Abstract
The electronic structure of 6p Hg-Ar complexes has been Investigated and described by a simple electrostatic model using the 6p average orientation with respect to the internuclear axis. The vibrational structure of the triatomic complex Hg-N2 was also described in terms of two vibrational modes, a stretching and a bending vibration. This description is essential as it is observed that the torsional modes with vibrational angular momentum Induce strong fine structure relaxation 3P1 – 3P0.
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© 1987 D. Reidel Publishing Company
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Breckenridge, W.H., Duval, M.C., Jouvet, C., Soep, B. (1987). Structure and Dynamics of Mercury Van Der Waals Complexes. In: Weber, A. (eds) Structure and Dynamics of Weakly Bound Molecular Complexes. NATO ASI Series, vol 212. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3969-1_16
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DOI: https://doi.org/10.1007/978-94-009-3969-1_16
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