Abstract
The vibrational predissociation (VP) process of the van der Waals complex He-I2-Ne, where the diatomic subunit is initially in an excited vibrational level of the electronic B state, is studied using an approximate quantum mechanical model and also a quasiclassical trajectory (QCT) method.
Only coplanar configurations of the complex have been considered. The potential surface is assumed to be the addition of atom-atom interactions that are described by Morse functions. A good agreement between QCT and quantal calculations is found for the total rate of predissociation.
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© 1987 D. Reidel Publishing Company
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Delgado-Barrio, G., Villarreal, P., Varadé, A., Martín, N., García, A. (1987). Dissociation Dynamics if the He-I2-Ne Van Der Waals Complex. In: Weber, A. (eds) Structure and Dynamics of Weakly Bound Molecular Complexes. NATO ASI Series, vol 212. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3969-1_42
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DOI: https://doi.org/10.1007/978-94-009-3969-1_42
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8261-7
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