Abstract
A detailed kinetic study on electron transfer quenching of Ru(bpy) 2+*3 and Ru(phen)2(CN) *2 by organic donors and acceptors with special reference to apparent negative temperature dependence led to the conclusion that the excited encounter complex and the ion pair produced by electron transfer were in equilibrium depending on the overall thermodynamic change. Difference in electrostatic interaction before and after electron transfer is an important factor governing the participation of back electron transfer processes. It was shown with examples that this type of electron transfer mechanism was common for many other systems.
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© 1987 D. Reidel Publishing Company
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Tazuke, S., Kitamura, N., Kim, HB. (1987). Photoinduced Looping Electron Transfer. What Occurs Between Electron Transfer and Charge Separation ?. In: Balzani, V. (eds) Supramolecular Photochemistry. NATO ASI Series, vol 214. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3979-0_6
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DOI: https://doi.org/10.1007/978-94-009-3979-0_6
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