differential optical absorption. Nature, 285, 312–314.

    Article  Google Scholar 

  4. Harris, G.W., W.P.L. Carter, A.M. Winer, J.N. Pitts, Jr., U. Piatt and D. Perner (1982). Observations of nitrous acid in the Los Angeles atmosphere and implications for the predictions of ozone-precursor relationships. Environm. Sci. Techn., 16, 414–419.

    Article  CAS  Google Scholar 

  5. Kessler, C. and U, Piatt (1984). Nitrous acid in polluted air masses - sources and formation pathways. Physico-Chernical Behaviour of Atmospheric Pollutants, Proc. 3rd Europ. Symp., Varese, Italy, B. Versino and G. Angeletti (eds.), Reidel, 412–422.

    Google Scholar 

  6. Sjoedin A. and M. Perm (1985). Measurement of nitrous acid in an urban area. Atmos. Environm., 19, 985 - 992.

    Article  CAS  Google Scholar 

  7. Hilliard, J.C. and R.W. Wheeler (1979). Nitrogen dioxide in engine exhaust. Paper 790691, SAE, Warrendale, Pennsylvania, USA.

    Book  Google Scholar 

  8. Pitts, J.N,, H. Biermann, A.M. Winer, and E.G. Tuazon (1984). Spectroscopic identification and measurement of gaseous nitrous acid in dilute auto exhaust. Atmos. Environm., 18, 847–854.

    Article  Google Scholar 

  9. Piatt, U. and D. Perner (1983). Measurements of atmospheric trace gases by long path differential UV/visible absorption spectroscopy. Optical and Laser Remote Sensing, D.K. Killinger and A. Mooradian ( Eds. ), Springer Ser. Opt. Sci., 39, 95–105.

    Google Scholar 

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© 1987 ECSC, EEC, EAEC, Brussels and Luxembourg

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Perner, D., Kessler, C., Platt, U. (1987). HNO2, NO2 and NO Measurements in Automobile Engine Exhaust by Optical Absorption. In: Grisar, R., Preier, H., Schmidtke, G., Restelli, G. (eds) Monitoring of Gaseous Pollutants by Tunable Diode Lasers. Air Pollution Research Reports. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3991-2_17

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  • DOI: https://doi.org/10.1007/978-94-009-3991-2_17

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8271-6

  • Online ISBN: 978-94-009-3991-2

  • eBook Packages: Springer Book Archive

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