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Vibration-Rotation Spectroscopy of ArHCI by Far-Infrared Laser and Microwave/Far-Infrared Laser Double Resonance Spectroscopy

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Structure and Dynamics of Weakly Bound Molecular Complexes

Part of the book series: NATO ASI Series ((ASIC,volume 212))

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Abstract

Direct absorption by the low frequency van der Waals vibrations in ArHCI has been observed using the technique of intracavity far infrared laser spectroscopy and more recently with microwave far-infrared double resonance. Constants are reported for the π bending state of ArH37 CI. These constants favor, though not conclusively, a potential surface with a double minimum. Further work on other vibrational bands of ArHCI using double resonance methods will elucidate the nature of the surface directly.

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References

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Author information

Authors and Affiliations

  1. Department of Chemistry and Materials and Molecular Research Division, University of California and Lawrence Berkeley Laboratories, Berkeley, CA, 94720, USA

    Ruth L. Robinson, Douglas Ray, Dz.-Hung Gwo & Richard J. Saykally

Authors
  1. Ruth L. Robinson
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  2. Douglas Ray
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  3. Dz.-Hung Gwo
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  4. Richard J. Saykally
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Editor information

Editors and Affiliations

  1. Molecular Spectroscopy Division, National Bureau of Standards, Gaithersburg, Maryland, USA

    Alfons Weber

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© 1987 D. Reidel Publishing Company

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Robinson, R.L., Ray, D., Gwo, DH., Saykally, R.J. (1987). Vibration-Rotation Spectroscopy of ArHCI by Far-Infrared Laser and Microwave/Far-Infrared Laser Double Resonance Spectroscopy. In: Weber, A. (eds) Structure and Dynamics of Weakly Bound Molecular Complexes. NATO ASI Series, vol 212. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3969-1_6

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  • DOI: https://doi.org/10.1007/978-94-009-3969-1_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8261-7

  • Online ISBN: 978-94-009-3969-1

  • eBook Packages: Springer Book Archive

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