Abstract
By using a molecular beam apparatus with a single frequency dye laser we were able to resolve several rovibronic transitions of some large molecules and their Van der Waals complexes with noble gas atoms. The rotational constants of tetracene, fluorene and the fluorene- argon complex have been determined. The structure of the complex was derived. In the rotational spectra of the tetracene-noble gas complexes perturbations were shown to be present, increasing with the size and number of the attached atoms. Fluorescence excitation spectra of trans- stilbene and the stilbene-argon complex are reported.
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© 1987 D. Reidel Publishing Company
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van Herpen, W.M., Majewski, W.A., Pratt, D.W., Meerts, W.L. (1987). Spectroscopy in the Visible and Near Ultraviolet Region of Some Organic Molecules and their Van Der Waals Complexes. In: Weber, A. (eds) Structure and Dynamics of Weakly Bound Molecular Complexes. NATO ASI Series, vol 212. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3969-1_20
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DOI: https://doi.org/10.1007/978-94-009-3969-1_20
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8261-7
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