Abstract
Recent advances in transition metal initiated polymerization of conjugated dienes are discussed, with emphasis on results obtained using simple η3-allyl nickel complexes that are good models for Ziegler-Natta type catalysts. Besides a brief reassessment of the mechanism, three types of data will be envisioned, that have not been completely clarified or implemented as yet : 1) The possibility to master a “living” coordination polymerization of butadiene, and to use it for the synthesis of new (stereo)block copolymers; 2) The control of a highly regioselective 1.4 polymerization, with a stereoselectivity ranging from very pure cis to very pure trans, and depending not only on temperature and complex ligand field but also unexpectedly on initiator concentration; 3) The existence of a dynamic situation allowing to “code” the distribution of the cis and trans isomeric units in chains of equibinary composition, from a purely random placement to a highly stereoblock one with interesting bulk properties. As far as possible, these data will be related to those obtained with Ziegler-Natta systems.
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Teyssie, P., Hadjiandreou, P., Julemont, M., Warin, R. (1987). Pending Questions in Coordination Polymerization of Diolefins. In: Fontanille, M., Guyot, A. (eds) Recent Advances in Mechanistic and Synthetic Aspects of Polymerization. NATO ASI Series, vol 215. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3989-9_42
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DOI: https://doi.org/10.1007/978-94-009-3989-9_42
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