Abstract
Rotationally inelastic collisions of Ar-O2, Ar-N2, Ar-CO and Ar-HCl are studied in a crossed molecular beams time of flight experiment.
The Ar-02 and Ar-N2 scattering shows the excitation of very large rotational quantum transitions. In Ar-HCl collisions, in contrast, the scattering is prevailingly elastic, or restricted to small △j≲2 transitions.
The Ar-O2 and the Ar-HC1 molecular beam scattering results are used for a comparison with the best available spectroscopically determined interaction potentials for these molecules.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
M. Faubel and G. Kraft; J.Chem.Phys. 85, 2671 (1986).
2/ G. Kraft; Ph.D. Thesis, Göttingen 1985.
H. Brämer; Diplom Thesis, Göttingen 1985.
J. Mettes, B. Heijmen, P. Verhoeve, J. Reass, D.C. Laine, and G. Brooks; Chem.Phys .,92, 9 (1985).
S.E. Novick, P. Davis, S.J. Harris, and W. Klemperer; J.Chem.Phys . 59, 2273 (1976).
J.M. Hutson and B.J. Howard; Molec.Phys.,45, 769 (1982).
M. Faubel ; Adv.At.Mol.Phys ,19, 345 (1983).
R. Candori, F. Pirani, and F. Vecchiocattivi; Chem.Phys.Lett. 102, 412 (1983).
D. Beck, in: “Physics of Electronic and Atomic Collisions”, p. 331, S. Datz, ed.. North Holland Publ., Amsterdam 1982.
J.M. Bowman and R. Schinke; Top.Curr. Phys .33, 61 (1982).
F.P..Tully and Y.T. Lee; J.Chem.Phys. 866 (1972), b/G. Rotzoll; Chem.Phys.Letters 179 (1982).
G. Brocks; this conference, TP-6.
We are grateful to R. Schinke and to U. Buck for providing these CS cross sections.
U. Buck and J. Schleusener; J.Chem.Phys. 75, 2470 (1981).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 D. Reidel Publishing Company
About this chapter
Cite this chapter
Faubel, M. (1987). Determination of Anisotropic Interaction Potentials from Rotational State Resolved Scattering Data. In: Weber, A. (eds) Structure and Dynamics of Weakly Bound Molecular Complexes. NATO ASI Series, vol 212. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3969-1_28
Download citation
DOI: https://doi.org/10.1007/978-94-009-3969-1_28
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8261-7
Online ISBN: 978-94-009-3969-1
eBook Packages: Springer Book Archive